Results 91 to 100 of about 1,561 (166)

How to Make a Phosphine by Catalytic Hydrophosphination

open access: yesChemistry–Methods, Volume 6, Issue 9, September 2026.
Catalysis is the winning hand for hydrophosphination. Three general advances, electrophilic metals, ionic and solvent effects, and photocatalysis have allowed for large categories of unsaturated and phosphine substrates to be accessed. Through these advances, a catalyst that can provide good conversion for most substrates can now be found. Implications
Rory Waterman
wiley   +1 more source

Solvation of ions. XIX. Thermodynamic properties for transfer of single ions between protic and dipolar aprotic solvents

open access: yes, 1974
Standard molar free energies, enthalpies and entropies of transfer of some uni-univalent electrolytes from water to methanol, N-methylformamide, formamide, dimethyl sulphoxide, N,N-dimethyl- formamide, propylene carbonate, sulpholane, N-methylpyrrolidone
AJ Parker, BG Cox, DW Watts, GR Hedwig
core   +1 more source

Microwave-assisted extraction of Garcinia × mangostana L. and its ‘Mesta’ cultivar rinds: Physicochemical and antioxidant properties analyzed using multiple chemometric algorithms

open access: yesFood Chemistry Advances
Mangosteen rind is an underutilized by-product rich in bioactive compounds. This study assessed the effect of microwave-assisted extraction (MAE) using different protic and aprotic solvents on the rinds of common mangosteen (Garcinia × mangostana L.) and
Peir Shinn Hew   +4 more
doaj   +1 more source

Efficient One‐Pot Synthesis of 1,2,4,5‐Tetrasubstituted Imidazoles Using GO@SiO2@[(CH2)3Im][Cl] as a Novel Nanocomposite Under MW Irradiation

open access: yesChemistryOpen, Volume 15, Issue 9, September 2026.
This study presents the development of a novel nanocomposite catalyst, GO@SiO2@[(CH2)3Im][Cl], for the efficient one‐pot synthesis of 1,2,4,5‐tetrasubstituted imidazoles under environmentally benign conditions. The catalyst design incorporates graphene oxide, silica, and an imidazolium‐functionalized layer, creating a unique catalytic environment for ...
Mohamed Abu Shuheil   +8 more
wiley   +1 more source

Structure Determination Using the Method of Continuous Variation: Lithium Phenolates Solvated by Protic and Dipolar Aprotic Ligands

open access: yes, 2016
The method of continuous variation (MCV) was used in conjunction with 6Li NMR spectroscopy to characterize four lithium phenolates solvated by a range of solvents, including N,N,N′,N′-tetramethylethylenediamine, Et2O, pyridine, protic amines, alcohols ...
David B. Collum (1308378)   +1 more
core   +1 more source

A Physical Organic Odyssey: From the Ultrafast Dynamics of Carbenes and Nitrenes to Contemporary Chemical Biology and Drug Discovery

open access: yesJournal of Physical Organic Chemistry, Volume 39, Issue 9, September 2026.
Physical organic chemistry transforms photoaffinity labeling from empirical photochemistry into rational probe design. By measuring reactive‐intermediate lifetimes, pathways, and selectivity, Platz's legacy connects carbene and nitrene mechanisms to modern chemoproteomics, enabling more precise protein labeling and drug‐discovery maps.
Bin Yang, Jin Wang
wiley   +1 more source

Molecular structural, vibrational spectra, dual descriptor, electronic transition and biological evaluations of ethyl 4‑hydroxy-3-methoxycinnamate using density functional theory

open access: yesChemical Physics Impact
Quantum chemical, spectroscopic and bioactivity studies of pharmacologically active Ethyl 4‑hydroxy 3‑methoxy ethyl cinnamate (EHMC) were investigated.
G. Bharathy   +4 more
doaj   +1 more source

Solvent‐Responsive Porous Organic Cage‐Based Membranes With Switchable Pore Openings for Molecular Sieving and Heavy Metal Recovery

open access: yesSmall, Volume 22, Issue 52, 16 September 2026.
An in situ fabricated porous organic cage membranes (PCM) exhibits reversible solvent pore switching property in response to water and methanol. Water stimulated structural rearrangement enables selective removal of Rh B and heavy metal ions (Ni2+ and Zn2+), whereas methanol stimulates the pore expansion promotes Ni2+ and Zn2+ ions recovery.
Jisha Kuttiani Ali, Emad Alhseinat
wiley   +1 more source

Synthesis, crystal structure and physico-chemical properties of 3,3’-[(4-hydroxyphenyl)methyl] bis-(4-hydroxy-2H-chromen-2-one)

open access: yesActa Chimica Slovenica, 2014
The compound 3,3’-[(4-Hydroxyphenyl)methyl]bis-(4-hydroxy-2H-chromen-2-one) was synthesized by the Knoevenagel reaction. Crystals, suitable for X-ray data collection were grown by slow evaporation from an ethanol solution.
Denitsa Elenkova   +3 more
doaj  

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