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Enzyme-Inspired Iron Porphyrins for Improved Electrocatalytic Oxygen Reduction and Evolution Reactions.

Angewandte Chemie, 2021
Nature uses Fe porphyrin sites for the oxygen reduction reaction (ORR). Synthetic Fe porphyrins have been extensively studied as ORR catalysts, but activity improvement is required.
Lisi Xie   +10 more
semanticscholar   +1 more source

Coordination chemistry of expanded porphyrins

Coordination Chemistry Reviews, 2019
Expanded porphyrins are a class of porphyirinoid macrocycles possessing more than four pyrrole/other heterocyclic rings and multiple meso-carbon bridges in their conjugated structural frame-work.
Vijayendra S Shetti   +1 more
exaly   +2 more sources

Applications of porphyrins in emerging energy conversion technologies

, 2020
Porphyrins are composed of four pyrrolic subunits interconnected via methine bridges to form fully conjugated 18 π electron-containing aromatic macrocycles.
Jong Min Park, Jeong Heon Lee, W. Jang
semanticscholar   +1 more source

Controlling the Oxygen Reduction Selectivity of Asymmetric Cobalt Porphyrins by Using Local Electrostatic Interactions.

Journal of the American Chemical Society, 2020
The development and improvement of electrocatalysts for the 4H+/4e- reduction of O2 to H2O is an ongoing challenge. The addition of ancillary groups (e.g., hydrogen bonding, Brønsted acid/base) near the active site of metal-containing catalysts is an ...
Rui Zhang, J. Warren
semanticscholar   +1 more source

Self-assembly of porphyrin–azulene–porphyrin and porphyrin–azulene conjugates

Organic & Biomolecular Chemistry, 2009
In this paper we report the synthesis and self-assembling behavior of new porphyrin-azulene-porphyrin and porphyrin-azulene conjugates. The porphyrin-azulene-porphyrin conjugate gelates a number of organic solvents, while the porphyrin-azulene conjugates form vesicles in a chloroform-methanol binary mixture.
Ze-Yun, Xiao   +3 more
openaire   +2 more sources

Arsenic and porphyrins

American Journal of Industrial Medicine, 2002
AbstractBackgroundTo evaluate the possible effect of inorganic arsenic (iAs) and of its species on the urinary excretion of porphyrin homologues.MethodsTotal porphyrins and their homologues (copro, penta, hexa, hepta, uroporphyrins) and arsenic species (trivalent and pentavalent As; monomethyl arsonic acid; dimethyl arsinic acid; arsenobetaine) were ...
APOSTOLI, Pietro   +3 more
openaire   +3 more sources

Porphyrin Boxes

Accounts of Chemical Research, 2018
In order to fabricate efficient molecular photonic devices, it has been a long-held aspiration for chemists to understand and mimic natural light-harvesting complexes where a rapid and efficient transfer of excitation energy between chlorophyll pigments is observed.
Rahul Dev Mukhopadhyay   +3 more
openaire   +3 more sources

Synthesis, self-assembly and applications of functional polymers based on porphyrins

Progress in polymer science, 2019
Porphyrins and their derivatives have attracted great attention due to their unique properties and diverse functionalities which contribute to their wide applications such as catalysis, solar cells, biomedicine and environmental science.
Jia Tian, Weian Zhang
semanticscholar   +1 more source

Nanometrological porphyrins

Nanotechnology, 2012
A new cationic silver N-alkylpyridylporphyrin complex is able to 'sense' nanometric conductive particles with a diameter below 10 nm. The luminescence of the molecule changes its maximum from red to blue when it embraces a conductive (metallic or semiconducting) nanoparticle.
G A M, Safar   +5 more
openaire   +2 more sources

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