Remarkable Formation of Indene Derivatives Upon Friedel–Crafts Acylation Reactions
This shows indene derivatives. Under the reaction conditions of a Friedel–Crafts acylation, alkyl benzenes underwent an unprecedented cyclopentannulation furnishing indene derivatives. Alkylbenzene derivatives react with two equivalents of pivaloyl chloride (PivCl) in the presence of aluminum trichloride under formation of indene derivatives with up to
Leah Bantel +3 more
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Unraveling UVA1-Induced Photomodifications of Eumelanin and Pheomelanin in Human Skin: Insights into Pigment Darkening. [PDF]
Ito S +4 more
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Triplet–triplet annihilation upconversion (TTA‐UC) performed inside supramolecular viscoelastic gels enables efficient CC and C–heteroatom coupling reactions under green LED irradiation in open‐air conditions. The gel network restricts oxygen diffusion, preserves triplet states, and allows aryl halide activation through upconverted excited states ...
Daniel Álvarez‐Gutiérrez +4 more
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Structural modification of functionalized carbazoles: from Z' = 1 to Z' = 6. [PDF]
Abualnaja M +4 more
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Azuleno[1′,2′:4,5]pyrrolo[2,3‐b]quinoxaline with a mesityl group as a solubilizing group was synthesized. By synthesizing derivatives in which various functional groups were introduced into two electronically distinct sites, the pyrrole nitrogen atom and the azulene five‐membered ring, we were able to reveal that the photophysical and electrochemical ...
Ryuta Sekiguchi +6 more
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Label-Free Impedimetric Biosensor Based on Molecularly Imprinted PPy/MWCNTs Nanocomposites for Sensitive and Selective Detection of <i>Escherichia coli</i>. [PDF]
Zhang W +5 more
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Electrochemical Three‐Component Synthesis of Heteroaryl Sulfonates
An electrochemical, metal‐free three‐component strategy for direct C(sp2)─H sulfonation of electron‐rich heteroarenes using SO2 and alcohols is described. Utilizing inexpensive graphite electrodes and practical SO2 stock solutions under mild conditions, this method provides straightforward access to heteroaryl sulfonates from simple building blocks ...
Po‐Chung Chien +2 more
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Pyrrole without Life: Reaction of Aminomethylene with the Propargyl Radical. [PDF]
McClish R +6 more
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The development of conventional phototheranostic nanomedicines suffers from an intrinsic trade‐off between NIR‐II fluorescence emission and phototherapeutic effects, leading to poor overall efficacy. Herein, we propose an innovative fluorination strategy by constructing fluorinated surroundings in NIR‐II‐emissive organic semiconducting agents to ...
Xiaoming Hu +7 more
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Regioselective Synthesis of 1,2,3-Trisubstituted Pyrroles via Addition-Cyclization of Crotonate-Derived Sulfonium Salts with a Carboxylic Acid and an Amine. [PDF]
Chavan LN +3 more
europepmc +1 more source

