Results 131 to 140 of about 26,157 (280)

Memory of Chirality in Radical Addition–Translocation–Cyclization Cascades

Helvetica Chimica Acta, EarlyView.
Radical addition–translocation–cyclization cascades of chiral alkynes show striking memory of chirality (MoC), with strong retention of configuration when fast, polarity favored cyclization are involved. The most effective system employs a highly electron‐poor pentafluorobenzenesulfonyl group.
Christian Simon Gloor, Fabrice Dénès, Valentin Soulard, Philippe Renaud   +3 more
wiley   +1 more source

Heterogeneous Catalyst Design Principles for the Conversion of Lignin into High Value Commodity Fuels and Chemicals [PDF]

, 2020
Chorkendorff I., L′udmila H., Wyman C. E., Wyman C. E.   +3 more
core   +1 more source

Mapping the Adolescent Mind: Profiles of Reflective Functioning and Epistemic Trust in Adolescent Psychopathology

Journal of Adolescence, EarlyView.
ABSTRACT Introduction Adolescence is a period of heightened vulnerability to psychopathology, when capacities for mentalising and interpersonal trust develop rapidly. This study investigated how configurations of reflective functioning (RF) and epistemic trust (ET) differentiate patterns of internalizing and externalizing problems in youth.
Ilaria Maria Antonietta Benzi, Nick Midgley, Karin Ensink, Laura Parolin, Peter Fonagy, Francesca Locati   +5 more
wiley   +1 more source

Synthesis, crystal structure and physico-chemical properties of 3,3’-[(4-hydroxyphenyl)methyl] bis-(4-hydroxy-2H-chromen-2-one)

Acta Chimica Slovenica, 2014
The compound 3,3’-[(4-Hydroxyphenyl)methyl]bis-(4-hydroxy-2H-chromen-2-one) was synthesized by the Knoevenagel reaction. Crystals, suitable for X-ray data collection were grown by slow evaporation from an ethanol solution.
Denitsa Elenkova, Bernd Morgenstern, Ilia Manolov, Maria Milanova   +3 more
doaj  

Role of High Fidelity Vs. Low Fidelity Experimental Data in Machine Learning Model Performance for Predicting Polymer Solubility

Macromolecular Rapid Communications, EarlyView.
The performance of machine learning models for classifying polymer solubility improves when a high‐fidelity experimental dataset is used compared to a low‐fidelity experimental dataset. This has important implications for justifying the value of spending additional time and resources preparing detailed experimental datasets.
Mona Amrihesari, Manali Banerjee, Raul Olmedo, Blair Brettmann   +3 more
wiley   +1 more source

Metathesis‐Sourced Epoxides in Ring‐Opening Copolymerization: Selective Access to Degradable Polythioesters

Macromolecular Rapid Communications, EarlyView.
Metathesis‐derived cyclopentene epoxides enable strictly alternating, scrambling‐free ring‐opening copolymerization with phthalic thioanhydride, yielding well‐defined polythioesters with molecular weights up to ∼38 kg/mol. Their performance extends to oxygen‐based anhydrides and selective terpolymerizations. Direct comparisons with all‐oxygen analogues
Niracha Tangyen, Bhargav R. Manjunatha, Valerio D'Elia, Alex J. Plajer   +3 more
wiley   +1 more source

A PLP‐SEC Investigation of Di(Ethylene Glycol) Methyl Ether Methacrylate Radical Polymerization Propagation Kinetics in Solution

Macromolecular Reaction Engineering, EarlyView.
The propagation rate coefficient of di(ethylene glycol) methyl ether methacrylate exhibits the same temperature dependency but is a factor of 12 higher in aqueous solution compared to bulk. Smaller increases are observed in ethanol and ethanol/water mixtures, with the value of the rate coefficient decreasing as the monomer concentration in solution is ...
Fatemeh Salarhosseini, Robin A. Hutchinson   +1 more
wiley   +1 more source

A green solvent processable, self‐doped N‐annulated perylene butyl tetraester applied as a solar cell cathode interlayer

Polymer International, EarlyView.
A new organic molecular cathode interlayer is presented built upon the perylene butyl tetraester scaffold. The new molecule incorporates N‐annulation and a functional amine group to control optical, electrochemical and physical properties and delivers excellent solar cell performance. Abstract We report a new amino‐bay‐substituted, N‐annulated perylene
Kathryn M Wolfe, Shahidul Alam, Zachary T Gardner, Biswajit Pal, Alexander Harrison, Frédéric Laquai, Chad Risko, Gregory C Welch   +7 more
wiley   +1 more source

Tape Casting of LLZO Ceramic Separators: An Overview of Challenges, Optimization Strategies, and Paths to Industrial Implementation. [PDF]

ChemSusChem
Tape casting is a cost‐effective process for the scalable and continuous production of thin layers from ceramic powders. In recent years, interest in the use of tape casting for the production of solid‐state battery components such as ceramic separators, ceramic cathodes, or complete cells has grown significantly.
Touidjine K, Ye R, Finsterbusch-Rosen M, Lang A, Finsterbusch M, Fattakhova-Rohlfing D.   +5 more
europepmc   +2 more sources

Nickel Foam Electrodes—A Versatile, Powerful, and Readily Available Tool in Electro‐Organic Synthesis

The Chemical Record, EarlyView.
Nickel foam—one material, two faces, and several versatile roles depending on electrolytic conditions. For more than 50 years, nickel foam electrodes have served in electrosynthesis as powerful and readily available electrode materials. Due to their inexpensive nature and easy handling, they have been widely employed.
Rok Narobe, Johannes Schneider, Siegfried R. Waldvogel   +2 more
wiley   +1 more source