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Direct C–H Sulfonylimination of Pyridinium Salts

Organic Letters, 2022
A direct pyridinium C-H sulfonylimination has been developed for the synthesis of sulfonyl iminopyridine derivatives with high efficiency. This transformation features the direct and efficient formation of a C═N bond with a high functional group tolerance under metal-free conditions.
Lihua Luo   +8 more
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Imidazo [1,2‐a] pyridinium salts

Journal of Heterocyclic Chemistry, 1965
Abstract2‐Alkylamino‐ or arylaminopyridines react directly with α‐bromoketones to afford 1‐alkyl‐ or 1‐arylimidazo[1,2‐a]pyridinium salts with substituents at position 2. Use of chloroacetaldoxime as the quaternizing agent yields (after hydrolysis) the imidazo‐[1,2‐a]pyridinium ion with no substituent at position 2.
C. K. Bradsher   +2 more
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The reaction of N-nitrosamines with pyridinium salts

Talanta, 1988
N-Nitrosamines react readily with pyridinium salts containing an activated methylene group to give hydrazones. This reaction may serve as the basis for the routine determination of N-nitrosamines.
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N-(?-ferrocenylalkyl) pyridinium salts

Bulletin of the Academy of Sciences, USSR Division of Chemical Science, 1966
1. N- (α-Ferrocenylalkyl)pyridinium p-toluenesulfonates are formed when ferrocenylcarbinols are reacted with p-toluenesulfonyl chloride in pyridine. 2. The N-(α-ferrocenylalkyl)pyridinium salts are good ferrocenylalkylating agents.
A. N. Nesmeyanov   +2 more
openaire   +1 more source

Recyclization of polysubstituted pyridinium salts

Tetrahedron, 1995
Abstract 3,5-Diacetyl- and 3,5-dicyano-1,2,6-trimethylpvridinium perchlorates are converted by recyclization into N,5-dimethylanilines and 2-methylaminopyridines, respectively.
Galina P. Shkil   +3 more
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Pyridinium Salts as Organophosphate Antagonists

2015
By a standard screening in vivo, a series of pyridinium salts were tested for their protective activity against organophosphate poisoning. In order to obtain information about the protective mechanisms, several biochemical properties of these compounds were investigated in vitro, viz., their influence upon the enzymes cholineacetyltransferase and ...
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Hexahydrobenzothiazolo[3,2-a]pyridinium salts

Chemistry of Heterocyclic Compounds, 1988
Salts of hexahydrobenzothiazolo[3,2-a]pyridine are obtained by exchange reactions. Anions are placed in the order [(NC)2CCHC(CN)2]- > ClO4−>I3−>Br− according to the ability to displace each other. X-ray structural and spectroscopic studies establish the cis-attachment of the thiazolidine and cyclohexane rings in the hexahydrobenzothiazolo [3,2-a ...
A. M. Shestopalov   +6 more
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Oxidation of polysubstituted pyridinium salts

Collection of Czechoslovak Chemical Communications, 1982
Oxidation of 1-substituted 2,4,6-triphenylpyridinium salts Ia-Ij with potassium ferricyanide in an alkaline medium was accompanied by contraction of the pyridine ring and formation of 1,2,3,5-tetrasubstituted pyrroles II. The derivative IIf underwent facile electrophilic substitution in the position 4. Contrary to compounds Ia-Ij, the 1-substituted-2,6-
Petr Nesvadba, Josef Kuthan
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Thiazolo [3,2‐a] pyridinium salts

Journal of Heterocyclic Chemistry, 1966
AbstractThe sulfides formed by the reaction of α‐halo ketones or α‐halo acetals with 2‐mercaptopyridine may be cyclized in good yield to form thiazolo[3, 2‐a]pyridinium salts. The presence of chloro or nitro substituents on the pyridine ring does not interfere with the synthesis.
C. K. Bradsher, D. F. Lohr
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Investigation of Methyl Pyridinium-2-aldoxime Salts

Journal of Pharmaceutical Sciences, 1961
Methyl pyridinium-2-aldoxime iodide (2-PAM iodide) has been reported to be effective in preventing and overcoming the toxic effects in animals poisoned with organic phosphorus compounds that are inhibitors of the cholinesterase enzymes. In order to obtain greater water solubility of the oxime and to eliminate undesirable side effects due to the iodide ...
A A, KONDRITZER, R I, ELLIN, L J, EDBERG
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