Results 41 to 50 of about 150,397 (174)

Una reacción multicomponente verde en el laboratorio de química orgánica

open access: yesEducación Química, 2018
En este siglo, los químicos se han encontrado con un nuevo desafío: producir de manera eficiente los materiales necesarios para mantener la calidad de vida de los seres vivos, reduciendo los efectos negativos sobre el medio ambiente y la salud humana. En
Mariana Ingold   +3 more
doaj   +1 more source

A sequential multistep process for the fully mechanochemical, one-pot synthesis of the antiepileptic drug rufinamide

open access: yesGreen Chemistry Letters and Reviews, 2022
Mechanochemistry is a powerful tool to develop environmentally benign syntheses of active pharmaceutical ingredients. In this context, we report here the synthesis of the anti-epileptic agent rufinamide through a one-pot sequential multi-component ...
Jorge Gómez-Carpintero   +4 more
doaj   +1 more source

Candida antarctica lipase-catalyzed synthesis and characterization of novel acrylic teroligomers [PDF]

open access: yes, 2018
The synthesis of three novel low molecular weight acrylic terpolymers, containing at random sequences of ethyl acrylate, acrylic acid and N-(2-hydroxyethyl)acrylamide, catalyzed by Candida antarctica lipase was successfully conducted in organic media ...
Baldessari, Alicia   +4 more
core  

Counterintuitive Fluorescence Blue Shift in Symmetry Breaking Dicationic Bis(indolium) with Two‐Photon Absorption Properties for NIR Living Cell Imaging

open access: yesAdvanced Materials, EarlyView.
Highly water‐soluble dicationic bis(indolium) dyes have been prepared, showing excellent two‐photon absorption and light emission. Their fluorescence behavior discloses an unusual increasing blue shift with increasing solvent polarity, which, in parallel, is beneficial for enhanced detection in biological media.
Carlos Benitez‐Martin   +5 more
wiley   +1 more source

Spatially Resolved Monitoring of Drying of Hierarchical Porous Organic Networks [PDF]

open access: yes, 2016
Evaporation kinetics of water confined in hierarchal polymeric porous media is studied by low field nuclear magnetic resonance (NMR). Systems synthesized with various degrees of cross-linker density render networks with similar pore sizes but different ...
Acosta, Rodolfo Hector   +7 more
core   +1 more source

Self‐Cooling Molecular Spin Qudits

open access: yesAdvanced Materials, EarlyView.
A material made of [GdEr] molecular dimers can encode a qudit and perform as a magnetic refrigerant. Microwave resonant pulses coherently manipulate its 16 spin states, while direct demagnetization measurements cool the material and a device down to temperatures below 1 K.
Elías Palacios   +12 more
wiley   +1 more source

Electrochemical heteroarylation and amidation of alkanes using activated glassy carbon electrodes without mediators

open access: yesCommunications Chemistry
The functionalization of challenging unactivated C(sp 3)–H bonds was achieved electrocatalytically via hydrogen atom transfer and without mediators. This was possible through the sole activation of the surface of the Glassy Carbon Electrode (GCE) in an ...
Loris Laze   +2 more
doaj   +1 more source

A Cu‐Based Near‐IR Active MOF with an Ion‐Pair Guest Exhibiting Versatile and Selective Gas‐Solid Reactivity

open access: yesAdvanced Materials, EarlyView.
The new Cu‐containing MOF (Me2NH2)(CuICl2)@[Cu4(INA)4Cl2O]·1.5dmf (3) contains a cation and an anion as guests and shows UV‐near‐mid‐IR absorption and near‐IR emission. MOF 3 shows gas‐solid reactivity in the presence of NH3 and HCOOH to yield two new 3D MOF.
Rajat Saha   +10 more
wiley   +1 more source

Chiral Imidazolium Prolinate Salts as Efficient Synzymatic Organocatalysts for the Asymmetric Aldol Reaction

open access: yesMolecules, 2021
Chiral imidazolium l-prolinate salts, providing a complex network of supramolecular interaction in a chiral environment, have been studied as synzymatic catalytic systems.
Raúl Porcar   +4 more
doaj   +1 more source

Guía Pedagógica: Química Orgánica [PDF]

open access: yes, 2015
Guía ...
Avila Cordoba Liliana Ivette
core  

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