Results 51 to 60 of about 66,875 (309)

Reevaluating the Activity of ZIF‐8 Based FeNCs for Electrochemical Ammonia Production

open access: yesAdvanced Functional Materials, EarlyView.
Though receiving much attention, the field of electrochemical nitrogen reduction reaction (eNRR) to ammonia is marked by doubts about whether this reaction is possible in aqueous media. This work sheds light on this question for iron single‐atom on N‐doped carbon (FeNC) catalysts—a class of well‐known catalysts that is also worth testing for the sister
Caroline Schneider   +6 more
wiley   +1 more source

MOFs and COFs in Electronics: Bridging the Gap between Intrinsic Properties and Measured Performance

open access: yesAdvanced Functional Materials, EarlyView.
Metal‐organic frameworks (MOFs) and covalent organic frameworks (COFs) hold promise for advanced electronics. However, discrepancies in reported electrical conductivities highlight the importance of measurement methodologies. This review explores intrinsic charge transport mechanisms and extrinsic factors influencing performance, and critically ...
Jonas F. Pöhls, R. Thomas Weitz
wiley   +1 more source

Porphyrins as Theranostic Agents from Prehistoric to Modern Times

open access: yesTheranostics, 2012
Long before humans roamed the planet, porphyrins in blood were serving not only as indispensable oxygen carriers, but also as the bright red contrast agent that unmistakably indicates injury sites.
Yumiao Zhang, Jonathan F. Lovell
doaj  

Synthesis of Asymmetrical Porphyrins Substituted in the meso-Position from Dipyrrolomethanes

open access: yesMolecules, 2000
A convenient procedure for the synthesis of 5-(4-acetamidophenyl)-10,15,20-tris(4-substituted phenyl) porphyrins from dipyrrolomethane is reported. meso-(4-Substituted phenyl) dipyrrolomethanes were obtained in yields of 72-84%. The amide porphyrins were
E. N. Durantini   +3 more
doaj   +1 more source

Tailoring the Properties of Functional Materials With N‐Oxides

open access: yesAdvanced Functional Materials, EarlyView.
The properties of materials bearing N‐oxide groups are often dominated by the polar N+─O− bond. It provides hydrophilicity, selective ion‐binding, electric conductivity, or antifouling properties. Many of the underlying mechanisms have only recently been discovered, and the interest in N‐oxide materials is rapidly growing.
Timo Friedrich   +5 more
wiley   +1 more source

High‐Yield Synthesis of Fe‐NC Electrocatalysts Using Mg2+ Templating and Schiff‐Base Porous Organic Polymers

open access: yesAdvanced Functional Materials, EarlyView.
Fe─NC porous oxygen reduction electrocatalysts are prepared employing a 2,4,6‐Triaminopyrimidine‐based porous organic polymer, a Mg2+ Lewis acid, and a low‐temperature cation exchange protocol. Using the polymer precursor achieves high pyrolysis yields and results in atomically dispersed FeNx sites. The resulting catalysts feature hierarchical porosity
Eliot Petitdemange   +11 more
wiley   +1 more source

Effects of the Addition of Ortho- and Para-NH2 Substituted Tetraphenylporphyrins on the Structure of Nylon 66

open access: yesInternational Journal of Polymer Science, 2013
The synthetic tetrapyrrole macrocycles, such as porphyrins (H2P) and phthalocyanines (H2Pc), exhibit interesting physicochemical properties suitable to be used in modern technology.
Luis A. Díaz-Alejo   +4 more
doaj   +1 more source

Asymmetric Pt(II)-Porphyrin Incorporated in a PVC Ion-Selective Membrane for the Potentiometric Detection of Citrate [PDF]

open access: gold, 2023
Dana Vlascici   +7 more
openalex   +1 more source

Chiral Nanohoops as an Efficient Spin Polarization System

open access: yesAdvanced Functional Materials, EarlyView.
Chiral conjugated nanohoops with a central dibenzopentalene unit exhibit 90% spin polarization at low voltage and high conductivity. These properties make them ideal components in molecular spintronics applications. Abstract A central challenge in molecular spintronics is to achieve a high spin polarization at low operating voltages and ambient ...
Anu Gupta   +4 more
wiley   +1 more source

Characterization of designed cobaltacarborane porphyrins using conductive probe atomic force microscopy

open access: yesAIMS Materials Science, 2016
Porphyrins and metalloporphyrins have unique chemical and electronic properties and thus provide useful model structures for studies of nanoscale electronic properties.
Venetia D. Lyles   +4 more
doaj   +1 more source

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