Results 31 to 40 of about 4,840 (219)

Site Density Governs Switching Reactivity Regimes During Aerobic C─H Oxidation in Mn Single‐Atom Photocatalysts

open access: yesAngewandte Chemie, EarlyView.
Increasing the density of isolated manganese (Mn) atoms in carbon nitride (CNx) photocatalysts does not continuously improve performance. Instead, beyond a critical loading, the polymer support reorganizes, altering charge‐carrier dynamics and oxygen activation while preserving atomic dispersion.
Viktoria Velichko   +14 more
wiley   +2 more sources

Effect of Solvent and Catalyst Types on Stability and Properties of Zinc Phthalocyanine in the Organic–Inorganic Hybrid Materials

open access: yesCrystals, 2021
Hybrid materials, i.e., the organically modified silicates (ORMOSIL) based on zincphthalocyanine (ZnPc) and silica glass matrix were synthesized by the sol-gel method using protic solvents (methanol, ethanol, isopropanol, butanol) and aprotic solvent (N ...
Barbara Popanda   +2 more
doaj   +1 more source

Remote Electrostatic Effect between Octahedral Ru/Ir‐Complexes and Aromatic Micelles to Improve Their Photofunctions in Water

open access: yesAngewandte Chemie, EarlyView.
The aqueous‐state encapsulation of cationic Ru(II)/Ir(III)‐complexes is efficiently demonstrated by anionic aromatic micelles via remote electrostatic interactions. The resulting host–guest composites exhibit enhanced metal‐complex‐based emission (∼3 to 10‐fold) and NIR emission through guest‐to‐guest FRET upon co‐encapsulation.
Rina Morooka   +2 more
wiley   +2 more sources

Hydrothermal Reactions of Biomass-Derived Platform Molecules: Distinct Effect of Aprotic and Protic Solvents on Primary Decomposition of Glucose and Fructose in Hot-Compressed Solvent/Water Mixtures

open access: yes, 2020
The study compares the effects of aprotic (i.e., gamma-valerolactone, acetone, and 1,4-dioxane) and protic (i.e., methanol and ethanol) solvents on the primary decomposition reactions of glucose and fructose, which are key biomass-derived platform ...
Zhiliang Wu (618345)   +7 more
core   +1 more source

Red-Shifted Environmental Fluorophores and Their Use for the Detection of Gram-Negative Bacteria

open access: yesChemosensors, 2021
Two novel, water-soluble, merocyanine fluorophores were readily prepared by microwave-assisted synthesis. Full optical characterization was performed in a series of protic and aprotic solvents, and the dyes displayed fluorescence in the red region with ...
Alicia Megia-Fernandez   +7 more
doaj   +1 more source

Solvatochromism studies on UV spectra of 4,5-disubstituted-1,2,4-triazoline-3-thiones

open access: yesMacedonian Journal of Chemistry and Chemical Engineering, 2012
The influence of a series of organic solvents on the UV spectra of investigated 1,2,4-triazoles, was studied by implementing solvatochromic theory.
Vesna B. Dimova   +1 more
doaj   +1 more source

Prolonged Luminescence Lifetime of a Dual Emissive Ruthenium Dipyridophenazine-Type Complex in Aprotic and Protic Solvents

open access: yes, 2021
A recently reported ruthenium­(II) complex bearing an extended dipyridophenazine ligand exhibits unusual long-lived dual emission at room temperature. In this study, the effect of the introduction of a methyl protecting group to the imidazole moiety of ...
Sven Rau (1306290)   +9 more
core   +1 more source

Dynamic Fluorescence Modulation via Light‐Driven Competitive Protonation

open access: yesAdvanced Optical Materials, EarlyView.
A two‐component molecular system demonstrates reversible, light‐driven fluorescence write–erase cycling and thermal imaging. Illumination of a merocyanine photoacid transfers a proton to a highly efficient fluorescent pyridinium dye, switching its emission color; thermal relaxation reverses the process in the dark.
Serena X. Liu   +10 more
wiley   +1 more source

The Influence of Chromophore Structure on Intermolecular Interactions. A Study of Selected Rhodamines in Polar Protic and Aprotic Solvents [PDF]

open access: yes, 2020
We have studied the linear optical response and orientational relaxation dynamics of a family of rhodamine dyes in which there is substantial variation in the chromophore structure. For these chromophores, the identity of a substituent at the center ring
J L Dela Cruz, G J Blanchard
core  

Polarity-Dependent Twisted Intramolecular Charge Transfer in Diethylamino Coumarin Revealed by Ultrafast Spectroscopy

open access: yesChemosensors, 2022
Twisting intramolecular charge transfer (TICT) is a common nonradiative relaxation pathway for a molecule with a flexible substituent, effectively reducing the fluorescence quantum yield (FQY) by swift twisting motions.
Jiawei Liu, Cheng Chen, Chong Fang
doaj   +1 more source

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