Results 131 to 140 of about 10,338 (283)

Pulse Programme Considerations for Quantitative NOE Analysis

open access: yesMagnetic Resonance in Chemistry, EarlyView.
NOESY and ROESY spectra are frequently used to obtain interatomic distances in solution. Here, the performance of six routinely used pulse programmes is evaluated, with the number of quantified correlations and the accuracy of the NOE‐based distances being used as the main assessment criteria. ABSTRACT Accurate NOE/ROE‐based distance determination is a
Lianne H. E. Wieske   +2 more
wiley   +1 more source

Studies On the Solvent Effect of a Dipolar Protic Solvent On the Biochemicalpotential Of Methanoates

open access: yes
The solvent effect of ethanol (dipolar protic solvent) on the acid catalysed solvolysis of Propyl methanoate was studied by carrying out the hydrolysis of the ester in water-ethanol (EtOH) media of varying composition consisting of 20% to 80%(v/v) at different temperatures ranging from 20 to 40°C.
openaire   +1 more source

Interaction With Surface Spins as a Contribution to Nuclear Magnetic Relaxation of Liquids Adsorbed in Mesoporous Materials

open access: yesMagnetic Resonance in Chemistry, EarlyView.
Liquids at silica interfaces experience demixing as a consequence of their respective polarity. The distribution of liquids and their primary relaxation contributions are studied by surface modification with OD and radical moieties, respectively. ABSTRACT NMR relaxation of liquids in the presence of solid interfaces, such as silica gel or porous glass,
Carlos Mattea   +3 more
wiley   +1 more source

Effect of protic solvent on pyrolysis of sulfimides.

open access: yesNIPPON KAGAKU KAISHI, 1987
Eiichi TSUKURIMICHI   +2 more
openaire   +2 more sources

A PLP‐SEC Investigation of Di(Ethylene Glycol) Methyl Ether Methacrylate Radical Polymerization Propagation Kinetics in Solution

open access: yesMacromolecular Reaction Engineering, EarlyView.
The propagation rate coefficient of di(ethylene glycol) methyl ether methacrylate exhibits the same temperature dependency but is a factor of 12 higher in aqueous solution compared to bulk. Smaller increases are observed in ethanol and ethanol/water mixtures, with the value of the rate coefficient decreasing as the monomer concentration in solution is ...
Fatemeh Salarhosseini   +1 more
wiley   +1 more source

A green solvent processable, self‐doped N‐annulated perylene butyl tetraester applied as a solar cell cathode interlayer

open access: yesPolymer International, EarlyView.
A new organic molecular cathode interlayer is presented built upon the perylene butyl tetraester scaffold. The new molecule incorporates N‐annulation and a functional amine group to control optical, electrochemical and physical properties and delivers excellent solar cell performance. Abstract We report a new amino‐bay‐substituted, N‐annulated perylene
Kathryn M Wolfe   +7 more
wiley   +1 more source

Unspecific Molecular Adsorption (UMA) Sample Preparation Method for Bottom‐up and Whole Protein Analysis: The Foundation

open access: yesPROTEOMICS, EarlyView.
ABSTRACT The protein sample preparation methods for shotgun proteomics are nowadays well‐established unlike the ones for whole protein analysis. The goal of my work has been to create a simple methodology which provides a single uncomplicated sample preparation tool for these two fields. Nowadays the bulk of proteomics work is done using detergents for
Alexandre Zougman
wiley   +1 more source

Dynamic Polydisulfide Latex via Emulsion Ring‐Opening Polymerization of Cyclodisulfides

open access: yesJournal of Polymer Science, EarlyView.
A polydisulfide latex with a high molar mass was achieved by emulsion polymerization process starting from a dithiol. The mechanism reveals an entropy‐driven ring‐opening polymerization involving disulfide macrocycle intermediates. The polydisulfide particles can be degraded by thiol‐disulfide exchange, and the disulfide fragments can be reengaged in a
Sandric Afonso   +5 more
wiley   +1 more source

Sodium‐Based Battery Component Design: Imitating Lithium or Forging New Paths?

open access: yesSmall, EarlyView.
This Perspective elucidates the decisive yet underexplored impact of cation chemistry, Na+ vs. Li+ charge carriers, on the design, selection, and formulation of their corresponding battery systems, addressing common misconceptions and the pitfalls of overreliance on Li+ design principles. Leveraging the unique characteristics of Na+, it comprehensively
Xingxing Wang   +13 more
wiley   +1 more source

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