Results 141 to 150 of about 197,331 (314)

A Facile Protocol for C(sp2)–C(sp3) Bond Formation Reactions Toward Functionalized E3 Ligase Ligands

open access: yesChemMedChem, EarlyView.
A robust C(sp2)–C(sp3) decarboxylative coupling strategy enables access to new CRBN ligands and degraders with improved physicochemical properties. This synthetic approach is expanding the chemical space beyond C(sp2)–N linkages, fine‐tuning proteolysis‐targeting chimera activities and unlocking previously inaccessible degrader chemotypes.
Anita Maksutova   +15 more
wiley   +1 more source

Epimerization of chlorophyll derivatives [PDF]

open access: yes, 1992
Mazaki, Hitoshi   +4 more
core   +1 more source

Electrochemical Three‐Component Synthesis of Vinyl Sulfonamides via Decarboxylative Sulfonylation of Cinnamic Acids

open access: yesChemSusChem, EarlyView.
An efficient, metal‐free electrochemical three‐component reaction of cinnamic acids, SO2, and amines to access (E)‐β‐styryl sulfonamides is reported. Utilizing graphite electrodes and SO2 stock solutions, this decarboxylative protocol proceeds under mild conditions with high regio‐ and stereoselectivity.
Po‐Chung Chien   +2 more
wiley   +1 more source

Structural Design of MOF‐Based and MOF‐Derived Composites for Oxygen Evolution Electrocatalysis: Materials Innovation for Energy and Environmental Sustainability

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This review provides an overview of recent developments in metal organic framework (MOF)‐based and MOF‐derived composites for efficient oxygen evolution reaction. This review also emphasizes the structural design of electrocatalyst, active site optimization, and emerging prospects of their use in practical electrolyzer systems.
Bhagyashri B. Kamble   +7 more
wiley   +1 more source

Boosting Zinc‐Ion Hybrid Capacitors with Mesoporous Carbon Derived from Highly Graphitized Carbon Quantum Dots

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
The work presents an innovative method for the preparation of mesoporous carbon materials (MCs) from highly graphitized carbon quantum dots. The zinc‐ion hybrid capacitors assembled with MCs deliver high rate performance and stability, providing promising advancements for future energy storage solutions.
Guoli Zhang   +6 more
wiley   +1 more source

Channel Microenvironment‐Controlled Pillared MOF as Efficient Triboelectric Nanogenerator Material for Self‐Powered Degradation of Organic Pollutants

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
The pore microenvironment regulation of metal–organic framework (MOF) significantly enhanced the output performance of triboelectric nanogenerators (TENG) through SC‐SC transformation, which provides a new idea for the construction of self‐powered degradation systems for organic pollutants.
Long Li   +8 more
wiley   +1 more source

Facile Preparation Methods for Triarylmethyl‐Type Stable Luminescent Diradicals and Higher Multiradicals

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
A range of synthetic methods for photophysically attractive stable luminescent diradicals have been developed, enabling the preparation of diverse derivatives. Direct substitution of the tris(2,4,6‐trichlorophenyl)methyl radical introduces donor groups to afford acceptor–donor–acceptor luminescent diradicals, while halogenated triarylmethanes are ...
Yohei Hattori, Gwénaël Rapenne
wiley   +1 more source

Understanding protein–flavor interactions: Factors, characterization techniques, and the effect of processing

open access: yesFood Biomacromolecules, EarlyView.
Abstract The perception of flavor in a food system depends on its release from the protein matrix. Apart from hydrogen bonding, hydrophobic interactions and van der Waal's forces, the formation of covalent adducts between the flavor and protein highly impacts the release of flavor from the protein matrix.
Arshita Verma   +2 more
wiley   +1 more source

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