Results 161 to 170 of about 34,352 (289)
A Crystalline and Thermally Stable Selenocysteine Selenenic Acid
Angewandte Chemie, EarlyView.The long‐sought catalytic intermediate of selenoproteins, selenocysteine selenenic acid (Sec–SeOH), is isolated for the first time at ambient temperature. A bioinspired selenopeptide sequence encapsulated within a protective molecular cradle and an oxidant‐free route from selenenyl iodide (Sec–SeI) enable the isolation of Sec–SeOH. Contrary to the long‐
Ryosuke Masuda, Satoru Kuwano, Kei Goto
wiley +2 more sources
O momento da confissão para o acordo de não persecução penal
Boletim IBCCRIMO presente artigo objetiva suscitar a discussão acerca da ocasião exigida para a confissão no Acordo de Não Persecução Penal, explorando tendência jurisprudencial que, no intento de limitar a incidência retroativa do ANPP, impõe a antecedência da ...
Pedro Guilherme Müller Kurban +1 more
doaj
A APLICAÇÃO DA TEORIA DOS PRECEDENTES NA ADMINISTRAÇÃO PÚBLICA
, 2016 O presente trabalho tem por objetivo tratar da confluência da Teoria dos Precedentes com a Administração Pública, estudando especificamente as disposições do Novo Código de Processo Civil, artigo 496, §4.º, artigo 985, §2.º e artigo 1.040, IV.Pretende-se
Salim, Lucas
core
On the Ability of Bismuth to Couple Weakly Coordinating Anions
Angewandte Chemie, EarlyView.Motivated by the growing number of catalytic processes based on high‐valent Bi, we investigated in silico the reductive elimination step responsible for the coupling of weakly coordinating anions. Relativistic contributions appeared to be decisive to the electronic description of the intermediates involved in this process.
Lucas Mele +3 more
wiley +2 more sources
As decisões vinculantes (precedentes) da justiça constitucional
, 2009 Estuda as denominadas decisões constitucionais vinculantes (ou precedentes constitucionais)
Tavares, André Ramos
core
Angewandte Chemie, EarlyView.Azidoborylene photolysis results in the isolation of a reactive C═B═N═C heterocumulene bearing an ambiphilic boron centre. Addition of 3O2 to this species results in the clean conversion to a unique example of a dioxaborirane. ABSTRACT Oxidation of the formal boron(0) complex MeCAAC2B in the presence of tetrabutylammonium azide leads to the formation ...
Hayley King +4 more
wiley +2 more sources
1,7‐Digallatetracarborane: Between Nucleophilic closo‐Cluster and “Inverse Sandwich” Digallylene
Angewandte Chemie, EarlyView.A dianionic π‐ligand is used to make a Janus‐type twofold complex with low‐valent gallium Ga(+I). The resulting compound can be seen as and reveals the reactivity of both: a Wade‐type closo‐carborane cluster with nucleophilic Ga‐sites, as well as π‐ligand stabilized Ga(I) atoms in an inverse sandwich compound.
Julijan Sarcevic +4 more
wiley +2 more sources
Érythème pigmenté fixe bulleux associé à l’ibuprofène. [PDF]
CMAJWen HY, Gao XH.
europepmc +1 more source
Mitochondria‐Targeting Moieties Based on N‐Tethered Pyridinium Cations
Angewandte Chemie, EarlyView.Pyridinium cations were benchmarked as mitochondria‐targeting moieties in a panel of N‐tethered fluorescent‐, bioactive‐, and inert‐cargo conjugates. 3,5‐Diphenylpyridinium (DPPy+) is a competent triphenylphosphonium (TPP+) surrogate, combining high mitochondria‐targeting efficiency with lower intrinsic effects on mitochondrial function.
Ivan Džajić +27 more
wiley +2 more sources
La réduction de la contribution du Canada au Fonds mondial met en péril la lutte contre les maladies infectieuses au pays. [PDF]
CMAJPatrick K, Swinkels H.
europepmc +1 more source