Quasireversible cyclic voltammetry of a surface confined redox system: a mathematical treatment
Electrochemistry Communications, 2005 By removing complications caused by transport, the surface confinement of substrate and product members of a redox pair simplifies the relationships governing transient electrode reactions, often permitting a mathematical solution even when the voltammetry is kinetically controlled.
Jan C. Myland, Keith B. Oldham
openaire +1 more source
High Potential Isoindoline‐Based Nitroxides Posolytes for Aqueous Organic Redox Flow Batteries
ChemSusChem, Volume 19, Issue 3, February 2026.A convenient metal‐catalyzed [2 + 2 + 2] cycloaddition enables the synthesis of isoindoline‐based nitroxides as new posolytes for aqueous organic redox flow batteries. The cationic PPO exhibits a 220 mV higher oxidation potential than 4‐TMA‐TEMPO, 3 M solubility in 1 M NaCl, and a cell voltage of 1.56 V.
Karim Boutamine +8 more
wiley +1 more source
Sample path large deviations for multiclass feedforward queueing networks in critical loading
, 2007 We consider multiclass feedforward queueing networks with first in first out and priority service disciplines at the nodes, and class dependent deterministic routing between nodes. The random behavior of the network is constructed from cumulative arrival
Majewski, Kurt
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A Quasi-Boundary Semi-Analytical Approach for Two-Dimensional Backward Advection-Dispersion Equation [PDF]
, 2010 In this study, we employ a semi-analytical approach to solve a two-dimensional advection-dispersion equation (ADE) for identifying the contamination problems. First, the Fourier series expansion technique is used to calculate the concentration field C(x,
Chein-Shan Liu, Chih-Wen Chang
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Zeitschrift für anorganische und allgemeine Chemie, Volume 652, Issue 1, January 6, 2026.Asymmetrically substituted Jäger‐type ligands and their Fe(II) complexes show additive optical and redox trends. Ketone donors promote spin‐crossover while ester donors stabilize the high‐spin state, yet bulk materials display unexpected transitions governed by molecular symmetry and packing. A series of seven new asymmetrically substituted Jäger‐type (
Constantin Schreck +4 more
wiley +1 more source
Modified quasi-reversibility method for nonautonomous semilinear problems
Electronic Journal of Differential Equations, 2013 We prove regularization for the ill-posed, semilinear evolution problem $du/dt=A(t, D)u(t)+h(t, u(t))$, $0 leq s leq t < T$, with initial condition $u(s)=chi$ in a Hilbert space where D is a positive, self-adjoint operator in the space.
Matthew A. Fury
doaj
Multielectron Redox Chemistry of Transition Metal Complexes Supported by a Non‐Innocent N3P2 Ligand: Synthesis, Characterization, and Catalytic Properties [PDF]
, 2018 A new redox‐active, diarylamido‐based ligand (LN3P2) capable of κ5‐N,N,N,P,P chelation has been used to prepare a series of complexes with the general formula [MII(LN3P2)]X, where M = Fe (1; X = OTf), Co (2; X = ClO4), or Ni (3; X = ClO4).
Ekanayake, Danushka M. +4 more
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On recovering parabolic diffusions from their time-averages [PDF]
, 2019 The paper study a possibility to recover a parabolic diffusion from its time-average when the values at the initial time are unknown. This problem can be reformulated as a new boundary value problem where a Cauchy condition is replaced by a prescribed ...
Dokuchaev, Nikolai
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Mind the Solid Side: Electrochemical Thermodynamics, Kinetics, and Hysteresis in Energy Materials
ChemElectroChem, Volume 13, Issue 1, January 2026.This mini‐review presents the electrochemical thermodynamics, kinetics, and hysteresis in solid‐to‐solid electrochemical phase transformation under three distinct categories of regular solutions, Fickian diffusion models, and spinodal decomposition. It highlights the role of electrochemical modeling combined with galvanostatic and cyclic voltammetry ...
Keyvan Malaie
wiley +1 more source
A New Quasi-Boundary Scheme for Three-Dimensional Backward Heat Conduction Problems [PDF]
, 2011 In this study, we employ a semi-analytical scheme to resolve the three-dimensional backward heat conduction problem (BHCP) by utilizing a quasi-bound -ary concept.
Chih-Wen Chang
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