Spectroscopic, electrochemical, thermodynamic and theoretical insights into solvent effects for the intensification of the modified OxFA process. [PDF]
Krueger JH +7 more
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Identification of Au-hydrides as key intermediates in the reduction of Au(iii) prodrugs to active Au(i) species under protic conditions. [PDF]
Ochs J, Metzler-Nolte N.
europepmc +1 more source
A Promising Strategy for Solvent-Regulated Selective Hydrogenation of 5-Hydroxymethylfurfural over Porous Carbon-Supported Ni-ZnO Nanoparticles. [PDF]
Huang R +6 more
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The Relationship Between Catalyst and Solvent in Hydrogenation via Condensed Phase Heterogeneous Catalysis. [PDF]
Floyd JB +3 more
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Tuning CO<sub>2</sub> Absorption in Hydrophobic Protic Ionic Liquids via Temperature and Structure. [PDF]
Mazlan NAM +4 more
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Solvatochromic and Computational Study of Three Benzo-[f]-Quinolinium Methylids with Photoinduced Charge Transfer. [PDF]
Avadanei MI, Avadanei OG, Dorohoi DO.
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Proton solvation in protic and aprotic solvents
Journal of Computational Chemistry, 2016Protonation pattern strongly affects the properties of molecular systems. To determine protonation equilibria, proton solvation free energy, which is a central quantity in solution chemistry, needs to be known. In this study, proton affinities (PAs), electrostatic energies of solvation, and pKA values were computed in protic and aprotic solvents.
Ernst-Walter Knapp
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Hydrogen-Bonded Encapsulation Complexes in Protic Solvents
Journal of the American Chemical Society, 2004We describe here the behavior of the hydrogen-bonded capsule 1.1 and its complexes in protic solvents. The kinetics and thermodynamics of the encapsulation process were determined through conventional (1)H NMR methods. The enthalpies and entropies of encapsulation are both positive, indicating a process that liberates solvent molecules.
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