Results 121 to 130 of about 26,157 (280)

Structural Design of MOF‐Based and MOF‐Derived Composites for Oxygen Evolution Electrocatalysis: Materials Innovation for Energy and Environmental Sustainability

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This review provides an overview of recent developments in metal organic framework (MOF)‐based and MOF‐derived composites for efficient oxygen evolution reaction. This review also emphasizes the structural design of electrocatalyst, active site optimization, and emerging prospects of their use in practical electrolyzer systems.
Bhagyashri B. Kamble   +7 more
wiley   +1 more source

Organic–Inorganic Composite Nanofibers Based on YSZ Nanofibers Anchored PANI/SnS2 Heterojunction for Flexible Room Temperature NO2 Sensor

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A novel organic–inorganic YSZ@PANI/SnS2 composite nanofiber film was prepared via an in‐situ construction strategy of a PANI interfacial layer. The biomimetic "branch‐leaf" structure effectively disperses and releases stress and energy, while accelerating gas diffusion/transport and providing abundant active sites.
Han Zhang   +7 more
wiley   +1 more source

Expanded Scorpionate and Siderophore‐Inspired Ligands: From Foundational Designs to Modern Applications

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
The concept of scorpionate ligands has evolved significantly since the introduction of tris(pyrazolyl)borate. By integrating a biological supramolecular ligand scaffold with the classic scorpionate architecture, researchers have made notable strides in mimicking the active sites of nitrogenase and advancing homogeneous catalysis.
Austin Winfield Medley   +1 more
wiley   +1 more source

Kinetics and thermodynamics of the reversible solvation of 2, 3-butanedione [PDF]

open access: yes, 2019
En este trabajo se realiza un estudio de la adición reversible de agua y metanol a 2 ,3-butanodiona. Los valores de ΛH y ΛS de adición de agua y metanol son muy similares.
Lissi, E. A., Vargas, N.
core   +1 more source

Design and Synthesis of Lactose‐Derived Ligands and Their Application in Asymmetric Friedel–Crafts Alkylation

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
This work describes the synthesis of lactose‐ and glucose‐derived chiral ligands and their application in the catalytic enantioselective Friedel–Crafts alkylation of indole with a series of trans‐β‐nitrostyrenes. The optimal ligand was an acetate protected, lactose‐derived pyridyl imine and its zinc complex afforded ees up to 93% and yields up to 93 ...
Sandra Bulawa   +2 more
wiley   +1 more source

A Direct Method to Prepare Zwitterionic Organotrifluoroborates: Ammonium and Sulfonium Derivatives

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Organotrifluoroborates find applications in synthesis, diagnostics, and theranostics. This study outlines a one‐step reaction for producing ammonium and sulfonium trifluoroborate zwitterion derivatives. This method achieves satisfactory yields without the need for expensive reagents.
Vanessa Re   +6 more
wiley   +1 more source

1,2,6‐Thiadiazin‐4‐ones: Robust Photocatalysts for the Green Aerobic Oxidation of Sulfides to Sulfoxides

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
A new photocatalyst for the aerobic photochemical oxidation of sulfides to sulfoxides is described under really low catalyst loading (0.01 mol%) and methanol as the green solvent. The chemoselective oxidation of sulfides to sulfoxides is accomplished using a new family of photocatalysts, namely 1,2,6‐thiadiazin‐4‐ones. Utilizing a low catalyst loading (
Charikleia I. Karaousta   +6 more
wiley   +1 more source

SOLVATOCHROMISM OF ASYMMETRICAL SUBSTITUTED 3,7-DIAMINOPHENOTHIAZINIUM DYE

open access: yesStudia Universitatis Babes-Bolyai Chemia, 2015
A convenient procedure for the synthesis of 3-diethylamino-7-phenylaminophenothiazin-5-ium iodide was developed and the solvatochromism of this blue dye was examined by means of UV-Vis spectroscopy.
Camelia CIOBOTARIU   +2 more
doaj  

Divergent Synthesis of Polycyclic Derivatives via Gold Catalysis

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Gold(I)‐catalyzed cycloisomerization enables the formation of complex 3D structures from simple enyne precursors. This study presents a divergent strategy to synthesize functionalized bicyclic and tricyclic scaffolds from a common alkynyl ketone.
Emilie Gentilini   +4 more
wiley   +1 more source

Edible coatings in food: Specific materials and their impact on techno‐functional properties and sustainable applications

open access: yesFood Biomacromolecules, EarlyView.
Abstract Edible coatings have emerged as a significant advancement in the food industry. This review explains the different materials, methods, and applications of edible coatings, with a special focus on the integration of nanotechnology and its contribution to the circular economy.
Shankar Senthilkumar   +4 more
wiley   +1 more source

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