Results 171 to 180 of about 3,381,508 (304)

Hyperfine-Resolved Spectroscopy of Dysprosium Monoxide (DyO). [PDF]

open access: yesJ Phys Chem A
Lasner ZD   +7 more
europepmc   +1 more source

T½ Tuning in a Synergistic BODIPY‐Tetrazole Fe(II) Spin‐Crossover‐Photoluminescence System via Co‐Ligand Variation

open access: yesChemistry – A European Journal, EarlyView.
We report a modular spin crossover‐photoluminescence (SCO‐PL) system: heteroleptic, mononuclear Fe(II) coordination compounds bearing equatorial BODIPY fluorophores that exhibit synergistic PL response upon spin state switching. Exchanging apical nitrile co‐ligands tunes electronic and structural properties, giving precise control over the SCO and PL ...
Martin Huber   +4 more
wiley   +1 more source

Methyl on the Bridge: 2‐Methyl Propellane as Precursor for 1,3‐Substituted 2‐Methylated Bicyclo[1.1.1]Pentanes

open access: yesChemistry – A European Journal, EarlyView.
The synthesis of 2‐methyl propellane and its conversion to various 1,2‐ and 1,2,3‐di‐ and trisubstituted bicyclopentanes is reported. Abstract Bicyclo[1.1.1]pentanes (BCPs) have emerged as isosteric replacements for mono‐ and para‐substituted benzene rings in medicinal and materials applications, involving substitution at the BCP bridgehead (1,3 ...
Sean R. Verschaeve   +4 more
wiley   +1 more source

Probing the Influence of Sulfur–Aromatic Interactions on the Electronic Structure of Gas‐Phase Peptides

open access: yesChemistry – A European Journal, EarlyView.
Just as fingerprints reveal identity, spectroscopic fingerprints reveal molecular secrets. In this article, we show parts of the unique fingerprint of the sulfur–aromatic interaction. By measuring how this force alters the electronic structure of gas‐phase peptides, we provide a fundamental understanding of interactions that give insights into the ...
Laura Pille   +12 more
wiley   +1 more source

Enlarging Quantum Coherence of Vanadyl Spin Qubits in Zirconium Porphyrinic MOFs. [PDF]

open access: yesInorg Chem
Vujević L   +7 more
europepmc   +1 more source

Better Material Properties and Faster Catalyzed Chemical Recycling for Poly(L‐Lactide) Using a Simple Commercial Glycerol Ethoxylate Additive

open access: yesChemistry – A European Journal, EarlyView.
Glycerol ethoxylate (GEO), a branched ethylene glycol derivative, both toughens commercial PLLA and accelerates its chemical recycling to L‐lactide. The lead sample, containing 10 wt.% GEO, shows 9x higher elongation at break and 6x higher tensile toughness than pure PLLA. The GEO–PLLA samples are efficiently chemically recycled to L‐lactide, even when
Madeleine L. Smith   +4 more
wiley   +1 more source

A cryogenic Paul trap for probing the nuclear isomeric excited state 229 m Th 3 + . [PDF]

open access: yesEur Phys J D At Mol Opt Phys
Moritz D   +18 more
europepmc   +1 more source

A Novel Heterometallic Ring {Cr5Ni3} and New {Cr6Co2} and {Cr6Zn2} Rings

open access: yesChemistry – A European Journal, EarlyView.
A novel heterometallic ring containing five Cr(III) and three Ni(II) centers is reported. It forms an octagon and has a single isomer, as revealed by a combination of magnetic and EPR studies and collision‐induced dissociation mass spectrometry. ABSTRACT A new heterometallic ring, [Me4N][(Me4N)2Cr5Ni3F8(BTFB)16] (BTFB = 3,5‐bis(trifluoromethyl)benzoate)
Abdulelah Alsuhaymi   +9 more
wiley   +1 more source

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