Results 101 to 110 of about 73,143 (258)

Skeletal Editing from Pyridine to Aniline via C‐Insertion and N‐Isomerization

ChemistryEurope, EarlyView.
A concise protocol is presented that converts pyridines into anilines by externalizing the original pyridine nitrogen at either the "ipso" or "ortho" position, which results in para or meta‐primary aniline products. A key carbene‐insertion step precedes nitrogen migration, preserving both ring size and overall structure.
Yun Luo, Jing Dai, Yongchang Wei, Chang Min   +3 more
wiley   +1 more source

The Composition of Arylstibonic Acids [PDF]

, 2010
This thesis describes a detailed ESI-MS investigation into the arylstibonic acids, organo-antimony-containing compounds that are currently of interest as anticancer reagents. Four arylstibonic acids, of nominal formula RC6H4SbO3H2 [R = p-chloro-, p-tolyl-
Wright, Cody Elvin
core   +1 more source

Regioselective suzuki coupling on pyridinium N-(3,5-dibromoheteroar-2-yl)aminides [PDF]

, 2006
A regioselective Suzuki-Miyaura cross-coupling reaction on 3',5'-dibromo pyridinium N-(2'-azinyl)aminides is reported. A series of 3'-aryl(or heteroaryl)-5-bromo-pyridinium N-(2'-pirazinyl)aminides were obtained in good yields.
Castillo Romero, Rafael, Izquierdo Ceinos, Ma Luisa, Reyes Prados, María José, Álvarez-Builla Gómez, Julio   +3 more
core   +3 more sources

Shedding Light on Synthetic Autocatalysis: From Conventional Closed‐Shell Chemistries to Overlooked Open‐Shell Occurrences

Chemistry – A European Journal, EarlyView.
Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley   +1 more source

Photochemical Approaches to Complex Chemotypes: Applications in Natural Product Synthesis. [PDF]

, 2016
The use of photochemical transformations is a powerful strategy that allows for the formation of a high degree of molecular complexity from relatively simple building blocks in a single step. A central feature of all light-promoted transformations is the
Kärkäs, Markus D., Porco, John A., Stephenson, Corey R.J.   +2 more
core   +2 more sources

Membrane Engineering for Battery Systems: Bridging Design Principles and Frontier Applications

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
The review emphasizes membrane separators' role in battery performance and safety, covering redox flow, lithium‐ion, and solid‐state batteries. It reviews advances in membrane materials (e.g., polymer electrolytes, hybrid composites) and ion transport mechanisms, while addressing challenges like dendrite growth and crossover losses.
Xiaoqun Zhou, Justice Delali Akoto, Rui Tan, Jun Ma   +3 more
wiley   +1 more source

Bis(4,4′-bipyridin-1-ium) cis-bis(1,2-dicyano-2-sulfidoethene-1-sulfinato-κ2S,S′)platinate(2−)

IUCrData
Crystals of the sulfinate-containing platinate salt, (C10H9N2)2[Pt(C4N2O2S2)2], were obtained from a solution of [Pt(4,4′-bpy)2(mnt)] after a long period with minimal light (4,4′-bpy is 4,4′-bipyridine and mnt is maleonitriledithiolate). In the crystals,
Claire E. Welton, Eric W. Reinheimer, Bradley W. Smucker   +2 more
doaj   +1 more source

Hydroxyl Functionalized Pyridinium Ionic Liquids: Experimental and Theoretical Study on Physicochemical and Electrochemical Properties

Frontiers in Chemistry, 2019
Structurally modified hydroxyl functionalized pyridinium ionic liquids (ILs), liquid at room temperature, were synthesized and characterized. Alkylated N-(2-hydroxyethyl)-pyridinium ILs were prepared from alkylpyridines via corresponding bromide salts by
Kallidanthiyil Chellappan Lethesh, Sigvart Evjen, Jaganathan Joshua Raj, Denis C. D. Roux, Vishwesh Venkatraman, Kaushik Jayasayee, Anne Fiksdahl   +6 more
doaj   +1 more source

Synthesis of chiral 2-methyl-5,6,7,8-tetrahydroquinolines from naturally occurring monoterpenes [PDF]

, 2004
The synthesis is reported of chiral substituted 2-methylpyridines, in which the pyridine rings are annulated at the 5,6-positions to the chiral frameworks originating from (-)-β-pinene, (-)-isopinocampheol and (+)-camphor.
Chelucci, Giorgio Adolfo, Orrù, Gianmauro, Soccolini, Francesco   +2 more
core  

Flexible ionic pressure sensors: From migration‐electronic mechanisms to emerging iontronic paradigms

InfoMat, EarlyView.
Mechanisms, materials, structures, and applications of the FIPSs. Abstract Flexible ionic pressure sensors (FIPS) have emerged as promising candidates for bridging the gap between electronics and biologically compatible interfaces. Unlike previous reviews, which focused primarily on materials or devices, this review presents a classification of FIPS ...
Mengjie Wang, Yanan Ma, Jia Liu, Li Xu, Li Wen, Ranyun Wu, Yongfa Cheng, Liang Li, Siliang Wang, Yang Yue, Zhixiang Huang   +10 more
wiley   +1 more source