Results 41 to 50 of about 3,195 (187)

Photolytic Hydrophosphination: Insights Into Catalyzed and Uncatalyzed Processes

open access: yesChemistry – A European Journal, EarlyView.
Catalyst‐free photolytic hydrophosphination is demonstrated for vinyl arenes and activated alkenes in polar protic (alcohol) solvents. These reactions appear to be closed‐shell, affirming that even ambient light can impact a reaction—a potentially broad influence on even mundane reactions.
Emma J. Finfer   +2 more
wiley   +1 more source

Synthesis, Self-Assembly in Crystalline Phase and Anti-Tumor Activity of 2-(2-/4-Hydroxybenzylidene)thiazolo[3,2-a]pyrimidines

open access: yesMolecules, 2022
A series of new thiazolo[3,2-a]pyrimidines different by aryl substituents in 2 and 5 positions are synthesized and characterized in solution as well as in the crystalline phase using 1H and 13C NMR-, IR-spectroscopies, mass-spectrometry methods, and ...
Artem S. Agarkov   +10 more
doaj   +1 more source

Solvent Effects on the Conformational Preferences of 2,6‐Pyridylcarboxamide Foldamers

open access: yesChemistry – A European Journal, EarlyView.
The marked effect of organic solvents and water/methanol mixtures on the conformational preferences of a soluble chiral foldamer has been established in a diverse array of seventeen distinct environments. ABSTRACT The marked influence of organic solvents and water on the conformational preferences of a chiral, soluble 2,6‐pyridylcarboxamide foldamer ...
Alexander R. Davis   +5 more
wiley   +1 more source

Flipping the Card With Enantiodivergent Organocatalysis

open access: yesChemistry – A European Journal, EarlyView.
This minireview elaborates on recent organocatalytic strategies for achieving enantiodivergence—the ability to access both product enantiomers using a single chiral catalyst. It highlights how achiral stimuli, such as solvent polarity and chemical additives, along with minimal catalyst modifications, trigger stereochemical inversions in reactions ...
Debora Iapadre   +3 more
wiley   +1 more source

Aggregation-induced emission effect on turn-off fluorescent switching of a photochromic diarylethene

open access: yesBeilstein Journal of Organic Chemistry, 2019
Background: Diarylethenes are well-known photochromic compounds, which undergo cyclization and cycloreversion reactions between open- and closed-ring isomers.
Luna Kono   +10 more
doaj   +1 more source

On the chemiluminescence emission of luminol: protic and aprotic solvents and encapsulation to improve the properties in aqueous solution

open access: yesPhysical Chemistry Chemical Physics, 2020
Luminol encapsulation increases the chemiluminescence wavelength and emission intensity for non-invasive cancer treatments.
Ana Borrego-Sánchez   +3 more
openaire   +3 more sources

Xylose Acetals ‐ a New Class of Sustainable Solvents and Their Application in Enzymatic Polycondensation

open access: yesChemSusChem, Volume 18, Issue 6, March 15, 2025.
Novel organic solvents with an unmodified carbohydrate core were synthesised both from D‐xylose and directly from biomass and were successfully used as reaction media for lipase biocatalysts to synthesise aliphatic and aromatic polyesters. Abstract The use of organic solvents in academic research and industry applications is facing increasing ...
Anastasia O. Komarova   +8 more
wiley   +1 more source

Fluorescence and photostability studies of anthracene-9-carboxylic acid in different media

open access: yesInternational Journal of Photoenergy, 2000
Electronic absorption and fluorescence spectra of anthracene-9-carboxylic acid (ANCA) were studied in different homogeneous solvents, binary protic/aprotic solvent mixtures and in heterogeneous solutions of the cationic cetyltrimethyl ammonium bromide ...
M. S. A. Abdel-Mottaleb   +6 more
doaj   +1 more source

Impact of Electronic Substitution and Planarization on the Photophysical Properties of 2‐(2′‐Hydroxyphenyl)benzoxazole or 2‐(2′‐Hydroxyphenyl)‐Dimethylindole

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
We report the synthesis, structural characterization, and photophysical investigation of a series of Excited‐State Intramolecular Proton Transfer‐active HBO and HDMI derivatives. By varying heterocyclic cores, substituents, and ethynyl planarization, we establish structure–property relationships governing fluorescence behavior.
Mathieu Gervais   +7 more
wiley   +1 more source

Edible coatings in food: Specific materials and their impact on techno‐functional properties and sustainable applications

open access: yesFood Biomacromolecules, EarlyView.
Abstract Edible coatings have emerged as a significant advancement in the food industry. This review explains the different materials, methods, and applications of edible coatings, with a special focus on the integration of nanotechnology and its contribution to the circular economy.
Shankar Senthilkumar   +4 more
wiley   +1 more source

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