Results 31 to 40 of about 5,053 (175)
Modeling Pyran Formation in the Molybdenum Cofactor: Protonation of Quinoxalyl–Dithiolene Promoting Pyran Cyclization [PDF]
Inorganic Chemistry, 2019 Mononuclear Mo and W enzymes require a unique ligand known as molybdopterin (MPT). This ligand binds the metal through a dithiolene chelate, and the dithiolene bridges a reduced pyranopterin group. Pyran scission and formation have been proposed as a reaction of the MPT ligand that may occur within the enzymes to adjust reactivity at the Mo atom.
Douglas R. Gisewhite +4 more
openaire +2 more sources
On the Regioselectivity of the Nickel-Catalyzed Insertion of Alkynes into the Carbon-Carbon Bond of Oxetan-3-one [PDF]
, 2017 The study of the regioselectivity of insertion of unsymmetrical alkynes into the carbon–carbon bond of oxetan-3-one in the presence of a nickel catalyst has revealed a strong directing effect of a 2-thienyl substituent.
Aissa, Christophe +6 more
core +1 more source
ChemistryOpen, EarlyView.This study employed density functional theory (DFT) and conceptual DFT (CDFT) to calculate the structures and properties of potential antibacterial compounds derived from 16‐membered lactone ring‐containing secondary metabolites of extremophiles, as well as midecamycin.
Dilong Li +6 more
wiley +1 more source
ChemistryOpen, EarlyView.In organic synthesis, deep eutectic solvents (DES) have demonstrated their ability to be used as reaction media for the development of reactions in line with green chemistry principles. This review presents an overview of microwave‐assisted organic synthesis in DES, highlighting the diversity of uses for these solvents, their role in mechanisms, the ...
Pierre‐Olivier Delaye +2 more
wiley +1 more source
To better understand the formation of short-chain acids in combustion systems [PDF]
, 2008 International audienceOur study aims at a better control and understanding of the transfer of a complex [DNA supercoiled plasmid - dodecyltrimethylammonium surfactant] layer from a liquid-vapour water interface onto a silicon surface without any ...
Battin-Leclerc, Frédérique +3 more
core +7 more sources
The continuing significance of chiral agrochemicals
Pest Management Science, Volume 81, Issue 4, Page 1697-1716, April 2025.In the time frame 2018–2023, around 43% of the 35 chiral agrochemicals introduced to the market (herbicides, fungicides, insecticides, acaricides, and nematicides) contain one or more stereogenic centers in the molecule, and almost 69% of them have been marketed as racemic mixtures of enantiomers or stereoisomers.
Peter Jeschke
wiley +1 more source
Materials modeling and development for use in double-exposure lithography applications [PDF]
, 2009 The current optical photolithography technology is approaching the physical barrier to the minimum achievable feature size. To produce smaller devices, new resolution enhancement technologies must be developed.
Byers, Jeffrey +5 more
core +2 more sources
Small Science, EarlyView.The bimetallic ceria‐zinc nanoflowers coated with polypyrrole and loaded with methylene blue disrupt methicillin‐resistant Staphylococcus aureus biofilms synergistically, promote angiogenesis, thereby achieving efficient diabetic wound healing. Integrated photothermal therapy optimized, photodynamic therapy enhanced, pH‐mediated multifunctional ...
Prafful P. Kothari +3 more
wiley +1 more source
Development of fast switching photochromic coatings on transparent plastics and glass [PDF]
, 1999 A new photochromic organic-inorganic nanocomposite (Nanomer(R)) coating system has been developed. It is based on an epoxysilane as network former, an organic bisepoxide as spacer, an organic amine as thermal cross-linker and surface modified SiO2 ...
Fries, Kira +3 more
core +2 more sources
Plant Biotechnology Journal, EarlyView.ABSTRACT Iron (Fe) is an essential micronutrient for plant growth and development. Rhizosphere microorganisms play crucial roles in plant Fe nutrition, yet the underlying mechanisms remain largely unknown. Here, we assessed the effect of the volatile organic compounds (VOCs) produced by Bacillus velezensis SQR9 on Fe uptake in Arabidopsis, elucidated ...
Taimeng Tan +12 more
wiley +1 more source