Results 61 to 70 of about 2,936 (261)

A Bright Ratiometric Dipyrene Probe for Functional Imaging of Condensate Microenvironments in Living Cells

Advanced Science, EarlyView.
Ratiometric dipyrene imaging resolves monomer (M) and excimer (E) channels and computes pixel‐wise E/M maps within biomolecular condensates, yielding physicochemical fingerprints shaped by coupled polarity‐related solvation and microviscosity. These spatial fingerprints enable quantitative phenotyping of cellular states, exemplified by separation of ...
Koki Matsumoto, Sora Kitai, Yoshio Nishiyama, Shogo Amemori, Kei Makiyama, Dini Kurnia Ikliptikawati, Kentaro Ohira, Yuta Kozuka, Maho Tobita, Shih‐Cheng Chen, Chien‐Hung Yu, Wei‐Min Liu, De‐Chen Lin, Motohiro Mizuno, Kazuma Ogawa, Koichi Ogami, Kenji Takahashi, Hiroshi I. Suzuki, Richard W. Wong, Takahiro Soeta, Masaharu Hazawa   +20 more
wiley   +1 more source

Dispersion‐Clamped Crystalline Supramolecular Columnar π‐Stacks of Adamantyl‐Substituted Pyrenes

Angewandte Chemie, EarlyView.
Can neutral hydrocarbon π‐systems be forced into perfectly aligned cofacial stacks in crystals? An adamantyl‐decorated pyrene derivative crystallizes into rare translationally zero‐offset π‐columns, producing a short π–π distance below 3.3 Å and a large color shift arising from frontier crystal orbital (FCO) formation. ABSTRACT Despite their importance
Kazutaka Shoyama
wiley   +2 more sources

Time Resolved DNA Barcodes for Information Encoding and Dynamic Encryption

Advanced Science, EarlyView.
This study establishes a molecular information platform based on DNA Temporal Barcodes. Information is encoded through combinations of DNA tags with distinct retention times, while dynamic encryption is achieved through a key‐triggered DNA ligation.
Likang Chu, Haixia Wang, Haiyan Gao, Sixian Chen, Zilong Li, Zhanyihao Hao, Lei He, Da Han   +7 more
wiley   +1 more source

Impact of Threading State on the Mechanics of γ‐Cyclodextrin–Pyrene Gels

Angewandte Chemie, EarlyView.
Tuning the threading state of discrete γ‐cyclodextrin (γ‐CD)–pyrene pseudorotaxane crosslinkers controls gel topology and ring mobility. The resulting doubly threaded slide‐ring networks exhibit solvent‐switchable dissipative dynamics, high extensibility, rate‐dependent mechanics, and low hysteresis, revealing how crosslink topology governs macroscopic
Jongwon Oh, Heyi Liang, Natsumi Nitta, Jongmin Kim, Yuan Tian, Guancen Liu, Jerald E. Hertzog, Juan J. de Pablo, Stuart J. Rowan   +8 more
wiley   +2 more sources

Effect of methyl substitution on optoelectronic properties of 1,3,6,8-tetraphenyl pyrenes

上海师范大学学报. 自然科学版, 2014
Geometric structures of the ground states and excited states,frontier molecular orbitals,ionization potentials,electron affinities,reorganization energies,and absorption and emission spectra of three novel methyl-substituted 1,3,6,8-tetra-phenylpyrenes ...
LIU Yanling, DU Man, LIU Pengjun, HAN Lizhi, WANG Enju   +4 more
doaj   +1 more source

A Modular Standard Operating Procedure for Standardizing Lithium Metal Interfaces

Advanced Science, EarlyView.
A modular standard operating procedure (SOP) is developed to standardize lithium metal interfaces through sequential etching, brushing, and soaking. By transforming poorly controlled lithium surfaces into chemically uniform and structurally regulated interfaces, the framework improves electrochemical reproducibility, interfacial stability, and ...
Wen‐Hsin Chang, Anlin Shaju, Han‐Shiuan Lin, Sih‐Ling Hsu, Quang Huy Dinh, Che‐Ning Yeh, Elise Yu‐Tzu Li, Yu‐Sheng Su   +7 more
wiley   +1 more source

Pyrene Storage Time Reduces Dormancy and Physiological Quality in Butia Capitata (Arecaceae) Seeds [PDF]

Floresta e Ambiente
This study aimed to evaluate the physiological changes in pindo palm (Butia capitata) seeds, a native fruit species of the Brazilian Cerrado, over time under different storage conditions.
Marco Aurelio Santos Junior, Renan Ribeiro Silva, Silma da Conceição Neves, Leonardo Monteiro Ribeiro, Paulo Sergio Nascimento Lopes   +4 more
doaj   +1 more source

A Phosphorylation‐Induced Micellization Switch in the Low‐Complexity Domain of TDP‐43

Advanced Science, EarlyView.
Phosphorylation of TAR DNA‐binding protein's 43 kDa (TDP‐43) low‐complexity domain by casein kinase 1 delta (CK1δ) acts as a molecular switch, redirecting its self‐assembly from macroscopic phase separation toward finite‐sized, spherical block‐copolymer micelles of ∼30 nm.
Rodrigo F. Dillenburg, Anastasia Lopatina, Hao Ruan, Tom Scheidt, Simone Mosna, Emre Pekbilir, Julia Bieber, Frank Schäfer‐Depoix, Katharina Landfester, Carla Schmidt, Martin M. Möckel, Svenja Morsbach, Friederike Schmid, Dorothee Dormann, Lukas Stelzl, Martin Girard, Edward A. Lemke   +16 more
wiley   +1 more source

Diversity‐Oriented Two‐Step Annulative π‐Extension Enables Access to Structurally Complex Nanographenes

Angewandte Chemie, EarlyView.
Pd‐catalyzed C–H arylation of polycyclic aromatic hydrocarbons (PAHs) with various aryltrimethylsilanes enables the preparation of structurally complicated arylated PAHs, which can be further transformed to nanographenes in a manner of two‐step annulative π‐extension (APEX) reaction.
Honami Katsuragawa, Yoshifumi Toyama, Shota Mikawa, Kou P. Kawahara, Hideto Ito, Kenichiro Itami   +5 more
wiley   +2 more sources

Four new endemic genera of Rubiaceae (Pavetteae) from Madagascar represent multiple radiations into drylands

PhytoKeys, 2018
The taxonomic positions and phylogenetic relationships of six Pavetteae species endemic to Madagascar were tested with a phylogenetic study of the Afro-Madagascan representatives of the tribe Pavetteae based on sequence data from six markers rps16, trnT ...
Petra De Block, Franck Rakotonasolo, Salvator Ntore, Sylvain G. Razafimandimbison, Steven Janssens   +4 more
doaj   +3 more sources