Results 111 to 120 of about 8,250 (257)

Role of High Fidelity Vs. Low Fidelity Experimental Data in Machine Learning Model Performance for Predicting Polymer Solubility

open access: yesMacromolecular Rapid Communications, EarlyView.
The performance of machine learning models for classifying polymer solubility improves when a high‐fidelity experimental dataset is used compared to a low‐fidelity experimental dataset. This has important implications for justifying the value of spending additional time and resources preparing detailed experimental datasets.
Mona Amrihesari   +3 more
wiley   +1 more source

A PLP‐SEC Investigation of Di(Ethylene Glycol) Methyl Ether Methacrylate Radical Polymerization Propagation Kinetics in Solution

open access: yesMacromolecular Reaction Engineering, EarlyView.
The propagation rate coefficient of di(ethylene glycol) methyl ether methacrylate exhibits the same temperature dependency but is a factor of 12 higher in aqueous solution compared to bulk. Smaller increases are observed in ethanol and ethanol/water mixtures, with the value of the rate coefficient decreasing as the monomer concentration in solution is ...
Fatemeh Salarhosseini   +1 more
wiley   +1 more source

Bimetallic M2B Boride Nanoparticles: A Robust and Recyclable Platform for Dehydration‐Driven Condensation of Aldehydes

open access: yesChemistryOpen, EarlyView.
Metal borides (MBs) emerge as a versatile class of nanomaterials, featuring high stability and bifunctional Lewis‐acidic/basic active sites. Despite these properties, their applications in CN bond formation are less explored. Herein, we report the first systematic use of M2B‐type boride nanoparticles as efficient and magnetically recoverable catalysts
Akram Ashouri   +6 more
wiley   +1 more source

A green solvent processable, self‐doped N‐annulated perylene butyl tetraester applied as a solar cell cathode interlayer

open access: yesPolymer International, EarlyView.
A new organic molecular cathode interlayer is presented built upon the perylene butyl tetraester scaffold. The new molecule incorporates N‐annulation and a functional amine group to control optical, electrochemical and physical properties and delivers excellent solar cell performance. Abstract We report a new amino‐bay‐substituted, N‐annulated perylene
Kathryn M Wolfe   +7 more
wiley   +1 more source

Potassium‐Doped Borophane Nanosheets: A Multifunctional Platform for Reversible Hydrogen Storage and Metal‐Free Hydrogen Transfer

open access: yesSmall, EarlyView.
Borophane in dual roles: as a reductant in the conversion of levulinic acid to γ‐valerolactone and as a reversible hydrogen reservoir through partial rehydrogenation. ABSTRACT 2D borophene has long been proposed as a promising hydrogen storage material, but experimental demonstrations remain limited to boron hydride sheets derived from MgB2.
Rajamohanan Sobhana Anju   +12 more
wiley   +1 more source

Engineering Proton Conductive Metal–Organic Glasses Through Secondary Network Formers

open access: yesSmall, EarlyView.
Incorporating secondary network formers enables access to metal–organic glass with tunable structures and properties. This strategy allows systematic control over key metrics, including anhydrous proton conductivities up to 2.6 mS cm−1 at 150°C, a linear increase in glass transition temperature from 11.0°C to 57.4°C, and more than a 200‐fold increase ...
Nattapol Ma   +3 more
wiley   +1 more source

Self‐Assembled Nanostructured Microgels with Reconfigurable Morphologies

open access: yesSmall, EarlyView.
This work presents bent‐core amphiphiles that self‐assemble into fibrillar, tubular, and helical nanofiber‐like nanostructures, forming organogels that can be emulsified into water as nanostructured microgels. These droplets preserve internal architectures and, when combined with fluorocarbon oils, yield multicompartment emulsions with dynamically ...
Cristina Álvarez‐Solana   +2 more
wiley   +1 more source

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