Results 51 to 60 of about 2,727 (259)

Strong emission of excimers realized by dense packing of pyrenes in tailored bola-amphiphile nano assemblies

open access: yesCell Reports Physical Science, 2022
Summary: Pyrene is known for the quenched emission of excimers, especially in aqueous solution. Here, we report strong emission of pyrene excimers realized in amphiphile assemblies by controlling the face-to-face distance between the pyrene planes.
Yuhan Zhao   +4 more
doaj   +1 more source

Optimization of SWCNT‐FET Biosensors by Aptamer Engineering and Toehold‐Mediated Strand Displacement

open access: yesAdvanced Science, EarlyView.
Aptamer‐based single‐walled carbon nanotube (SWCNT) field‐effect transistor (FET) biosensors are developed for label‐free, real‐time biomarker detection. Truncated DNA aptamers enhance sensitivity through improved conformational switching. A toehold‐mediated strand displacement (TMSD) strategy optimizes functionalization and simplifies fabrication. The
Haosen Miao   +8 more
wiley   +1 more source

Incorporation of Organic Counter‐Cations Into Poly(Heptazine Imide) Networks for Promoting Proton‐Coupled Electron Transfer During Photocatalytic H2O2 Evolution

open access: yesAngewandte Chemie, EarlyView.
Incorporation of N‐based onium ions into the ionic framework of poly(heptazine imide) was obtained via protonation‐deprotonation of PHI frameworks arising from a parent Na‐containing analogue. Particularly, methylammonium moieties, through their small molecular size, hydrogen bonding capabilities and rotational mobility, appear to stabilize ...
Dingqiao Ji   +6 more
wiley   +2 more sources

Les bases oronyques préromanes sur les Pyrénés méditerranéenes

open access: yesCuadernos de Investigación Filológica, 2013
*** No hay resumen disponible ***
H. Guiter
doaj   +1 more source

Para-N-Methylpyridinium Pyrenes: Impact of Positive Charge on ds-DNA/RNA and Protein Recognition, Photo-Induced Bioactivity, and Intracellular Localisation

open access: yesPharmaceutics, 2022
The 2- and 2,7- substituted para-N-methylpyridinium pyrene cations show high-affinity intercalation into ds-DNAs, whereas their non-methylated analogues interacted with ds-DNA/RNA only in the protonated form (at pH 5), but not at physiological conditions
Marta Košćak   +10 more
doaj   +1 more source

Spatially Separated Redox Centers in One‐Dimensional Sp2‐Carbon Covalent Organic Frameworks Enable Synergistic Photocatalytic Palladium Recovery and Bisphenol A Mineralization

open access: yesAdvanced Science, EarlyView.
A one‐dimensional sp2‐carbon covalent organic framework with spatially segregated redox centers integrates a dual photosensitizing system and a cationic interface for synergistic photocatalysis. The material achieves exceptional palladium recovery (1749 mg g−1) and bisphenol A mineralization (0.1710 min−1) without sacrificial agents, demonstrating ...
Yi‐Ru Chen   +9 more
wiley   +1 more source

Caracterização dos pirênios e métodos para acelerar a germinação de sementes de muruci do clone Açu Pyrene characterization and methods to acelerate germination of muruci seeds of the clone Açu

open access: yesRevista Brasileira de Fruticultura, 2008
Pirênios (caroços) de murucizeiro (Byrsonima crassifolia (L.) Rich.) do clone Açu, um acesso da Coleção de Germoplasma de Fruteiras Tropicais da Embrapa Amazônia Oriental, foram caracterizados, e avaliados diferentes métodos para superação da dormência ...
José Edmar Urano de Carvalho   +1 more
doaj   +1 more source

Aromaticity‐Engineered Open‐Shell Radical Anions for Air‐Stable Doublet Emission in N‐Annulated Perylene Diimide

open access: yesAdvanced Science, EarlyView.
Open‐shell type radical anions with stable doublet emission have been synthesized that feature aromaticity engineering, through‐space charge‐transfer (TSCT), and electro(fluoro)chromism. ABSTRACT We report the doublet emissive open‐shell radical anions, where the N‐annulated perylene diimide (PDIN–H) is functionalized with aromatic rings.
Jeongyoon Kim   +4 more
wiley   +1 more source

Wet Transfer of In Situ Grown Azo‐Containing Two‐Dimensional Conjugated Covalent Organic Framework Films for Photoswitchable Electronic Devices

open access: yesAngewandte Chemie, EarlyView.
Wet transfer of an atomically flat azo‐functionalized 2D covalent organic framework film onto monolayer MoS2 enables clean van der Waals heterostructure devices with reversible photoswitching and multilevel nonvolatile memory. ABSTRACT Two‐dimensional π‐conjugated covalent organic frameworks (2D π‐COFs) combine in‐plane π‐delocalization with periodic ...
Kexin Wang   +11 more
wiley   +2 more sources

Carbamate‐Directed peri‐CH Alkynylation: Application to the Synthesis of Zethrenes and Pyranthrenes

open access: yesChemistryEurope
The Rh(III)‐catalyzed regioselective alkynylation of 1‐pyrenyl and 1‐naphthyl carbamates with bromoacetylenes allows for the selective introduction of an alkyne at the peri position of readily available amino‐substituted polycyclic aromatic hydrocarbons (
Xiaoqing Shao   +4 more
doaj   +1 more source

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