Results 181 to 190 of about 66,627 (253)

Shedding Light on Synthetic Autocatalysis: From Conventional Closed‐Shell Chemistries to Overlooked Open‐Shell Occurrences

open access: yesChemistry – A European Journal, EarlyView.
Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley   +1 more source

A Mononuclear Scenario for the Copper‐Catalyzed Monooxygenation of Phenolic Substrates

open access: yesChemistry – A European Journal, EarlyView.
ABSTRACT Whereas a dinuclear pathway applies to the monooxygenation of phenols by the type 3 copper enzyme tyrosinase, a mononuclear pathway has been identified for the same reaction in corresponding small‐molecule systems. DFT calculations of five copper model complexes reveal that the latter mechanism is energetically feasible, identifying all ...
Alexander Koch   +3 more
wiley   +1 more source

Oxygenation and Oxidation of Lignin Model Dimers by Fungal <i>Ortho</i>-Methoxyphenolases. [PDF]

open access: yesJ Am Chem Soc
de Oliveira Gorgulho Silva C   +10 more
europepmc   +1 more source

Characterization of a membrane-bound PQQ-dependent D-lactate dehydrogenase in Gluconobacter japonicus. [PDF]

open access: yesAppl Microbiol Biotechnol
Kataoka N   +5 more
europepmc   +1 more source

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