Results 81 to 90 of about 108,024 (198)

Structural Features and Reaction Profile of an Evolved Unspecific Peroxygenase From Candolleomyces Aberdarensis

open access: yesAdvanced Synthesis &Catalysis, Volume 368, Issue 9, 5 May 2026.
Fungal unspecific peroxygenases (UPOs) are promiscuous heme‐containing enzymes that selectively oxyfuntionalize C‐H bonds. Structural and enzymatic reaction studies of an evolved UPO mutant from Candolleomyces (Psathyrella) aberdarensis (PabUPO‐I) reveal how the heme channel architecture dictates the regioselectivity towards alkanes, fatty acids and ...
Andrea Menés‐Rubio   +6 more
wiley   +1 more source

Bioactive Secondary Metabolites from Phomopsis sp., an Endophytic Fungus from Senna spectabilis

open access: yesMolecules, 2014
Chemical investigation of an acetonitrile fraction from the endophytic fungus Phomopsis sp. led to the isolation of the new natural product 2-hydroxy-alternariol (7) together with the known compounds cytochalasins J (1) and H (2), 5'-epialtenuene (3) and
Vanessa Mara Chapla   +10 more
doaj   +1 more source

Tuning the Twist by Molecular Design: A New Strategy for Hexabenzocoronene‐Containing Helical Twistacene

open access: yesChemistry – A European Journal, Volume 32, Issue 17, 5 May 2026.
An efficient Scholl–based strategy enables precise control of the C–C bond to access the first hexabenzocoronene–containing helical twistacene (NG2). The resulting nanographene shows pronounced helical distortion, high stability, enhanced solubility, and promising redox and optoelectronic properties.
Juan P. Mora‐Fuentes   +8 more
wiley   +1 more source

Dinâmica da matéria orgânica no ambiente. [PDF]

open access: yes, 2013
bitstream/item/32409/1/documento-105 ...
MARTIN NETO, L.   +2 more
core  

Carbamate‐Directed peri‐CH Alkynylation: Application to the Synthesis of Zethrenes and Pyranthrenes

open access: yesChemistryEurope, Volume 4, Issue 5, May 2026.
The Rh(III)‐catalyzed regioselective alkynylation of 1‐pyrenyl and 1‐naphthyl carbamates with bromoacetylenes enables the selective installation of an alkyne at the peri position of readily accessible amino‐substituted polycyclic aromatic hydrocarbons (PAHs).
Xiaoqing Shao   +4 more
wiley   +1 more source

Efficient access to β-vinylporphyrin derivatives via palladium cross coupling of β-bromoporphyrins with N-tosylhydrazones

open access: yesBeilstein Journal of Organic Chemistry, 2017
This work describes a new approach to obtain new β-vinylporphyrin derivatives through palladium-catalyzed cross-coupling reaction of 2-bromo-5,10,15,20-tetraphenylporphyrinatozinc(II) with N-tosylhydrazones.
Vinicius R. Campos   +5 more
doaj   +1 more source

Avaliação de parâmetros físicos e químicos do efluente de uma Grande indústria frigorífica de aves [PDF]

open access: yes, 2006
TCC (graduação) - Universidade Federal de Santa Catarina. Centro de Ciências Físicas e Matemáticas. Curso de Química.As indústrias frigoríficas de aves geram uma grande quantidade de efluentes líquidos com elevada concentração de poluentes, necessitando ...
MORÉS, Silvane
core  

Quantifying Carboxylate Burial in Synthetic Hydrophobic Pockets in Water

open access: yesChemistryEurope, Volume 4, Issue 5, May 2026.
How “buried” is a buried ion? Double mutant cycles quantify the cost of placing a carboxylate within a deep aromatic calix[4]pyrrole pocket in water. The penalty is only +1.3 to +3.0 kcal·mol−1 because water penetrates through cracks and the portal, creating a wet, high‐dielectric microenvironment.
Esteban A. Valencia   +4 more
wiley   +1 more source

Carboxyxanthones: Bioactive Agents and Molecular Scaffold for Synthesis of Analogues and Derivatives

open access: yesMolecules, 2019
Xanthones represent a structurally diverse group of compounds with a broad range of biological and pharmacological activities, depending on the nature and position of various substituents in the dibenzo-γ-pyrone scaffold.
João Ribeiro   +4 more
doaj   +1 more source

Contribuição ao estudo das características físico-químicas e da fração lipídica do leite orgânico. [PDF]

open access: yes, 2008
Produtos orgânicos consistem em uma alternativa para uma alimentação saudável. Considera-se leite orgânico aquele produzido em sistema no qual é vedado o uso de agrotóxico sintético ou outros insumos artificiais tóxicos e organismos geneticamente ...
Almeida, Keila Emílio de   +6 more
core   +3 more sources

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