Results 31 to 40 of about 23,430 (289)

Asymmetric racemic compound 143-A7d. Raw diffraction data, 6ZX8

open access: yes, 2020
Raw diffraction data of asymmetric racemic compound 143-A7d ...
Rypniewski, Wojciech   +3 more
core   +1 more source

(1S*,5R*)-9-Phenyl-9-azabicyclo[3.3.1]nonan-3-one

open access: yesActa Crystallographica Section E, 2012
In the title compound, C14H17NO, the piperidinone and piperidine rings both adopt a chair conformation. The chiral crystals were obtained from a racemic reaction product via spontaneous resolution.
Zhen-ju Jiang   +3 more
doaj   +1 more source

The Heats of Solution of Optically Active Compounds and the Corresponding Racemic Compounds [PDF]

open access: yesBulletin of the Chemical Society of Japan, 1980
Abstract The heats of solution of crystalline amino acids and hydroxy acid in water at 298.15 K were measured with a twin isoperibol calorimeter. It was found, as was expected from the theory, that the difference in the heat of solution between optically active compounds and their corresponding racemic compounds was appreciably large ...
Masayuki Matsumoto, Kazuo Amaya
openaire   +1 more source

rac-Ethyl 3-(3-bromo-2-thienyl)-2-oxo-6-(4-propoxyphenyl)cyclohex-3-ene-1-carboxylate

open access: yesActa Crystallographica Section E, 2008
The racemic title compound, C22H23BrO4S, crystallizes with two molecules in the asymmetric unit. The dihedral angles between the thiophene and phenyl rings are 71.64 (17) and 73.41 (17)°.
Andreas Fischer   +3 more
doaj   +1 more source

[2,2′-Bis(diphenylphosphanyl)-1,1′-binaphthyl-κ2P,P′]dichloridoplatinum(II) acetonitrile trisolvate

open access: yesIUCrData, 2020
The crystal structure (150 K) of the racemic title compound, [PtCl2(C44H32P2)]·3CH3CN, has been determined. The asymmetric unit comprises a single molecule of the title compound co-crystallized with three acetonitrile solvent molecules.
Jason D. Braun   +2 more
doaj   +1 more source

Synthesis, Spectral and Solid State Characterization of a New Bioactive Hydrazine Bridged Cyclic Diphosphonium Compound

open access: yesMolecules, 2012
The facile preparation of a racemic hydrazine bridged diphosphonium compound possessing a ring system analogous to bicyclo[3.3.2]decane is reported. Although the reaction yield is low, the structure of the compound, which possesses an eight-membered ring,
Miroslava Vujčić   +7 more
doaj   +1 more source

3-(2,2-Dioxo-3,4-dihydrobenzo[e][1,2,3]oxathiazin-4-yl)-3-fluoro-1-phenylindolin-2-one

open access: yesIUCrData, 2020
The title compound, C21H15FN2O4S, contains two chiral carbon centres, but crystal symmetry generates a racemic mixture. The crystal structure features N—H...O hydrogen bonding. The sulfonate group is disordered with an occupancy ratio of 0.933 (4):0.067 (
Mei-Fang Wu, Ling-Yan Chen, Ya Li
doaj   +1 more source

3-(2-Amino-1-methyl-4-oxo-4,5-dihydro-1H-imidazol-5-yl)-3-hydroxy-1-phenylindolin-2-one ethanol solvate

open access: yesActa Crystallographica Section E, 2009
In the title compound, C18H16N4O3·C2H5OH, molecules are linked into chains by a series of intermolecular N—H...O, N—H...N and O—H...O hydrogen bonds which stabilize the crystal structure.
Narsimha Reddy Penthala   +3 more
doaj   +1 more source

Non-Linear Effects in Asymmetric Reactions: Negative and Positive Stereoselectivity in the Formation of Homoleptic 1:2 Metal to Ligand Complexes of Chiral 1,9-Disubstituted Semicorrin Ligands

open access: yesCHIMIA, 2003
The stereoselectivity of the formation of bis-chelates with the 1,9-disubstituted chiral semicorrin ligands (1S,9S)-dimethyl 5-cyanosemicorrin-1,9-dicarboxylate (1) for Co2+, Ni2+, Cu2+, and Pd2+ and with its (1S,9S)-diethyl analogue 2 for Co2+
Nathalie Guicher   +2 more
doaj   +1 more source

3,3,6-Tribromo-1-methyl-1H-2,1-benzothiazin-4(3H)-one 2,2-dioxide

open access: yesActa Crystallographica Section E, 2010
In the title compound, C9H6Br3NO3S, a halogenated benzothiazine derivative, the thiazine ring adopts a sofa conformation. The crystal studied was a racemic twin with a contribution of 72 (1)% of the major domain.
Ghulam Mustafa   +3 more
doaj   +1 more source

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