Results 41 to 50 of about 151,662 (178)

A Cu‐Based Near‐IR Active MOF with an Ion‐Pair Guest Exhibiting Versatile and Selective Gas‐Solid Reactivity

open access: yesAdvanced Materials, EarlyView.
The new Cu‐containing MOF (Me2NH2)(CuICl2)@[Cu4(INA)4Cl2O]·1.5dmf (3) contains a cation and an anion as guests and shows UV‐near‐mid‐IR absorption and near‐IR emission. MOF 3 shows gas‐solid reactivity in the presence of NH3 and HCOOH to yield two new 3D MOF.
Rajat Saha   +10 more
wiley   +1 more source

Tandem cross enyne metathesis (CEYM)–intramolecular Diels–Alder reaction (IMDAR). An easy entry to linear bicyclic scaffolds

open access: yesBeilstein Journal of Organic Chemistry, 2015
A new tandem cross enyne metathesis (CEYM)–intramolecular Diels–Alder reaction (IMDAR) has been carried out. It involves conjugated ketones, esters or amides bearing a remote olefin and aromatic alkynes as the starting materials.
Javier Miró   +5 more
doaj   +1 more source

INFLUENCIA DEL CATALIZADOR DE TRANSFERENCIA DE FASES EN LA SÍNTESIS DE HIDROXIMETILFURFURAL (HMF)

open access: yesAvances en Ciencias e Ingeniería, 2019
Se presenta la síntesis de 5-hidroximetilfurfural (HMF) empleando condiciones de la química verde, el cual se obtiene a través de la reacción de deshidratación de la fructosa empleando un catalizador ácido y un catalizador de transferencia de fase.
Martha Menes-Arzate   +5 more
doaj  

Synthesis and Characterization of New Functionalized 1,2,3-Triazole-Based Acetaminophen Derivatives via Click Chemistry from Expired Commercial Acetaminophen Tablets

open access: yesReactions, 2023
We hereby describe an efficient method for the preparation of a series of new 1-substituted 1,2,3-triazole-based acetaminophen derivatives through a clean, good-yielding, simple, and expeditious procedure based on the O-propargylation reaction of the ...
Vladimir V. Kouznetsov   +2 more
doaj   +1 more source

Withanolides and related steroids [PDF]

open access: yes, 2011
Since the isolation of the first withanolides in the mid-1960s, over 600 new members of this group of compounds have been described, with most from genera of the plant family Solanaceae.
A Bhattacharya   +251 more
core   +1 more source

Arene Incorporation and Ring Expansion in the Thermal Decomposition of a Divanadium(III) Complex With Four Bridging Methyl Groups

open access: yesChemistry – A European Journal, EarlyView.
Thermolysis of [{VCp*(µ‐CH3)2}2] (Cp* = η5‐C5Me5) in hexane leads to a tetranuclear cube‐type methylidene complex [{VCp*(µ3‐CH2)}4], while in benzenic solvents C6H5R produces the formal insertion of a CH fragment into the six‐membered aromatic ring of a solvent molecule to give trovacene derivatives with η7‐cycloheptatrienyl ligands [VCp*(η7‐C7H6R ...
Adrián Calvo‐Molina   +5 more
wiley   +1 more source

Nitrogen-Rich Multinuclear Ferrocenophanes as Multichannel Chemosensor Molecules for Transition and Heavy-Metal Cations

open access: yesSensors, 2014
[m.n] Multinuclear ferrocenophanes prepared by aza-Wittig reaction of bisiminophosphoranes derived from 1,1'-diazidoferrocene and isophthaladelhyde or 2,5-diformylthiophene, behave as efficient electrochemical and chromogenic chemosensor molecules for ...
Antonia Sola   +3 more
doaj   +1 more source

Transition Metal-Free Synthesis of Halobenzo[b]furans from O-Aryl Carbamates via o-Lithiation Reactions

open access: yesMolecules, 2022
A straightforward and transition metal-free one-pot protocol to synthesize halobenzo[b]furans has been developed employing simple and easily available starting materials such as O-aryl carbamates and alkynylsulfones.
Claudia Feberero   +5 more
doaj   +1 more source

Candida antarctica lipase-catalyzed synthesis and characterization of novel acrylic teroligomers [PDF]

open access: yes, 2018
The synthesis of three novel low molecular weight acrylic terpolymers, containing at random sequences of ethyl acrylate, acrylic acid and N-(2-hydroxyethyl)acrylamide, catalyzed by Candida antarctica lipase was successfully conducted in organic media ...
Baldessari, Alicia   +4 more
core  

Human Heme Oxygenase Oxidation of 5- and 15-Phenylhemes [PDF]

open access: yes, 2004
Human heme oxygenase-1 (hHO-1) catalyzes the O2- dependent oxidation of heme to biliverdin, CO, and free iron. Previous work indicated that electrophilic addition of the terminal oxygen of the ferric hydroperoxo complex to the -meso-carbon gives 5 ...
Alvarez, Diego Ezequiel   +7 more
core   +1 more source

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