More than a ring: the emerging role of heme in angiogenesis. [PDF]
De Giorgio F +3 more
europepmc +1 more source
We propose a novel displacement‐assisted approach for temperature‐programmed desorption (TPD), allowing for the detection of reactive intermediates of on‐surface reactions. We demonstrate the approach by investigating the temperature‐dependent ring fusion reactions (cyclodehydrogenations) of tetraphenylporphyrin on Cu(111), revealing the quantitative ...
Simon Steinbach +4 more
wiley +1 more source
Triarylphosphonium-conjugated Sn(iv)-porphyrins for antimicrobial photodynamic therapy: impact of substituents on lipophilicity, aggregation, and photoantibacterial activity. [PDF]
Mp G +3 more
europepmc +1 more source
First direct observation of a quasi‐reversible superoxo (FeIII─O2˙ˉ)/peroxo (FeIII─O22ˉ) redox couple in a heme model complex, featuring a biologically relevant low‐spin ferric end‐on peroxo species stabilized by second‐sphere hydrogen bonding. These findings highlight the key role of second‐sphere interactions in modulating O2 activation pathways ...
Adelais Trapali +6 more
wiley +1 more source
From Porphyrins to Versatile Photostable Bacteriochlorins: Triplet-State-Driven Design of Perfluorinated Photosensitizers. [PDF]
Barczyk D +4 more
europepmc +1 more source
Transcriptomic Profiling of SLC and ABC Transporters in the Human Term Placenta
Solute carriers (SLC) and ATP‐binding cassette (ABC) transporters are essential for placental solute exchange and fetal protection, yet their transcriptomic profiles in the human placenta remain poorly characterized. Although fetal sex influences placental development and function, its impact on transporter expression is unclear.
Elijah Marsh Jung +12 more
wiley +1 more source
Comparison of the efficacy and safety of 755-nm picosecond alexandrite laser with diffractive lens array vs. fractional microneedle radiofrequency for the treatment of facial photoaging: a retrospective study. [PDF]
Wu X +13 more
europepmc +1 more source
This review highlights emerging integrated energy systems based on perovskite photovoltaics, including PSC–thermoelectric, photovoltaic–electrochemical, self‐charging, and building‐integrated architectures. By coupling multiple energy conversion and storage pathways, these multifunctional platforms enable enhanced solar utilization, improved stability,
Yihuai Huang +10 more
wiley +1 more source
Protoporphyrin IX iron(II) revisited. overview ofthe Mössbauer spectroscopic parameters of low spin porphyrin iron(II) complexes Part II. [PDF]
Silver J +3 more
europepmc +1 more source
A single‐atom iron catalyst with well‐defined Fe–N4 sites enables a tandem epoxidation‐hydrolysis process for converting terminal olefins to 1,2‐diols. The in situ‐generated isobutyric acid drives the hydrolysis step, affording broad substrate scope and excellent recyclability.
Tao‐Tao Liu +7 more
wiley +1 more source

