Results 121 to 130 of about 60,159 (283)

Nitrooxylation in Organic Synthesis: From Classical Nitrate Ester Formation to Modern Catalytic Strategies

open access: yesChemistry – A European Journal, EarlyView.
Nitrooxylation—the installation of nitrate esters (–ONO2) has evolved from classical mixed‐acid protocols to catalytic and mechano‐, flow‐, photo‐, and electrochemical strategies. This review delineates ionic and radical manifolds for C–ONO2 bond formation, emphasizing mechanistic control, selected substrate scope, and selectivity.
Jayanta Dey, Dmitry Katayev
wiley   +1 more source

Push-pull systems based on pyridinium betaines.

open access: yes, 2012
Byla provedena literarni rešerše mapujici využiti a synteticke postupy vedouci k push-pull systemům na bazi pyridinium betainů. Využiti těchto latek spočiva předevšim v jejich NLO vlastnostech.
Miklík, David
core   +1 more source

Bis(4,4′-bipyridin-1-ium) cis-bis(1,2-dicyano-2-sulfidoethene-1-sulfinato-κ2S,S′)platinate(2−)

open access: yesIUCrData
Crystals of the sulfinate-containing platinate salt, (C10H9N2)2[Pt(C4N2O2S2)2], were obtained from a solution of [Pt(4,4′-bpy)2(mnt)] after a long period with minimal light (4,4′-bpy is 4,4′-bipyridine and mnt is maleonitriledithiolate). In the crystals,
Claire E. Welton   +2 more
doaj   +1 more source

π‐Extended Salphen Scaffolds Enable CO2 Electroreduction and Singlet Oxygen Generation

open access: yesChemistry – A European Journal, EarlyView.
New family of π‐extended salen ligands bearing phenylene bridge and tunable phenyl‐based substituents, and their corresponding boron difluoride complexes. Thanks to the extended π‐delocalization over the molecule, the ligands themselves show promising results in electrochemical CO2 reduction to CO, while the complexes act as efficient photosensitizers ...
Vincenzo Langellotti   +10 more
wiley   +1 more source

Pyridinium Compounds

open access: yes, 1994
Methods for using novel quaternary pyridinium compounds in inhibiting acetylcholinesterase in mammals, specifically using the quaternary pyridinium compounds in the prophylaxis and treatment of organophosphate poisoning and mammalian dementia by ...

core  

Hybrid Macrocyclic Peptides — Synthetic Strategies to Diversify and Cyclize Peptide Libraries in Phage Display Selections

open access: yesChemistry – A European Journal, EarlyView.
Hybrid macrocyclic peptides unite genetically encoded peptide libraries with the structural complexity of synthetic small molecules. This Review critically analyzes phage‐compatible cyclization and diversification chemistries, highlights emerging opportunities beyond traditional cysteine‐based approaches, and outlines how future advances may enable the
Titia Rixt Oppewal, Clemens Mayer
wiley   +1 more source

Expanding the Scope of Indium in Frustrated Lewis Pair Chemistry

open access: yesChemistry – A European Journal, EarlyView.
All good things come in threes: The pyridine‐“protected” FLP tBu2InCH2PtBu2·Py shows three different kinds of reactivity: Besides “typical” FLP activity, it prefers formation of the “soft” isomers for substrates with multiple sites for FLP attack, but reacts with SO2 as a “masked” In/C FLP by insertion into the In─C bond.
Daniel N. Heuer   +5 more
wiley   +1 more source

From Charge‐Transfer Adducts to (Tri)Halide‐Templated Supramolecular Cages: Covalent vs Ionic Products in the Reactions of Pyridin‐4‐ylthio‐Substituted Tetrathiafulvalene With Dihalogens and Interhalogens

open access: yesChemistry – A European Journal, EarlyView.
The reactions between tetra(pyridin‐4‐ylthio)tetrathiafulvalene and Br2/I2/ICl/IBr led to a variety of products, including a rare example of neutral 1:4 CT adduct and ionic products showing supramolecular cage motifs at (tri)halide templates. The nature of the reaction products was elucidated based on XRD analysis, Raman spectroscopy and QTAIM, NCI ...
Anna Caria   +6 more
wiley   +1 more source

Polymer–ionic liquid interactions in aqueous media: A viscosity, conductivity, and UV–Vis study of poly(ethylene oxide) and 1-alkyl-4-methylpyridinium bromide

open access: yesChemical Thermodynamics and Thermal Analysis
Viscosity and electrical conductivity of ternary systems (poly(ethylene oxide) + 1-alkyl-4-methyl pyridinium bromide + water) were studied. The results imply that thermodynamic quality of solvent (1-alkyl-4-methyl pyridinium bromide aqueous solutions) is
Abbas Mehrdad   +2 more
doaj   +1 more source

Pyridinium-based fluorosulfonamide reagents enabled photoredox catalyzed radical fluorosulfonamidation [PDF]

open access: yes
Sulfamoyl fluorides, as a crucial building block of SuFEx, have garnered extensive research interest due to their applications in chemical biology, materials science, and drug discovery. Recently, considerable research has been dedicated to the synthesis
Chao, Sun   +10 more
core   +2 more sources

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