Results 31 to 40 of about 775,231 (229)

Non-Linear Effects in Asymmetric Reactions: Negative and Positive Stereoselectivity in the Formation of Homoleptic 1:2 Metal to Ligand Complexes of Chiral 1,9-Disubstituted Semicorrin Ligands

open access: yesCHIMIA, 2003
The stereoselectivity of the formation of bis-chelates with the 1,9-disubstituted chiral semicorrin ligands (1S,9S)-dimethyl 5-cyanosemicorrin-1,9-dicarboxylate (1) for Co2+, Ni2+, Cu2+, and Pd2+ and with its (1S,9S)-diethyl analogue 2 for Co2+
Nathalie Guicher   +2 more
doaj   +1 more source

Synthesis and crystal structure of (±)-Goniotamirenone C

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2020
The structure of the racemic version of the natural product Goniotamirenone C [racemic anti-6-(2-chloro-1-hydroxy-2-phenylethyl)-2H-pyran-2-one, C13H11ClO3] at 150 K is reported. The compound crystallizes with monoclinic (P21/n) symmetry and with Z′ = 2.
Pornphimol Meesakul   +3 more
doaj   +1 more source

3,3,6-Tribromo-1-methyl-1H-2,1-benzothiazin-4(3H)-one 2,2-dioxide

open access: yesActa Crystallographica Section E, 2010
In the title compound, C9H6Br3NO3S, a halogenated benzothiazine derivative, the thiazine ring adopts a sofa conformation. The crystal studied was a racemic twin with a contribution of 72 (1)% of the major domain.
Ghulam Mustafa   +3 more
doaj   +1 more source

rac-3-[(Anilino)(naphthalen-2-yl)methyl]thian-4-one

open access: yesActa Crystallographica Section E, 2012
In the title compound, C22H21NOS, the thiopyranone ring adopts a chair-like conformation with the substituent in the axial position. The relative configuration of the racemic compound is 3R,7S according to the numbering scheme used in this publication ...
A. Wahid Mesbah   +3 more
doaj   +1 more source

Expected and Unexpected Products in Half Curcuminoid Synthesis: Crystal Structures of But-3-en-2-ones and 3-Methylcyclohex-2-enones

open access: yesCrystals, 2021
The expected (E)-but-3-en-2-ones compounds I and II (half curcuminoids) were obtained by the Claisen–Schmidt reaction between aldehydes 3,4-dimethoxybenzaldehyde or 4-nitrobenzaldehyde with acetone.
Marco A. Obregón-Mendoza   +7 more
doaj   +1 more source

FeEDDHA-facilitated Fe uptake in relation to the behaviour of FeEDDHA components in the soil-plant system as a function of time and dosage. [PDF]

open access: yes, 2010
FeEDDHA products are widely used to prevent and remedy Fe chlorosis in crops grown on calcareous soils. These products consist of a mixture of FeEDDHA components: racemic o,o-FeEDDHA, meso o,o-FeEDDHA, o,p-FeEDDHA and rest-FeEDDHA. The FeEDDHA components
Temminghoff, E.J.M.   +3 more
core   +1 more source

(3aR*,7aS*)-1-(p-Tolylsulfonyl)perhydroindol-2-one

open access: yesActa Crystallographica Section E, 2010
In the racemic title compound, C15H19NO3S, the dihedral angle between the planes of the benzene ring and the O=S=O group is 56.92 (7)° and the cyclohexane ring adopts a chair conformation.
Lei Fang, Xu-Bin Fang, Lei Chen
doaj   +1 more source

rac-18-Methoxycoronaridine hydrochloride

open access: yesActa Crystallographica Section E, 2012
In the crystal structure of the racemic title compound, C22H29N2O3+·Cl−, both NH groups form N—H...Cl hydrogen bonds with the chloride counter-ion, forming translational chains along the a axis.
Martin E. Kuehne, Rory Waterman
doaj   +1 more source

rac-Ethyl rel-(2R,3R,4S)-4-hydroxy-1,2-dimethyl-5-oxopyrrolidine-3-carboxylate

open access: yesIUCrData, 2023
The asymmetric unit of the title compound, C9H15NO4, consists of a functionalized pyrrolidine ring having an envelope conformation, synthesized as an ethyl ester. The molecule has three chiral centres and crystallized as a racemic mixture. In the crystal,
Fatin Nur Ain Abdul Rashid   +6 more
doaj   +1 more source

Crystallization of the Racemic Compound and Conglomerate of (RS)-2-Chloromandelic Acid

open access: yes, 2016
(RS)-2-Chloromandelic acid is a new example of chiral compounds that can exist as a racemic compound or a conglomerate depending on the crystallization conditions. Two polymorphic racemic compounds and one conglomerate were disclosed and characterized in
Sohrab Rohani (1755568)   +3 more
core   +1 more source

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