Results 91 to 100 of about 104,064 (339)

Organocatalytic Lewis base functionalisation of carboxylic acids, esters and anhydrides via C1-ammonium or azolium enolates [PDF]

open access: yes, 2014
This tutorial review highlights the organocatalytic Lewis base functionalisation of carboxylic acids, esters and anhydrides via C1-ammonium/azolium enolates.
Morrill, Louis C., Smith, Andrew D.
core   +1 more source

Self‐Reinforcing Degradation of Solution‐Processed Small‐Molecule OLEDs: Excited‐States and Molecular Interactions as Key Triggers

open access: yesAdvanced Functional Materials, EarlyView.
Self‐reinforcing degradation in solution‐processed small‐molecule organic light‐emitting diodes (OLEDs) arises from charge accumulation and exciton‐polaron interactions, leading to molecular aggregation and efficiency loss. This study uncovers the fundamental mechanisms behind this degradation and introduces strategic material engineering approaches ...
Eonji Cha   +8 more
wiley   +1 more source

Axitinib, cabozantinib, everolimus, nivolumab, sunitinib and best supportive care in previously treated renal cell carcinoma: a systematic review and economic evaluation

open access: yesHealth Technology Assessment, 2018
Background: Several therapies have recently been approved for use in the NHS for pretreated advanced or metastatic renal cell carcinoma (amRCC), but there is a lack of comparative evidence to guide decisions between them.
Steve J Edwards   +7 more
doaj   +1 more source

2-Bromo-5-methylpyridine

open access: yesIUCrData, 2016
The title compound, C6H6BrN, has half of a molecule in the asymmetric unit, as it sits on a crystallographic plane of symmetry. In the crystal, weak C—H...N interactions link the molecules, forming chains along [100]. No π–π interactions are observed.
Mrittika Roy   +2 more
doaj   +1 more source

Functionalized Lignin Derivatives as Melt‐Spinnable Precursors for Carbon Fiber Production without Stabilization

open access: yesAdvanced Functional Materials, EarlyView.
By turning off hydrogen bonds by bulky ethyl cinnamate ester derivatization, softwood kraft lignin can flow under elevated temperatures, providing tough fiber in the melt for high take‐up speed. Subsequently, lignin ethyl cinnamate derivatives are readily stabilized with only dilute nitric acid leading to direct carbonized fiber with outstanding ...
Qi Hua   +8 more
wiley   +1 more source

Mechanically Tunable Bone Scaffolds: In Vivo Hardening of 3D‐Printed Calcium Phosphate/Polycaprolactone Inks

open access: yesAdvanced Functional Materials, EarlyView.
A 3D bone scaffold with osteogenic properties and capable of hardening in vivo is developed. The scaffold is implanted in a ductile state, and a phase transformation of the ceramic induces the stiffening and strengthening of the scaffold in vivo. Abstract Calcium phosphate 3D printing has revolutionized customized bone grafting.
Miguel Mateu‐Sanz   +7 more
wiley   +1 more source

A Peptide Nucleic Acid‐Functionalized Heterojunction Thin Film Transistor as a Scalable and Reusable Platform for Label‐Free Detection of MicroRNA

open access: yesAdvanced Functional Materials, EarlyView.
A miniaturized, label‐free, and enzyme‐free biosensor (miR‐TFT) enables direct electrical detection of microRNA (miRNA) with single‐nucleotide specificity and a detection limit of 0.6 fM. Built on a tri‐channel In2O3/ZnO heterojunction and functionalized with bespoke peptide nucleic acid (PNA) probes, the device is robust, reusable, and compatible with
Wejdan S. Al Ghamdi   +5 more
wiley   +1 more source

Role of Crosslinking and Backbone Segmental Dynamics on Ion Transport in Hydrated Anion‐Conducting Polyelectrolytes

open access: yesAdvanced Functional Materials, EarlyView.
Thermally crosslinked poly(2‐vinylpyridine)‐based anion conducting polyelectrolytes have been synthesized. The segmental dynamics of these polyelectrolytes have been systematically modified by varying the degree of crosslinking. Both the experimental and simulation results indicate that segmental dynamics have a limited influence on ion transport in ...
Zhongyang Wang   +11 more
wiley   +1 more source

Metal‐Organic Frameworks Facilitating Complexation for Long‐Cycle Zinc‐Bromine Flow Batteries

open access: yesAdvanced Functional Materials, EarlyView.
The organic ligands (imidazole and benzimidazole) from the decomposed zinc ZIF‐62 is proposed to further improve the Br2 complexing ability of the mature complexing agent (i.e., N‐methyl‐N‐ethyl pyrrolidinium bromide (MEP) ionic liquid). The synergistic effect between Im/BIm of the decomposed ZIF‐62 toward bromine species and MEP toward bromine species,
Huaiyang Zheng   +8 more
wiley   +1 more source

Unexpected = 4 + 2 Cycloaddition through Chromium Non-Heteroatom-Stabilized Alkynyl Carbene Complexes: Regioselective Access to Substituted 6-Azaindoles [PDF]

open access: yes, 2018
This research was supported by the Spanish Government MINECO/FEDER (CTQ-2016-76840-R and CTQ-2017-87372-P (AEI/FEDER, UE)) and the Principality of Asturias, Spain (GRUPIN14 ...
Funes Ardoiz, Ignacio   +3 more
core   +2 more sources

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