Results 141 to 150 of about 52,626 (269)

Synthesis, characterisation and magnetic behaviour of ionic metalloporphyrins: metal-tetrakis(N-octyl-4-pyridinium)-porphyrins with tetrabromoferrate(III) anions [PDF]

open access: yes, 2013
A series of magnetic, ionic-substituted tetrapyridyl metalloporphyrins, [tetrakis(N-octyl-4-pyridinium)-metal-porphyrin][tetrabromoferrate(III)] 4 (metal=iron, cobalt, manganese, copper or zinc), have been synthesised.
Zhou, Qing   +9 more
core  

All‐in‐One Intelligent Hemostatic Sponge: Rapid Hemostasis for Non‐Compressive Wounds With Synergetic Enhanced Antibacterial Efficacy and Self‐Reporting Biodegradation

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Clinicians often concurrently tackle critical challenges including emergency hemorrhage, secondary infection, and the elusive tracking of biodegradation of conventional hemostatic agents for complex wounds. Here, we report an intelligent hemostatic sponge (spCS@AIE) by incorporating aggregation‐induced emission (AIE) nanoparticles with short‐wave ...
Zhicheng Liu   +12 more
wiley   +1 more source

Tellurium Electrochemistry: From Mechanistic Analysis in Diverse Electrolytic Media to Advanced Energy Storage Applications

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
As a metalloid with broad prospects in advanced applications, Te has not been fully clarified in terms of its intricate electrochemical behaviors across varied systems. This review systematically integrates fundamental electrochemical mechanisms, reaction kinetics identifications, and device application insights, establishing a comprehensive framework ...
Meng Zhang   +6 more
wiley   +1 more source

Expanding the Scope of 1,2‐Diazepines Through Alternative Activation Strategies

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Often overlooked due to tedious synthetic routes, 1,2‐diazepines can be found in handful of biorelevant molecules. Previous reports from our group lifted the principal synthetic lock: a rapid and user‐friendly protocol to reach monocyclic 1,2‐diazepines from readily available pyridines and electrophilic activating groups. Herein, we extend the scope of
Alexis Leblais   +4 more
wiley   +1 more source

The Expanding Role of Diazirines in Synthetic Methodology

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Beyond their established role in photoaffinity labeling, diazirines have emerged as versatile reagents in synthetic chemistry. This review highlights their dual reactivity as carbene and nitrogen‐transfer precursors, showcasing mechanistic insights and diverse applications in cyclopropanations, cycloadditions, skeletal editing, amination, heterocycle ...
Viktor Savic   +3 more
wiley   +1 more source

Mining Oral Probiotics Based on Their Pathogen Inhibition and Deodorization Roles

open access: yesFood Bioengineering, EarlyView.
A promising oral probiotic strain Streptococcus salivarius MY‐6 stood out from 41 candidate lactic acid bacteria through the high‐throughput strategy based on its inhibitions of the growth and biofilm formation of the main oral pathogens Fusobacterium nucleatum and Porphyromonas gingivalis, as well as its elimination of oral malodor‐associated ...
Yaao Chen   +8 more
wiley   +1 more source

Spatially Resolved Metabolomics of Optimal Cutting Temperature (OCT) Compound‐Embedded Tumors

open access: yesInternational Journal of Cancer, EarlyView.
ABSTRACT Mass spectrometry imaging (MSI) is emerging as a powerful tool for uncovering the distribution of metabolites in the tumor microenvironment and studying tumor metabolism in vivo. To date, MSI of biobanked tissues contextualized by patient data has been limited to peptides, proteins, and glycans—with few examples for metabolites.
Joseph Monaghan   +6 more
wiley   +1 more source

Investigating the chemistry of pyridinium ylides [PDF]

open access: yes
This thesis describes investigation into catalytic formation of pyridinium ylides from diazo compounds and their subsequent reactivity. In particular, cycloaddition reactions with electrophilic alkenes are performed to generate tetrahydroindolizines that
Abdullah, Rasha Azzam
core  

Gold(I)‐Catalyzed Annulation of Pyridines Containing Alkyne: Synthesis of N‐Alkenyl Pyridonyl Azides via Rearrangement

open access: yesJournal of Heterocyclic Chemistry, EarlyView.
One‐pot gold(I)‐catalysts synthesis was developed in order to prepare N‐alkenyl 2‐pyridonyl azides. This method provides a series of N‐alkenyl 2‐pyridonyl azides in moderate to excellent yields (up to 94%). ABSTRACT A novel strategy, involving the preparation of gold‐catalyzed cyclization salts and the rearrangement of these salts in the presence of ...
Ali Osman Karatavuk
wiley   +1 more source

Sustainable Metal Recovery From E‐Waste: Exploring Greener Leachates in Hydrometallurgical Processes

open access: yesMetalMat, EarlyView.
Recycling of electronic waste to synthesize valuable metals using green leachate. ABSTRACT The accumulation of electronic waste (e‐waste) poses environmental hazards and leads to the loss of valuable metals such as gold, silver, copper, and rare earth elements.
Shassatha Paul Saikat   +4 more
wiley   +1 more source

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