Enzyme‐Like Synthetic Cleft for Light‐Driven Water‐Oxidation Catalysis Via an Oxide Relay Pathway
A carboxylic acid group introduced into the second coordination sphere of a Ru(bda) water oxidation catalyst forms a defined hydrogen bond within the catalytic cleft. This interaction locks the group in place and enables an intramolecular oxide relay pathway between Ru(V)═O and the carboxylate group, providing a distinct and efficient route for O─O ...
Daniel A. P. Friedewald +7 more
wiley +2 more sources
AI-driven adaptive adversaries and the erosion of cryptographic trust in public key systems. [PDF]
Radanliev P.
europepmc +1 more source
A Post-Quantum Authentication and Key Agreement Protocol Based on Lattice-Based KEM for Secure Network Environments. [PDF]
Chen X, Wu W, Liang G, Tan H, Yu Y.
europepmc +1 more source
AND‐Logic‐Gated Aptamer Switch for Precise Targeting and Regulation of RNA G‐Quadruplexes
An AND‐logic‐gated aptamer switch enables tumor‐selective activation of RNA G‐quadruplex (rG4)‐targeting function. By combining cell‐surface recognition and intracellular redox sensing, the system achieves precise regulation of disease‐relevant RNA structures exclusively in tumor cells, with minimal off‐target effects in normal cells, offering a ...
Dan Wang, Ying Feng, Chun Kit Kwok
wiley +2 more sources
Entanglement Swapping Enables the Practical Security of Quantum Cryptography. [PDF]
Jiang YF +11 more
europepmc +1 more source
Chelator‐Free Radiometal Labeling Inside Engineered Affibodies
Affibodies are compact and robust three‑helix binders used in imaging and therapy. Engineering a triple‑cysteine motif into their core enables chelator‑free binding of important radiometals, like Bi(III), Pb(II), In(III), and Ga(III) with rapid uptake and exceptional stability.
Lani J. Davies +6 more
wiley +2 more sources
Post-Quantum Entropy as a Service for Embedded Systems. [PDF]
Blanco-Romero J +5 more
europepmc +1 more source
Sequence‐Encoded Frustration Directs the Formation of Abridged G‐Quadruplex Architectures
Programmable frustration reshapes the free‐energy surface (FES) of guanine‐quadruplex (G4) folding, stabilizing an abridged G4 and a G‐triplex intermediate. ABSTRACT Frustration—competing interactions that cannot be simultaneously optimized—shapes energy landscapes in proteins and soft matter, but has rarely been exploited as a programmable design ...
Yuncheng Qian +6 more
wiley +2 more sources
TTEA: designing a quantum-ready and energy-conscious encryption model for secure IoT environments. [PDF]
Abdelaal MA +3 more
europepmc +1 more source
Post-quantum cryptographic authentication protocol for industrial IoT using lattice-based cryptography. [PDF]
Shahid AB +4 more
europepmc +1 more source

