Results 31 to 40 of about 18,999 (260)

Determination of proton-proton coupling constants in 13C-labeled molecules

open access: yesJournal of Magnetic Resonance (1969), 1992
Pulse sequences that rely on heteronuclear one-bond couplings like ‘J(H, C) and ‘J( C, C) couplings are among the most sensitive correlation experiments available in high-resolution NMR of biological macromolecules. Therefore it is desirable to extract NMR parameters such as coupling constants from such experiments.
Griesinger, Christian, EGGENBERGER, U.
openaire   +2 more sources

Identification of the plant mitochondrial OrfX protein: A mass spectrometry approach

open access: yesFEBS Letters, EarlyView.
The mitochondrial genome of plants contains an open reading frame, orfx, which encodes a rare protein that has so far escaped mass spectrometric detection. The protein resembles the c‐subunit of bacterial twin‐arginine‐motif‐dependent protein translocases (TatC).
Matthias Döring   +3 more
wiley   +1 more source

Polarization‐resolved femtosecond Vis/IR spectroscopy tailored for resolving weak signals in biological samples using minimal sample volume

open access: yesFEBS Open Bio, EarlyView.
Unique biological samples, such as site‐specific mutant proteins, are available only in limited quantities. Here, we present a polarization‐resolved transient infrared spectroscopy setup with referencing to improve signal‐to‐noise tailored towards tracing small signals. We provide an overview of characterizing the excitation conditions for polarization‐
Clark Zahn, Karsten Heyne
wiley   +1 more source

Synthesis and Protonation Constants of an Amide-Based Chelating Cyclophane

open access: yesMolbank, 2006
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Julio Cesar Altamirano-Coronado   +2 more
doaj   +1 more source

Determination of intrinsic equilibrium constants at alumina/electrolyte interface [PDF]

open access: yesJournal of the Serbian Chemical Society, 2004
Intrinsic ionization and complexation constants at an alumina/electrolyte interface were studied by the site binding model, while the sorption of alkali cations from aqueous solutions was interpreted by the triple-layer model.
Todorović Žaklina N.   +1 more
doaj   +1 more source

Molecular dynamics simulations of positively selected codons in FcγRI reveal novel biochemical binding properties

open access: yesFEBS Open Bio, EarlyView.
Evolutionary analysis across 32 placental mammals identified positive selection at residues H148 and W149 in the immune receptor FcγR1. Ancestral reconstruction combined with molecular dynamics simulations reveals how these mutations may influence receptor structure and dynamics, providing insight into the evolution of antibody recognition and immune ...
David A. Young   +7 more
wiley   +1 more source

A Comprehensive Equilibrium Analysis of Tartronate with Proton and Major Cations in Natural Fluids

open access: yesMolecules
This study presents a detailed thermodynamic investigation on the protonation behavior of tartronic acid in aqueous solutions of various ionic media, including sodium chloride, potassium chloride, tetramethylammonium chloride, and tetraethylammonium ...
Gabriele Lando   +5 more
doaj   +1 more source

Comparison and thermodynamic studies on complexation of adrenaline with some metal ions in mixed solvents

open access: yesMain Group Metal Chemistry, 2012
Two methods are described for the determination of stability constants of adrenaline with metal ions. In method A, the solution equilibria of Al(III) complex formed with bidentate ligand of adrenaline in acidic media at pH ranges of ≈3 to ≈5 have been ...
Gh Azar Bagheri, Gangtalab Masome
doaj   +1 more source

A yeast model of 5‐oxoproline accumulation reveals a general toleration to 5‐oxoproline

open access: yesFEBS Open Bio, EarlyView.
Using a yeast model, we show that even high accumulation of 5‐oxoproline causes only mild cellular stress and does not trigger oxidative stress. Instead, cells adapt by activating efflux pumps and diverse protective pathways, suggesting that previously proposed harmful effects of 5‐oxoproline may arise from indirect metabolic imbalances rather than the
Pratiksha Dubey   +4 more
wiley   +1 more source

Determination of protonation constants of some 3-alkyl(aryl)-4-(p-t-butyl(benzyl/benzyliden)amino)-4,5-dihydro-1H-1,2,4-triazole-5-one derivatives in ethanol-water mixtures

open access: yesBulletin of the Chemical Society of Ethiopia, 2010
Stoichiometric protonation constants of some 3-alkyl(aryl)-4-(p-t-butyl(benzyl/benzyliden)amino)-4,5-dihydro-1H-1,2,4-triazole-5-one derivatives were determined potentiometrically in 50% (v/v) ethanol-water mixtures at 25 oC with an ionic strength of 0 ...
Fatih İslamoğlu   +3 more
doaj  

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