Results 41 to 50 of about 18,999 (260)

Potentiometry, Effect of Solvent and Thermodynamics of Novel Carbohydrazone and Its Transition Metal(II) Complexes

open access: yesInternational Journal of Electrochemical Science, 2019
The ligand (2E,2'E)-2,2'-(carbonylbis(hydrazine-2-yl-1-ylidene))dipropionic acid (CBHP) had been synthesized and characterized using different tools of analysis.
Ahmed A. El-Sherif   +3 more
doaj   +1 more source

Protolytic equlibria of bromazepam [PDF]

open access: yesJournal of the Serbian Chemical Society, 2002
The protolytic equilibria of bromazepam, an ampholyte sparingly soluble in water, in homogeneous and heterogeneous systems were studied in the pH range 0–14 at 25ºC and at ionic strength of 0.1 mol/dm3 (NaCl).
Pfendt Lidija B.   +3 more
doaj   +1 more source

Molecular characterization of covRS mutations in M1UK Streptococcus pyogenes

open access: yesFEBS Open Bio, EarlyView.
Group A Streptococcus (GAS) acquires covRS mutations driving a hypervirulent bacterial state, frequently associated with invasive disease‐like necrotizing fasciitis. We demonstrate that the newly emerged M1UK GAS lineage can also acquire these mutations.
Jarrad Pritchard   +12 more
wiley   +1 more source

Formation Constants of Protonated Amidinothiourea

open access: yes, 1967
The reactions of amidinothiourea NH2 -(S=) C-NH-C (=NH).NH2 with metal ions1 and their analytical applications2-5 are reported in the literature, but the protons-tion of amidinothiourea has not yet been investigated. The protonation reaction may be represented as follows: B + H+ \(\rightleftharpoons\) BH+ BH++ H+ \(\rightleftharpoons\) \(BH^{++}_2 ...
R. A Nadkarni, B. C. Haldar
openaire   +2 more sources

Identifying and characterising a plant GH1 β‐glucosidase that exhibits hydrolytic activity on N‐linked glucopyranoside

open access: yesFEBS Open Bio, EarlyView.
We report the first β‐glucosidase with demonstrated hydrolytic activity on an N‐linked glycopyranoside. The enzyme, native to maize, was biochemically characterised for this novel reaction, and structural modelling of the enzyme–substrate complex revealed several clues to the underlying reduced catalytic rate relative to its native O‐glycopyranoside ...
Hani Gharabli   +3 more
wiley   +1 more source

Halkalı Alkil Tiyofen-Schiff Bazlarının Protonlanma ve Bunların Ni(II) İyonu ile Kompleks Oluşum Sabitlerinin Belirlenmesi

open access: yesSüleyman Demirel Üniversitesi Fen-Edebiyat Fakültesi Fen Dergisi, 2011
Özet: Halkalı alkil tiyofen-Schiff bazların protonlanma ve bunların Ni(II) iyonu ile olan komplekslerinin kararlılık sabitleri %50 etil alkol-su (v/v) ortamında, potansiyometrik titrasyon yöntemi ile tayin edildi.
Nurşen Sarı   +2 more
doaj  

Structural studies and functional engineering of NanX: an anhydro‐sialic acid transporter from Escherichia coli

open access: yesFEBS Open Bio, EarlyView.
Biophysical characterisation shows that NanX, a membrane transport protein from the major facilitator superfamily (MFS), forms both monomers and dimers after purification. AlphaFold modelling and substrate docking provide information on residues likely involved in substrate recognition for NanX and another MFS member, NanT.
Michael C. Newton‐Vesty   +13 more
wiley   +1 more source

Thermodynamic Properties of Some Lanthanide Metal Ion Complexes of Newly Mono- and Dioximes in Dioxan-water mixtures

open access: yesInternational Journal of Electrochemical Science, 2015
The protonation constants of monoxime HL1 and dioxime H2L2, derived from 1-(o-hydroxybenzoyl)propane-1,2-dione were determined by pH-metric method. The stability constants of their complexes with a series of lanthanide metal ions increase in the order of
Aisha I. Mosa   +3 more
doaj   +1 more source

Superlubricity and Corrosion Inhibition Properties of Solvate Ionic Liquids in Hybrid Carbon Fiber Reinforced Plastic–Steel Interfaces

open access: yesAdvanced Engineering Materials, EarlyView.
Solvate ionic liquids lubrication reduced the coefficient of friction by ∼60% compared to dry sliding, reaching steady‐state values as low as 0.04–0.05. Corrosion weight‐loss measurements in 1 M HCl further demonstrated significant inhibition behavior, with only 100 ppm of [Li(G3)][TFSI] (∼68.5 μL/L) reducing corrosion‐product weight loss by 63 ...
Sameh Dabees   +6 more
wiley   +1 more source

Potentiometric Determination of Phytic Acid and Investigations of Phytate Interactions with Some Metal Ions

open access: yesActa Chimica Slovenica, 2015
Determination of correct amount (concentration) of phytic acid is of vital importance when dealing with protonation and/or metal complexation equilibria.
Gregor Marolt, Boris Pihlar
doaj   +1 more source

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