Results 131 to 140 of about 1,079 (262)

Revealing Structure–Performance Relations in Core‐Shell Catalyst‐Based PEM Water Electrolyzer Anodes with Low Iridium Loading

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Table of Contents The TiO2@IrO2 core–shell architecture ensures high electronic conductivity even at a low iridium content of 10 wt%. The resulting catalyst layer shows significantly higher iridium utilization than a commercial reference, leading to improved PEMWE single‐cell performance at low iridium loading.
Selina Finger   +16 more
wiley   +1 more source

Polymerization of Heteroleptic Amphiphilic Osmium(II) Complexes at the Air/Water Interface: Attempts Toward Nanoarchitectonics in Form of Molecular Textiles

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
Amphiphilic heteroleptic osmium(II) complexes enable a bottom‐up route toward molecular textiles via interfacial polymerization. Confined to a single monolayer, noncontact atomic force microscopy reveals predominantly linear polymers with partial branching.
Luise J. Sokoliuk   +7 more
wiley   +1 more source

Investigation of α‐Silylalcohols as Chiral Umpolung Carbanion Surrogates Through Stereospecific 1,2‐Brook Rearrangement

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Deprotonation of chiral α‐silyl secondary alcohols leads to masked polarity‐reversed chiral carbanions through stereospecific 1,2‐Brook rearrangement. In situ trapping with Weinreb amide electrophiles affords α‐hydroxyketones with moderate to excellent enantiospecificity (es).
TyAnn McHenry, Joshua D. Sieber
wiley   +1 more source

Axial Chirality Control Through Palladium‐Catalyzed Alkenylation Reactions for the Atroposelective Synthesis of 4‐Arylquinolin‐2‐ones

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Palladium(II)‐catalyzed intramolecular C─H alkenylation of cinnamides allows the atroposelective synthesis of axially chiral 4‐arylquinolones, with the chirality being installed by ring formation. DFT studies have shown that the reaction proceeds by prior activation of the alkene and the enantioselectivity is determined during the β‐hydride elimination
Brenda Fundora   +8 more
wiley   +1 more source

Bridging Flavour and Fragrance: A Behaviour‐Based Olfactory Pyramid for Whisky Maturation Inspired by Perfumery Principles

open access: yesFlavour and Fragrance Journal, EarlyView.
This framework transposes the perfumery olfactory pyramid to whisky maturation by sequencing aromas into top, heart, and base notes according to their temporal persistence. Using Log P as a behaviour‐based classification axis and oak macromolecules as natural fixative analogues, it proposes a behaviour‐based aromatic wheel bridging flavour chemistry ...
Magali Picard
wiley   +1 more source

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