In the title salt of an S-substituted dithiocarbazate, C16H16N3S2+·Cl−, the dihedral angles between the almost planar (r.m.s deviation = 0.005 Å) central CN2S2 residue and the terminal pyridinium and phenyl rings are 80.09 (11) and 3.82 (11 ...
May Lee Low +4 more
doaj +1 more source
One-Flow, Multi-Step Synthesis of Nucleosides via Brønsted Acid- Catalyzed Glycosylation [PDF]
Nucleosides in flow: A general, scalable method of Brønsted acid-catalyzed nucleoside formation is described. Because of the high reaction temperatures readily available to the flow reaction format, mild Brønsted acids, particularly pyridinium triflates,
Bedore, Matthew W. +2 more
core +1 more source
High Potential Isoindoline‐Based Nitroxides Posolytes for Aqueous Organic Redox Flow Batteries
A convenient metal‐catalyzed [2 + 2 + 2] cycloaddition enables the synthesis of isoindoline‐based nitroxides as new posolytes for aqueous organic redox flow batteries. The cationic PPO exhibits a 220 mV higher oxidation potential than 4‐TMA‐TEMPO, 3 M solubility in 1 M NaCl, and a cell voltage of 1.56 V.
Karim Boutamine +8 more
wiley +1 more source
4-Aminopyridinium cis-2-carboxycyclohexane-1-carboxylate
In the structure of the title molecular salt, C5H7N2+·C8H11O4−, the cis monoanions associate through short O—H...O hydrogen bonds in the carboxylic acid groups [graph set C(7)], forming zigzag chains which extend along the c ...
Urs D. Wermuth, Graham Smith
doaj +1 more source
Poly(Pyridinium Salt)s Containing 2,7-Diamino-9,9'-Dioctylfluorene Moieties with Various Organic Counterions Exhibiting Both Lyotropic Liquid-Crystalline and Light-Emitting Properties. [PDF]
Bhowmik PK +8 more
europepmc +1 more source
Construction of 3,5-dinitrated 1,4-dihydropyridines modifiable at 1,4-positions by a reaction of β-formyl-β-nitroenamines with aldehydes [PDF]
A novel and efficient method for the synthesis of 4-substituted 3,5-dinitro-1,4-dihydropyridines by a reaction of β-formyl-β-nitroenamines with aldehydes was developed.
1187 +7 more
core +2 more sources
This study reports the synthesis of a pyridinium salt achieved by heating 2-chloropyridine with 2-bromoacetamide in the absence of solvent. The synthesized salt exhibits a high reactivity towards nucleophilic substitution reactions with C-nucleophiles ...
Oleksii Y. Kashner +2 more
doaj +1 more source
Crystal structure of the co-crystal salt 2-amino-6-bromopyridinium 2,3,5,6-tetrafluorobenzoate
The asymmetric unit of the co-crystal salt 2-amino-6-bromopyridinium 2,3,5,6-tetrafluorobenzoate, C5H6BrN2+·C7HF4O2−, contains one pyridinium cation and one benzoate anion. In the crystal, the aminopyridinium cationic unit forms two hydrogen bonds to the
Eric Bosch
doaj +1 more source
Pyridinium N-(2'-azinyl)aminides: Regioselective synthesis of 2-alkylaminoazines [PDF]
The regioselective alkylation of pyridinium-N-(2'-azinil)aminides with alkyl halides under mild conditions is described. The alkylation, combined with a reduction of the N-N bond, allows an easy preparation of 2-alkylaminoazines.The authors wish to thank
Burgos Gómez, Carolina +5 more
core +3 more sources
The constrained tryptophan (Trp) analog 1,2,3,4‐tetrahydro‐β‐carboline‐3‐carboxylic acid (Tcc) is used to restrict peptide conformation in structure–activity relationship studies. Although Pictet–Spengler cyclization of Trp and aldehydes with mineral acid gives Tcc analogs, such harsh conditions do not tolerate acid‐labile functionality.
Omer S. L. N'dri +10 more
wiley +1 more source

