Results 11 to 20 of about 10,994 (228)

Investigations of the reactivity of pyridine carboxylic acids with diazodiphenylmethane in protic and aprotic solvents, Part I: Pyridine mono-carboxylic acids [PDF]

open access: yesJournal of the Serbian Chemical Society, 2005
Rate constants for the reaction of diazodiphenylmethane with isomeric pyridine carboxylic acids were determined in chosen protic and aprotic solvents at 30 °C, using the well known UV spectrophotometric method.
Marinković Aleksandar D.   +3 more
doaj   +1 more source

Post-modification of PLLA nanofiber nonwovens by various solvent treatments

open access: yesCurrent Directions in Biomedical Engineering, 2023
Degradable polymeric Biomaterials, such as polylactic acid, are widely used in medical field as bioresorbable implant coatings. More recently, stent covers, implantable tubes or wound dressings made from electrospun nanofibers have been developed.
Götz Andreas   +4 more
doaj   +1 more source

Elucidating the Solvent-Dependent Solvation and Structural Stability of Irinotecan: A Molecular Simulation Study. [PDF]

open access: yesChemphyschem
The solvation preference of irinotecan is governed by a competition between cavity formation and electrostatic stabilization. Computations reveal that the high cost of breaking water's hydrogen bond network outweighs its electrostatic benefits. In contrast, polar aprotic solvents (e.g., pyridine) offer an optimal thermodynamic balance, providing strong
Bitabo MM   +4 more
europepmc   +2 more sources

Solvent effect on electronic absorption spectra of some 2-aminobenzimidazoles [PDF]

open access: yesActa Periodica Technologica, 2002
The effect of protic and aprotic solvents on electronic apsorption spectra of 1-(3-X-benzil)-2-aminobenzimidazoles (X=CH3;OCH3; Cl) was examined. UV-apsorption spectra (200-400 nm) were recorded in five protic and four aprotic solvents. Batochromic shift
Perušić-Janjić Nada U.   +2 more
doaj   +1 more source

Effects of solvent and structure on the reactivity of 6-substituted nicotinic acids with diazodiphenylmethane in aprotic solvents [PDF]

open access: yesJournal of the Serbian Chemical Society, 2009
The rate constants for the reactions of diazodiphenylmethane (DDM) with 6-substituted nicotinic acids in aprotic solvents at 30°C were determined. The obtained second order rate constants in aprotic solvents, together with literature data for benzoic and
Drmanić Saša Ž.   +2 more
doaj   +3 more sources

The Role of Solvent on the Kinetics and Mechanism of the Hydrolysis of Salicylidene Benzoyl Hydrazone [PDF]

open access: yesمجلة جامعة النجاح للأبحاث العلوم الطبيعية, 1988
The effect of various solvents on the kinetics and mechanism of the hydrolysis of Salicylidene Benzoyl hydrazone (SBH) has been studied at five different temperatures (17-45 C) using U.V. and visible spectrophotometry. In both protic and aprotic solvents,
Maher Abu-Eid
doaj   +1 more source

Poly(Pyridinium Salt)s Containing 2,7-Diamino-9,9′-Dioctylfluorene Moieties with Various Organic Counterions Exhibiting Both Lyotropic Liquid-Crystalline and Light-Emitting Properties

open access: yesMolecules, 2021
A series of poly(pyridinium salt)s-fluorene main-chain ionic polymers with various organic counterions were synthesized by using ring-transmutation polymerization and metathesis reactions. Their chemical structures were characterized by Fourier Transform
Pradip K. Bhowmik   +8 more
doaj   +1 more source

Ultrafast Intramolecular Charge Transfer of Formyl Perylene Observed Using Femtosecond Transient Absorption Spectroscopy [PDF]

open access: yes, 2010
The excited-state photophysics of formylperylene (FPe) have been investigated in a series of nonpolar, polar aprotic, and polar protic solvents. A variety of experimental and theoretical methods were employed including femtosecond transient absorption (
Mohammed, Omar F.
core   +1 more source

Facile Synthesis of Functionalized Phenoxy Quinolines: Antibacterial Activities against ESBL Producing Escherichia coli and MRSA, Docking Studies, and Structural Features Determination through Computational Approach

open access: yesMolecules, 2022
The synthesis of new 6-Bromoquinolin-4-ol derivatives (3a–3h) by Chan–Lam coupling utilizing different types of solvents (protic, aprotic, and mixed solvents) and bases was studied in the present manuscript.
Mahwish Arshad   +4 more
doaj   +1 more source

Conformational Preferences of 3-(Dimethylazinoyl)propanoic Acid as a Function of pH and Solvent; Intermolecular versus Intramolecular Hydrogen Bonding [PDF]

open access: yes, 2009
The conformational equilibrium of 3-(dimethylazinoyl)propanoic acid (DMAPA, azinoyl = N^+(O^−) has a weak pH-dependence in D_2O, with a slight preference for trans in alkaline solutions.
Alley, Olivia J.   +5 more
core   +2 more sources

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