Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley +1 more source
Predicting the Redox Potentials and Hammett Parameters of Quinone Derivatives with the Information-Theoretic Approach. [PDF]
Xu M +6 more
europepmc +1 more source
A Mononuclear Scenario for the Copper‐Catalyzed Monooxygenation of Phenolic Substrates
ABSTRACT Whereas a dinuclear pathway applies to the monooxygenation of phenols by the type 3 copper enzyme tyrosinase, a mononuclear pathway has been identified for the same reaction in corresponding small‐molecule systems. DFT calculations of five copper model complexes reveal that the latter mechanism is energetically feasible, identifying all ...
Alexander Koch +3 more
wiley +1 more source
Oxygenation and Oxidation of Lignin Model Dimers by Fungal <i>Ortho</i>-Methoxyphenolases. [PDF]
de Oliveira Gorgulho Silva C +10 more
europepmc +1 more source
Tailored Biochar-<i>Pseudomonas chlororaphis</i> Composites for Triclocarban Removal: A Feedstock-Dependent Structure-Interface-Metabolism Study. [PDF]
Wang C +5 more
europepmc +1 more source
Derivatization-assisted dual-mode colorimetric and fluorometric detection of dopamine using 4-hexyl resorcinol. [PDF]
Goda MN +6 more
europepmc +1 more source
Characterization of a membrane-bound PQQ-dependent D-lactate dehydrogenase in Gluconobacter japonicus. [PDF]
Kataoka N +5 more
europepmc +1 more source
Comprehensive review on environmental pollution caused by 6PPD-quinone and remediation strategies. [PDF]
Sivalingam S +4 more
europepmc +1 more source

