Results 201 to 210 of about 26,162 (241)
The linear and nonlinear (chir)optical properties of four oligoamide foldamers with different donor groups are studied by means of time‐dependent density functional theory calculations. It is shown that stronger donors yield larger hyperpolarizabilities due to low‐lying charge–transfer states. The agreement with the experiments concerning the key bands
Komlanvi Sèvi Kaka +5 more
wiley +1 more source
Rh(III)-Catalyzed Regioselective [4 + 2] Annulation of 2-Benzyl-2H-indazole-6-carboxylic Acids with Ynamides to Access Indazole-Fused Pyrans. [PDF]
Hsieh HS +4 more
europepmc +1 more source
Skeletal Editing from Pyridine to Aniline via C‐Insertion and N‐Isomerization
A concise protocol is presented that converts pyridines into anilines by externalizing the original pyridine nitrogen at either the "ipso" or "ortho" position, which results in para or meta‐primary aniline products. A key carbene‐insertion step precedes nitrogen migration, preserving both ring size and overall structure.
Yun Luo +3 more
wiley +1 more source
Identification of sulfonylated indolo[1,2-a]quinolines as EGFR tyrosine kinase inhibitors. [PDF]
Phetcharawetch J +7 more
europepmc +1 more source
We report a biosynthesis‐inspired ring distortion approach that involves oxidative ring cleavage, ring rearrangement, and ring expansion reactions from a diverse collection of indole alkaloids and derivatives. This chemical synthesis approach led to the synthesis of >25 distinct chemotypes from 14 indole alkaloids.
Derek A. Leas +7 more
wiley +1 more source
Synthesis of 2‑Quinolones via Thiolate-Mediated Cyclization of (<i>E</i>)‑2-Aminocinnamic Acid Derivatives. [PDF]
Kim TW, Goh NM, Cheon CH.
europepmc +1 more source
This review summarizes recent advances in copper‐ and silver‐catalyzed reactions of active methylene isocyanides for the synthesis of highly substituted five‐ and six‐membered heterocycles. Emphasis is placed on [3+n] cycloadditions, annulations, and asymmetric strategies, highlighting current limitations and future opportunities in heterocycle ...
Jimil George, Kyungsoo Oh
wiley +1 more source
The triglyceride-glucose index shows promise as a novel prognostic marker for advanced hepatocellular carcinoma. [PDF]
Xu T, Qi X, Zhao FY, Qian NS.
europepmc +1 more source
A modular late‐stage manifold exploits the embedded alkyne of alkynylbicyclo[1.1.0]butanes (ABCBs) to deliver triazole‐, isoxazole‐, free‐NH‐pyrrole, free‐NH‐pyrazole, or silacyclohexene‐decorated BCBs in a single operation. Strain‐release transformations of bicyclo[1.1.0]butanes are powerful methods for constructing four‐membered rings and bicyclo[n.1.
Yu‐Jie Li +3 more
wiley +1 more source

