Results 31 to 40 of about 1,561 (166)

Broadband fluorescence reveals mechanistic differences in excited-state proton transfer to protic and aprotic solvents

open access: yes, 2020
Excited-state proton transfer (ESPT) to solvent is often explained according to the two-step Eigen-Weller model including a contact ion pair (CIP*) as an intermediate, but general applicability of the model has not been thoroughly examined.
Vauthey, Eric   +4 more
core   +1 more source

Towards Understanding the Solvatochromatic Behavior of Fluorenone and Benzofluorenone Derivatives in Protic Solvents

open access: yes, 2022
In this paper, we investigate the solvatochromatic behaviors of fluorenone and benzofluorenone derivatives in both protic and aprotic solvents. While the effects of aprotic solvents on these dyes have been extensively studied in silico, little has been ...
Colley, Kiser Z., Dunn, Timothy
core   +1 more source

The Influence of Chromophore Structure on Intermolecular Interactions. A Study of Selected Rhodamines in Polar Protic and Aprotic Solvents [PDF]

open access: yes, 2020
We have studied the linear optical response and orientational relaxation dynamics of a family of rhodamine dyes in which there is substantial variation in the chromophore structure. For these chromophores, the identity of a substituent at the center ring
J L Dela Cruz, G J Blanchard
core  

Sustainable and Multifunctional Natural Macromolecular Polymers for Aqueous Zn Metal Batteries

open access: yesAdvanced Materials, EarlyView.
We comprehensively review the structure‐function relationships and regulatory mechanism of natural macromolecular polymers in stabilizing zinc anodes at the microscopic and mesoscopic scales. The interactions among polymer structures, optimization strategies, and regulatory mechanisms are discussed systematically summarizing recent related research ...
Yunuo Shi   +13 more
wiley   +1 more source

Formação de micelas de cloreto de cetilpiridinio em soluções aquosas de dimetilsulfoxido, dimetilformamida e dimetilacetamida [PDF]

open access: yes, 1981
Dissertação (mestrado) - Universidade Federal de Santa Catarina. Centro de Ciencias Fisicas e MatematicasA formação de micelas de cloreto de cetilpiridinio (CPC1) em soluções aquosas de dimetilsulfóxido (DMSO), dimetilformamida (DMF) e dimetilacetamida ...
Souza, Valmor Eretiano de
core  

Ultrafast Excited-State Dynamics of Hydrogen-Bonded Cytosine Microsolvated Clusters with Protic and Aprotic Polar Solvents

open access: yes, 2018
Microsolvation effects on the ultrafast excited-state deactivation dynamics of cytosine (Cy) were studied in hydrogen-bonded Cy clusters with protic and aprotic solvents using mass-resolved femtosecond pump–probe ionization spectroscopy.
Hung-Chien Yen   +17 more
core   +1 more source

Hidratação da 2,2,2-tricloro-1-feniletanona e derivados [PDF]

open access: yes, 1983
Dissertação (mestrado) - Universidade Federal de Santa Catarina, Curso de Pós-Graduação em Físico ...
Silva, Mauro Baldez
core  

Prolonged Luminescence Lifetime of a Dual Emissive Ruthenium Dipyridophenazine-Type Complex in Aprotic and Protic Solvents

open access: yes, 2021
A recently reported ruthenium­(II) complex bearing an extended dipyridophenazine ligand exhibits unusual long-lived dual emission at room temperature. In this study, the effect of the introduction of a methyl protecting group to the imidazole moiety of ...
Sven Rau (1306290)   +9 more
core   +1 more source

Polarity-Dependent Twisted Intramolecular Charge Transfer in Diethylamino Coumarin Revealed by Ultrafast Spectroscopy

open access: yesChemosensors, 2022
Twisting intramolecular charge transfer (TICT) is a common nonradiative relaxation pathway for a molecule with a flexible substituent, effectively reducing the fluorescence quantum yield (FQY) by swift twisting motions.
Jiawei Liu, Cheng Chen, Chong Fang
doaj   +1 more source

Cinetica da reação de aminolise de 2, 2, 2 - tricloro - 1 - ariletanonas [PDF]

open access: yes, 1988
Dissertação (mestrado) - Universidade Federal de Santa Catarina, Centro de Ciencias Fisicas e MatematicasA cinética da aminólise de 2,2,2-tricloro-1-ariletanonas (1), a 25oC mostra que a ordem da reação em relação às aminas depende do solvente usado ...
Druzian, Janice Izabel
core  

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