Results 21 to 30 of about 1,535 (151)

Water, Alcohols, Amines, and Amides as Formal Hydrogen‐Atom‐Transfer Reagents Through Activation With Redox‐Active Lewis Acids

open access: yesAngewandte Chemie, EarlyView.
Protic molecules containing strong O─H or N─H bonds typically resist hydrogen‐atom abstraction because of the high reactivity of the resulting heteroatom‐centered radicals. However, association of the protic molecules with redox‐active Lewis acids can provide powerful hydrogen‐atom donors or proton‐coupled‐electron‐transfer reagents.
Petra Vojáčková, Armido Studer
wiley   +2 more sources

Microwave-assisted synthesis of pyrrolidinone derivatives using 1,1’-butylenebis(3-sulfo-3H-imidazol-1-ium) chloride in ethylene glycol

open access: yesGreen Processing and Synthesis, 2019
The energy efficiency of the microwave-assisted synthesis of pyrrolidinones was demonstrated using catalytic loading of 1,1’-butylene-bis(3-sulfo-3H-imidazol-1-ium) chloride as a sulfonic acid functionalized ionic liquid in ethylene glycol as green ...
Khaligh Nader Ghaffari   +3 more
doaj   +1 more source

Recent Developments in Energy Storage and Conversion Applications of Multifunctional Vanadium Carbides

open access: yesAdvanced Materials Technologies, EarlyView.
This review systematically explains the synthesis, properties, and energy storage and conversion applications of vanadium carbides. We introduce the structural and the synthetic strategies and reviewed recent developments in the material synthesis processes. The emerging applications of vanadium carbides in energy storage and conversion are highlighted.
Swathy B. Saseendran   +2 more
wiley   +1 more source

Streptavidins Coordinate Biotin Sequestration and Self‐Resistance Within a Biotin‐Pathway Antibiotic Network

open access: yesAdvanced Science, EarlyView.
A conserved genomic region between two streptavidin genes in Streptomyces packages biosynthetic gene clusters for diverse biotin‐pathway antibiotics: acidomycin, stravidin, the new non‐proteinogenic amino acid ANDA, and the new BioA inhibitor α‐methyl‐KAPA.
Sumire Kurosawa   +8 more
wiley   +1 more source

Tailoring K+ Dosage in K+/Zn2+ Mixed Electrolytes via Lattice Expansion Regulation of Zinc Hexacyanoferrate for High‐performance Zinc Ion Batteries

open access: yesAdvanced Science, EarlyView.
The study proposes a fitting curve as a reference to quantify the optimal K+ ratio in K+/Zn2+ mixed electrolyte, thus achieving stable and high‐capacity aqueous zinc ion batteries at each current density. ABSTRACT Incorporating K+ into Zn‐based electrolytes can enhance the performance of aqueous zinc ion batteries, while the lack of a clear rule for ...
Yewei Li   +7 more
wiley   +1 more source

Dynamically Modified Flexible Zn Powder Anodes with Stable Performance at High Rate and High Zn Utilization

open access: yesAdvanced Science, EarlyView.
A dynamically shape‐variant liquid metal‐based network is integrated into Zn powder electrode, where intrinsic fluidity and structural adaptability of the liquid metal‐based network enable effective mitigation of dendritic growth, alleviation of stress accumulation, and prevention of Zn loss during Zn plating‐stripping processes.
Yuxuan Wang   +9 more
wiley   +1 more source

Metabolites from Marine Macroorganisms of the Red Sea Acting as Promoters or Inhibitors of Amylin Aggregation

open access: yesBiomolecules
Amylin is part of the endocrine pancreatic system that contributes to glycemic control, regulating blood glucose levels. However, human amylin has a high tendency to aggregate, forming isolated amylin deposits that are observed in patients with type 2 ...
Mawadda Alghrably   +11 more
doaj   +1 more source

The influence of Ag2O/NbO2 nanocomposites on the optical properties of PVA/PVP lend in biomedical applications

open access: yesJournal of the Pakistan Medical Association
Objective: To study the optical properties of nanocomposites as well as antibacterial activity. Method: The experimental study was conducted at the University of Babylon, College of Science and College of Education for Pure Sciences, Babylon, Iraq, from
Sroor Fadhil Obaid, Raheem Kadhim
doaj   +1 more source

Dynamic Control of Nucleic Acids Self‐Assembly and Expression Using Photoswitches

open access: yesChemistry – A European Journal, EarlyView.
We review here the recent progress made in the design of molecular photoswitches, and highlight their implementation for the dynamic control over nucleic acids self‐assembly and expression. ABSTRACT Synthetic nucleic acids have become readily available and now constitute versatile building blocks in materials science—where they can be used to engineer ...
Noemí Nogal   +4 more
wiley   +1 more source

A concise approach to functionalised, homochiral pyrrolidinones

open access: yesTetrahedron: Asymmetry, 1995
Abstract Acylation of O , N -acetal 1 gives excellent yields of the C-7 substituted products 2a,b . Alkylation of 2a under mild conditions gives high yields of the exo- 3 and endo- 4 substituted products in varying ratios, depending on the alkylating agent.
Bamford, M   +3 more
openaire   +1 more source

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