Results 81 to 90 of about 10,994 (228)

Spectroscopic and computational insights into the ion–solvent interactions in hydrated aprotic and protic ionic liquids [PDF]

open access: yesPhysical Chemistry Chemical Physics, 2019
Systematic experimental and theoretical analysis of protic and aprotic ionic liquids (ILs) was executed to gain insights into the IL-hydration at molecular level, which will be basis for the next step, i.e., the study of proteins in hydrated ILs.
Kaushik Kundu   +3 more
openaire   +3 more sources

State‐of‐the‐Art and Synthetic Challenges for Hydrosilane Production

open access: yesChemistry – A European Journal, EarlyView.
The synthesis of hydrosilanes is currently energy intensive and their recycling is not considered. However, these compounds are important in many industrial fields but also for the valorization of oxygenated waste, towards a circular economy. This review compares the available synthetic routes and highlights the remaining challenges for the production ...
Gabriel Durin   +3 more
wiley   +1 more source

Electrical Conductivity of Films Formed by Few-Layer Graphene Structures Obtained by Plasma-Assisted Electrochemical Exfoliation of Graphite

open access: yesInternational Journal of Electrochemistry, 2019
Current-voltage characteristics of few-layer graphene structures (FLGS) obtained by plasma-assisted electrochemical exfoliation of graphite in Na2SO4 solution were measured.
Vladimir P. Vasiliev   +2 more
doaj   +1 more source

Special Solvation Behaviour of Salts in Ionic Liquid

open access: yes, 2012
In a previous study1 from the Welton Group, the reactivity resulting from mixing two different and reactive salts together was observed to be highly dependent on the type of solvent, with molecular and ionic liquids exhibiting fundamentally different ...
Lui, Matthew Yuk Yu, Lui, Matthew Yuk Yu
core   +1 more source

Harnessing poly(ionic liquid)s for sensing applications [PDF]

open access: yes, 2016
The interest in poly(ionic liquid)s for sensing applications is derived from their strong interactions to a variety of analytes. By combining the desirable mechanical properties of polymers with the physical and chemical properties of ILs, new materials ...
Ambrogi, M., Guterman, R., Yuan, J.
core   +2 more sources

Cationic Permethylated Cyclodextrins Capable of Self‐Assembling Into Linear Nanostructures in Water

open access: yesChemistry – A European Journal, EarlyView.
A quaternary ammonium bridge equipped with a lipophilic substituent in permethylated cyclodextrins suppresses undesired supramolecular interactions and promotes controlled, directional head‐to‐tail self‐assembly into well‐defined linear nanostructures.
Maxime Kolb   +4 more
wiley   +1 more source

Thermodynamics of liquids: standard molar entropies and heat capacities of common solvents from 2PT molecular dynamics [PDF]

open access: yes, 2011
We validate here the Two-Phase Thermodynamics (2PT) method for calculating the standard molar entropies and heat capacities of common liquids. In 2PT, the thermodynamics of the system is related to the total density of states (DoS), obtained from the ...
Goddard, William A., III   +2 more
core   +2 more sources

Photolytic Hydrophosphination: Insights Into Catalyzed and Uncatalyzed Processes

open access: yesChemistry – A European Journal, EarlyView.
Catalyst‐free photolytic hydrophosphination is demonstrated for vinyl arenes and activated alkenes in polar protic (alcohol) solvents. These reactions appear to be closed‐shell, affirming that even ambient light can impact a reaction—a potentially broad influence on even mundane reactions.
Emma J. Finfer   +2 more
wiley   +1 more source

Synthesis and Characterization of Trivalent Cerium Complexes of p-tert-Butylcalix[4,6,8]Arenes: Effect of Organic Solvents

open access: yesJournal of Chemistry, 2013
Reaction of Ce3+ with p-tert-butylcalix[n]arene (n=4,6,8) yields purple crystalline complexes structurally as [Ce(p-tert-butylcalix[4]arene-3H)2(NO3)(DMF)x](2 − x)DMF (1), [Ce(p-tert-butylcalix[6]arene-4H)2(NO3)(DMF)x](3 − x)DMF (2), and [Ce(p-tert ...
Md. Hasan Zahir
doaj   +1 more source

Response and Discrimination Performance of Arrays of Organothiol-Capped Au Nanoparticle Chemiresistive Vapor Sensors [PDF]

open access: yes, 2011
The response and discrimination performance of an array that consisted of 20 different organothiol-capped Au nanoparticle chemiresistive vapor sensors was evaluated during exposure to 13 different organic vapors.
Brunschwig, Bruce S.   +5 more
core   +2 more sources

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