Results 71 to 80 of about 1,079 (262)

Molecular Conversion of Thermally Stable Cu‐Ag Networks for Mechanically Robust Printed Electronics

open access: yesAdvanced Science, EarlyView.
An air‐processable Cu–Ag reactive ink enables in situ formation of an Ag‐surface‐enriched Cu conductive network. Optimized Ag distribution suppresses Cu oxidation while preserving continuous electrical pathways, allowing printed conductors to achieve high conductivity, reduced migration, and stable operation at extreme temperatures up to 800 °C in air.
Qikun Feng   +9 more
wiley   +1 more source

Guest Transition Metals in Host Keplerate Nanocapsules as Supramolecular Inorganic Functional Mimics of Monooxygenase Enzymes

open access: yesAngewandte Chemie, EarlyView.
A Keplerate, an inorganic, porous buckyball was used as a host for copper metal cations ligated by histidine surrogates. Prepared by a simple assembly technique, the guest–host complex was used as a primitive biomimetic model of a monooxygenase enzyme complex, where C─H bonds were electrocatalytically hydroxylated by oxygen under reducing conditions ...
Eynat Haviv   +4 more
wiley   +2 more sources

Polymer Sequence Design of Zwitterionic Polymer/PEDOT:PSS Blend Films for Improved Charge Transport and Stability in Organic Electrochemical Transistors

open access: yesAdvanced Electronic Materials, EarlyView.
Solution blending of zwitterionic polymers with PEDOT:PSS provides a simple route to OECT materials with enhanced threshold voltage stability in biologically relevant environments. The polymer sequence alters outer‐domain structure within the preserved PEDOT:PSS framework, thereby tuning charge transport.
Wakana Takahashi   +3 more
wiley   +1 more source

Sidechain Modulation of Responsive Metal‐Organic Framework Pore Chirality for Enhanced Enantioseparation

open access: yesAngewandte Chemie, EarlyView.
[Zn2(L‐ValPyr)2] is a chiral and flexible metal‐organic framework that places the isopropyl sidechains of L‐valine inside the pores, creating accessible space in the shape of a three‐blade propeller. The framework adapts its structure to position the substituted aromatic guests in its peripheral pockets through favorable interactions with the isopropyl
Luke A. Johnson   +7 more
wiley   +2 more sources

Modulation of Local Environment for Selective Bicarbonate Conversion to Multi‐Carbon Products

open access: yesAdvanced Energy Materials, EarlyView.
Highly porous Cu electrode partially coated with an ionomer/carbon composite enables efficient conversion of bicarbonate to multi‐carbon products. By regulating the local reaction microenvironment, this strategy overcomes selectivity and reaction‐rate limitations, achieving Faradaic efficiencies of 43% for ethylene and 60% for total multi‐carbon ...
Tai Nguyen   +15 more
wiley   +1 more source

Straightforward Synthesis of Enantiopure 2,3-Dihydrobenzofurans by a Sequential Stereoselective Biotransformation and Chemical Intramolecular Cyclization

open access: yes, 2016
A new family of optically active 2,3-dihydrobenzofurans has been prepared by a simple chemoenzymatic asymmetric strategy. This synthetic approach is based on the combination of a lipase-mediated kinetic resolution of 1-aryl-2-propanols or bioreduction of
Eduardo Busto (1470310)   +3 more
core   +2 more sources

On the dehydrogenation of 1- and 2-propanols on Cu(111) surface: A UBI-QEP based approach

open access: yes, 2004
2049-2054The method of unity bond index-quadratic exponential potential (UBI-QEP) has been employed to investigate the energetics of routes to adsorption and decomposition of 1- and 2-propanols on Cu(111) plane.
Gobal, F, Eftekhari, A
core  

MXene‐Derived Highly Oriented TiN Enables Ta3N5 Photoanodes for Transmission‐Mode Bias‐Free Solar Water Splitting

open access: yesAdvanced Energy Materials, EarlyView.
This work reports 2D MXene‐derived TiN thin films with (111)‐preferred orientation for transparent Ta3N5 photoanodes, demonstrating effective electron transfer behavior. All‐nitride electron‐collection architecture based on MXene‐derived TiN and n‐GaN resolves a long‐standing materials bottleneck between photocarrier transport and light transmission in
Jin Wook Yang   +10 more
wiley   +1 more source

Nanocrystalline LCO/LLZO Composite Cathode Films for Solid State Batteries

open access: yesAdvanced Energy Materials, EarlyView.
A single precursor solution is solution‐deposited and calcined at only 750°C to yield a dense, nanograined LiCoO2/LLZO composite cathode, in which both phases crystallize independently with minimal interdiffusion. Assembled into all‐solid‐state Li‐metal batteries, the composite delivers 111.7 mAh g−1 initial discharge capacity and retains 93% after 100
Lucie Quincke   +8 more
wiley   +1 more source

Reaction of 5-Chloroalkyl-3-phenyl-4,5-dihydroisoxazoles with strong base. An unexpected new synthesis of the 2-Oxa-3-azabicyclo[3,1,0]hex-3-ene ring system

open access: yes, 1977
Reaction of 5-chloromethyl-3-phenyl-4,5-dihydroisoxazole with potassium t-butoxide in dimethyl sulphoxide gives 4-phenyl-2-oxa-3- azabicyclo[3,1,0]hex-3-ene in high yield and reaction of the 5-(1?- chloroethyl) homologue gives high yields of the ...
WR Jackson   +3 more
core   +1 more source

Home - About - Disclaimer - Privacy