Results 41 to 50 of about 1,561 (166)

Synthesis and fluorosolvatochromism of 3-arylnaphtho[1,2-b]quinolizinium derivatives

open access: yesBeilstein Journal of Organic Chemistry, 2016
Cationic biaryl derivatives were synthesized by Suzuki–Miyaura coupling of 3-bromonaphtho[1,2-b]quinolizinium bromide with arylboronic acids. The resulting cationic biaryl derivatives exhibit pronounced fluorosolvatochromic properties.
Phil M. Pithan   +4 more
doaj   +1 more source

The capacitance and electron transfer of 3D-printed graphene electrodes are dramatically influenced by the type of solvent used for pre-treatment

open access: yesElectrochemistry Communications, 2019
3D-printing (or additive manufacturing) is presently an emerging technology that promises to reshape traditional manufacturing processes. The electrochemistry field can certainly take advantage of this fabrication tool for sensing and energy-related ...
Rui Gusmão   +3 more
doaj   +1 more source

Preferential Solvation of Zwitterionic Benzo-[f]-Quinolinium Ylids in Binary Solvent Mixtures: Spectral Study and Quantum Chemical Calculations

open access: yesMolecules
Three derivatives of benzo-[f]-quinolinium ylids, which all underwent an intermolecular charge transfer process, were used as solvatochromic indicators to study the specific solvent–solute interactions in binary mixtures of protic–aprotic solvents with ...
Mihaela Iuliana Avadanei   +2 more
doaj   +1 more source

Amino-functionalized polysaccharide derivatives: Synthesis, properties and application

open access: yesCurrent Research in Green and Sustainable Chemistry, 2022
Polysaccharides, cellulose and chitin are fundamental structural biopolymers of our biome, they therefore demonstrate relatively high tensile strength compared to other biopolymers and great diversity.
Anwar Jardine
doaj   +1 more source

Solvent Effects on the Conformational Preferences of 2,6‐Pyridylcarboxamide Foldamers

open access: yesChemistry – A European Journal, EarlyView.
The marked effect of organic solvents and water/methanol mixtures on the conformational preferences of a soluble chiral foldamer has been established in a diverse array of seventeen distinct environments. ABSTRACT The marked influence of organic solvents and water on the conformational preferences of a chiral, soluble 2,6‐pyridylcarboxamide foldamer ...
Alexander R. Davis   +5 more
wiley   +1 more source

Mechanistic Insights Into Luminol Chemiexcitation: The Role of the Amide Carbonyls

open access: yesChemistry – A European Journal, EarlyView.
By means of quantum‐chemical calculations, we demonstrate that the 1,2‐dioxin ring forms following nitrogen release from parent luminol. We also identify alkoxide groups derived from the amide carbonyls of luminol as key enhancers of the chemiexcitation yield.
Juliana Cuéllar‐Zuquin   +3 more
wiley   +1 more source

The comparative study of linear solvatation energy relationship for the reactivity of pyridine carboxylic acids with diazodiphenylmethane in protic and aprotic solvents [PDF]

open access: yesJournal of the Serbian Chemical Society, 2012
Protic and aprotic solvent effects on the reactivity of picolinic, nicotinic and isonicotinic acid, as well as of some substituted nicotinic acids with diazodiphenylmethane (DDM) were investigated.
Drmanić Saša Ž.   +3 more
doaj   +1 more source

Xylose Acetals ‐ a New Class of Sustainable Solvents and Their Application in Enzymatic Polycondensation

open access: yesChemSusChem, Volume 18, Issue 6, March 15, 2025.
Novel organic solvents with an unmodified carbohydrate core were synthesised both from D‐xylose and directly from biomass and were successfully used as reaction media for lipase biocatalysts to synthesise aliphatic and aromatic polyesters. Abstract The use of organic solvents in academic research and industry applications is facing increasing ...
Anastasia O. Komarova   +8 more
wiley   +1 more source

Protic Ionic Liquids:  Solvents with Tunable Phase Behavior and Physicochemical Properties

open access: yes, 2016
The phase behavior, including glass, devitrification, solid crystal melting, and liquid boiling transitions, and physicochemical properties, including density, refractive index, viscosity, conductivity, and air−liquid surface tension, of a series of 25 ...
Irena Krodkiewska (2223880)   +4 more
core   +2 more sources

Solubility and dissolution thermodynamic data of mefenamic acid crystals in different classes of Organic solvents [PDF]

open access: yes, 2013
Different classes of solvents provide different polarity values, which influence the solubility of pharmaceutical solids. In this article, the solubility of mefenamic acid in different classes of organic solvents, including polar protic, dipolar aprotic,
Adam, Fatmawati   +3 more
core   +2 more sources

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