Results 31 to 40 of about 3,195 (187)

Enhancing Biogenic Formic Acid Production in the Modified OxFA Process by Acetonitrile Addition

Advanced Science, EarlyView.
In this study, the beneficial effect of using acetonitrile as a co‐solvent in the modified OxFA process is shown, outperforming methanol, demonstrating improved reaction kinetics combined with high selectivity for the HPA‐2 (H5PV2Mo10O40) catalyzed oxidation of xylose to FA.
Jan‐Dominik H. Krueger, Pegah Saedi, Maximilian J. Poller, Alberto Collauto, Jason P. Hallett, David Robinson, Maxie M. Roessler, Jakob Albert   +7 more
wiley   +1 more source

Synthesis and fluorosolvatochromism of 3-arylnaphtho[1,2-b]quinolizinium derivatives

Beilstein Journal of Organic Chemistry, 2016
Cationic biaryl derivatives were synthesized by Suzuki–Miyaura coupling of 3-bromonaphtho[1,2-b]quinolizinium bromide with arylboronic acids. The resulting cationic biaryl derivatives exhibit pronounced fluorosolvatochromic properties.
Phil M. Pithan, David Decker, Manlio Sutero Sardo, Giampietro Viola, Heiko Ihmels   +4 more
doaj   +1 more source

The capacitance and electron transfer of 3D-printed graphene electrodes are dramatically influenced by the type of solvent used for pre-treatment

Electrochemistry Communications, 2019
3D-printing (or additive manufacturing) is presently an emerging technology that promises to reshape traditional manufacturing processes. The electrochemistry field can certainly take advantage of this fabrication tool for sensing and energy-related ...
Rui Gusmão, Michelle P. Browne, Zdenek Sofer, Martin Pumera   +3 more
doaj   +1 more source

Interpretable Machine Learning for Solvent‐Dependent Carrier Mobility in Solution‐Processed Organic Thin Films

Advanced Intelligent Discovery, EarlyView.
This work establishes a correlation between solvent properties and the charge transport performance of solution‐processed organic thin films through interpretable machine learning. Strong dispersion interactions (δD), moderate hydrogen bonding (δH), closely matching and compatible with the solute (quadruple thiophene), and a small molar volume (MolVol)
Tianhao Tan, Lian Duan, Dong Wang
wiley   +1 more source

Amino-functionalized polysaccharide derivatives: Synthesis, properties and application

Current Research in Green and Sustainable Chemistry, 2022
Polysaccharides, cellulose and chitin are fundamental structural biopolymers of our biome, they therefore demonstrate relatively high tensile strength compared to other biopolymers and great diversity.
Anwar Jardine
doaj   +1 more source

Shedding Light on Synthetic Autocatalysis: From Conventional Closed‐Shell Chemistries to Overlooked Open‐Shell Occurrences

Chemistry – A European Journal, EarlyView.
Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley   +1 more source

Transitioning Formamide Solvothermal Syntheses of MOFs to Less Toxic Solvents

Chemistry – A European Journal, EarlyView.
Metal‐organic Frameworks (MOFs) are commonly synthesized in toxic formamide solvents. This study investigates the synthetic factors required for effective removal of formamides across various classes of MOFs, providing a foundation for designing new sustainable MOF syntheses.
Julia C. Donovan, Evelyn C. Peterson, Adam J. Matzger   +2 more
wiley   +1 more source

State‐of‐the‐Art and Synthetic Challenges for Hydrosilane Production

Chemistry – A European Journal, EarlyView.
The synthesis of hydrosilanes is currently energy intensive and their recycling is not considered. However, these compounds are important in many industrial fields but also for the valorization of oxygenated waste, towards a circular economy. This review compares the available synthetic routes and highlights the remaining challenges for the production ...
Gabriel Durin, Albane Fontaine, Jean‐Claude Berthet, Thibault Cantat   +3 more
wiley   +1 more source

Cationic Permethylated Cyclodextrins Capable of Self‐Assembling Into Linear Nanostructures in Water

Chemistry – A European Journal, EarlyView.
A quaternary ammonium bridge equipped with a lipophilic substituent in permethylated cyclodextrins suppresses undesired supramolecular interactions and promotes controlled, directional head‐to‐tail self‐assembly into well‐defined linear nanostructures.
Maxime Kolb, Marvin Benjaffel, Peter Faller, Laurent Raibaut, Dominique Armspach   +4 more
wiley   +1 more source

The comparative study of linear solvatation energy relationship for the reactivity of pyridine carboxylic acids with diazodiphenylmethane in protic and aprotic solvents [PDF]

Journal of the Serbian Chemical Society, 2012
Protic and aprotic solvent effects on the reactivity of picolinic, nicotinic and isonicotinic acid, as well as of some substituted nicotinic acids with diazodiphenylmethane (DDM) were investigated.
Drmanić Saša Ž., Nikolić Jasmina B., Marinković Aleksandar D., Jovanović Bratislav Ž.   +3 more
doaj   +1 more source