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Preferential Solvation Stabilization for Hydrophobic Polymeric Nanoparticle Fabrication
The Journal of Physical Chemistry B, 2005Preferential solvation of polymer molecules and strong EPD-EPA (EPD, electron pair donor; EPA, electron pair acceptor) interaction between solvent and nonsolvent molecules were found to be of great significance in the fabrication of two kinds of aromatic polyimide (AP) nanoparticles.
Xiong, J.-Y. +3 more
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Demystifying Preferential Solvation Phenomena.
The journal of physical chemistry. BIn this work we identify and derive the rigorous formal signature and unique molecular-based expression for the unambiguous assessment of the preferential solvation phenomena involving any type of dilute solute in any mixed binary-solvent system. In particular, we formulate the rigorous assessment of preferential solvation in ternary system involving a
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Preferential solvation of methylmercurated calf thymus deoxyribonucleic acid
Archives of Biochemistry and Biophysics, 1976Abstract The changes in polymer-solvent interactions that occur when native calf thymus DNA is dialyzed against Na 2 SO 4 solutions of a given ionic strength and buffer concentration but of varying concentrations in methylmercuric hydroxide have been investigated with the help of solution density measurements at 25 °C and pH 6.8–7.0.
J C, Fu, D W, Gruenwedel
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Pure and Applied Chemistry, 1979
Of paramount importance to the understanding of the behaviour of solutes in solvent media is the problem of solute-solvent interaction (solvation), or, in solvent mixtures, of solvent-sorting in the solvation sphere of the solute (preferential solvation).
A. K. Covington, K. E. Newman
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Of paramount importance to the understanding of the behaviour of solutes in solvent media is the problem of solute-solvent interaction (solvation), or, in solvent mixtures, of solvent-sorting in the solvation sphere of the solute (preferential solvation).
A. K. Covington, K. E. Newman
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Preferential solvation study: Solvation of sodium chloride in water-hydroxylamine mixtures
Chemical Physics, 1996Abstract MC simulations have been carried out to determine the solvation structure of NaCl in water/hydroxylamine mixtures of different composition. Na + prefers solvation by NH 2 OH over the whole concentration range studied, proving a stronger N-affinity of this ion compared to the O-preferring Li + .
Sergi Vizoso, Bernd M. Rode
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Preferential Solvation/Hydration of α-Chymotrypsin in Water–Acetonitrile Mixtures
The Journal of Physical Chemistry B, 2017The aim of our study is to monitor the preferential hydration/solvation of the protein macromolecules at low and high water content in water-organic mixtures. Our approach is based on the analysis of the absolute values of the water/organic solvent sorption.
Vladimir A. Sirotkin +1 more
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Preferential solvation in two-component systems
The Journal of Physical Chemistry, 1989Deux types de melanges binaires sont etudies: (alcool ou THF ou dioxanne) avec soit de l'eau, soit du tetrachlorure de ...
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The Journal of Physical Chemistry B, 2019
We report the solvation structure of a lower critical solution temperature (LCST)-type thermoresponsive polymer in a solvate ionic liquid (SIL, i.e., an ionic liquid comprising solvate ions) to elucidate the predominant interaction for the dissolution of the thermoresponsive polymer in SIL at low temperatures.
Kei Hashimoto +6 more
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We report the solvation structure of a lower critical solution temperature (LCST)-type thermoresponsive polymer in a solvate ionic liquid (SIL, i.e., an ionic liquid comprising solvate ions) to elucidate the predominant interaction for the dissolution of the thermoresponsive polymer in SIL at low temperatures.
Kei Hashimoto +6 more
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Study on Preferential Solvation of Water by Electrochemical Method
Electroanalysis, 2019AbstractThe preferential solvation of water plays an important role in ferrocene research which is a subject of current interest. Voltammetric investigations were carried out for Au electrode in acetonitrile/water, showing preferential solvation of water.
Chunxia Yan +4 more
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A Fluorescence Spectroscopy Study of Preferential Solvation in Binary Solvents
ChemInform, 2006AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
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