Results 211 to 220 of about 1,871,225 (278)

Electron‐Rich Para‐Methylpyridine‐Functionalized TEMPO Empowers Long‐Lived Neutral Aqueous Organic Redox Flow Batteries

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Three methylpyridine‐functionalized TEMPOs were synthesized through an electron‐rich regulation strategy. The calculation of transition states supported the highest reaction efficiency of para‐MePy‐TEMPOs, which outperformed its analogues to have the best performance of AORFBs, opening a new avenue for exploring TEMPO‐based catholytes.
Shaopeng Wang   +10 more
wiley   +1 more source

Fire‐Safe Polymeric Insulation Foams for Energy‐Efficient and Low‐Carbon Buildings

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This review systematically summarizes recent advances in fire‐safe polymeric insulation foams, emphasizing the balance among flame retardancy, thermal insulation, mechanical reliability, and long‐term durability. By linking material‐level thermophysical properties with building cooling‐energy demand and operational carbon emissions, it establishes a ...
Qinhe Guo   +10 more
wiley   +1 more source

Synthesis of Zwitterionic Tris(pyrazolyl) Ligands and Their Mn(II) Bis‐Chelates Exhibiting Charge–Transfer‐Induced Spin Crossover

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
In this article, a series of zwitterionic scorpionate ligands based on the anionic tris‐(pyrazolyl)borate ligand scaffold is presented. These ligands are used to prepare bis‐chelates with divalent manganese ions. The resulting complexes are studied via magnetic, crystallographic, and electrochemical means to characterize the charge–transfer‐induced ...
Matthew C. Kessinger   +5 more
wiley   +1 more source

Asymmetric Synthesis of Tertiary α‐Aryl Stereocentres in Tetrahydro‐4H‐pyran‐4‐ones Using Pd‐Catalyzed Decarboxylative Asymmetric Protonation

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
The Pd‐catalyzed decarboxylative asymmetric protonation (DAP) has been developed for sterically hindered tetrahydro‐4H‐pyran‐4‐one derived α‐aryl‐β‐keto esters. A substrate scope of nine examples of DAP showed that substrates containing a di‐ortho methoxy substitution pattern on the aryl ring gave rise to the highest enantioselectivities of up to 85 ...
Fionn McNeill   +5 more
wiley   +1 more source

π‐Extended Silyl Enolates as Emerging Platforms in Radical Chemistry

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
This review covers the emerging role of π‐extended silyl polyenol ethers in radical chemistry. It highlights their versatile roles as electron‐rich SOMOphiles, silyl radical cation precursors, and nucleophilic partners in radical–polar crossover manifolds, while considering recent advances in photoredox catalysis, electrochemistry, and transition metal‐
Debora Guazzetti   +3 more
wiley   +1 more source

MXene‐Induced Selective Ion Separation in Capacitive Deionization: Bridging Fundamentals With Frontier Innovations

open access: yesElectron, EarlyView.
This review presents an in‐depth analysis of employing the MXenes electrodes in advancing ion‐selective capacitive deionization technologies, by exploring various strategies to achieve the desired selectivity. It highlights the critical challenges that hinder scalability and practical implementation. The review showcases the future opportunities toward
Rahat Alam   +3 more
wiley   +1 more source

The gut microbiome and drug‐resistant epilepsy: Microbiome–antiseizure medication interactions and implications for pharmacoresistance

open access: yesEpilepsia Open, EarlyView.
Abstract Drug‐resistant epilepsy (DRE) affects approximately one‐third of patients with epilepsy and represents a major unmet clinical need. While traditional hypotheses of pharmacoresistance have focused on alterations in drug targets, efflux transporter overexpression, and intrinsic disease severity, the gut microbiome has recently emerged as a ...
Khaled Zammar   +4 more
wiley   +1 more source

Strategies for Identification and Mitigation of Sanguinarine in Mustard Oil Adulterated by Argemone—A Comprehensive Review

open access: yesFood Chemistry International, EarlyView.
Sanguinarine, a toxic alkaloid present in argemone, can lead to epidemic dropsy or chronic diseases through DNA intercalation and immune system suppression. Regulatory efforts face challenges due to economic motivations for adulteration as well as technical, social, and infrastructure barriers.
Gururaj Pejavara Narayana   +4 more
wiley   +1 more source

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