Enantioselective Route to Terminal 2,3-Epoxy Tosylates Enabled by Cooperative Organocatalytic Desymmetrization of 2-Substituted Glycerol Derivatives. [PDF]
Astone A, Meninno S, Lattanzi A.
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Enantioselective cyclization of bromoenynes: mechanistic understanding of gold(i)-catalyzed alkoxycyclizations. [PDF]
Cataffo A +10 more
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Asymmetric synthesis of stereogenic-at-sulfur compounds via biocatalytic oxidation with Unspecific Peroxygenases. [PDF]
Li J +6 more
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Chiral phosphoric acid-catalyzed asymmetric synthesis of helically chiral, planarly chiral and inherently chiral molecules. [PDF]
Liu W, Yang X.
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(±)-Rutacycoumarins A and B: two pairs of unprecedented coumarin enantiomers from the aerial part of <i>Ruta graveolens</i> L. and chemically synthesized. [PDF]
Feng X +10 more
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Total syntheses of ent-aogacillin A and aogacillin B. [PDF]
Gu H +12 more
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A new method of resolving a racemic compound [26]
Karagunis, G., Coumoulos, G.
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Racemic Compound, Conglomerate, or Solid Solution: Phase Diagram Screening of Chiral Compounds
Crystal Growth & Design, 2010Crystallization in racemic solutions usually results in a racemic compound, a conglomerate or a solid solution. Resolution of a chiral compound strongly depends on the kind of solid state that it forms. Solid−liquid equilibria are related to the prevailing solid state of the chiral compound.
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