Results 71 to 80 of about 3,131,133 (230)

OPTICAL ACTIVATION METHOD FOR RACEMIC α-SUBSTITUTED CARBONYL COMPOUNDS [PDF]

open access: yesChemistry Letters, 1975
Abstract The optical activation of racemic α-substituted carbonyl compounds by the hydrolysis of enamines with optically active α-pipecoline was reported. Solvent effect on the optical activation was also examined.
Hajime Matsushita   +2 more
openaire   +1 more source

Crystal structure of β-d,l-fructose

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2015
The title compound, C6H12O6, was crystallized from an aqueous solution of equimolar mixture of d- and l-fructose (1,3,4,5,6-pentahydroxyhexan-2-one, arabino-hexulose or levulose), and it was confirmed that d-fructose (or l-fructose) formed β-pyranose ...
Tomohiko Ishii   +4 more
doaj   +1 more source

racemic compound

open access: yes, 2014
Citation: 'racemic compound' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.R05027 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms.
openaire   +1 more source

4-(3-Methoxyphenyl)-2,6-dimethylcyclohex-3-enecarboxylic acid

open access: yesActa Crystallographica Section E, 2010
The racemic title compound, C16H20O3, was synthesized to study the hydrogen-bonding interaction of the two enantiomers in the solid state. In the crystal structure, R and S pairs of the racemate are linked by pairs of intermolecular O—H...O ...
Songwen Xie   +3 more
doaj   +1 more source

(R,R/S,S)-9-Benzyl-3-methyl-7-phenyl-1,6-dioxa-3,9-diazaspiro[4.4]nonane-2,8-dione

open access: yesIUCrData, 2019
The title compound, C19H18N2O4, a rare example of a spirocyclic orthoamide, was synthesized by a double cyclization of a N-Boc protected sarcosine derivative.
Craig M. Forsyth, Zohreh Nazarian
doaj   +1 more source

rac-8a'-Methyl-3′,4′,8′,8a'-tetrahydro-2′H-spiro[[1,3]dioxolane-2,1′-naphthalen]-6′(7′H)-one

open access: yesActa Crystallographica Section E, 2011
The title racemic compound, C13H18O3, a common precursor in the total synthesis of terpenes, crystallizes with two molecules in the asymmetric unit.
Franz Werner, Liina Toon, Riina Aav
doaj   +1 more source

Structural basis of the chiral selectivity of Pseudomonas cepacia lipase [PDF]

open access: yes, 1998
To investigate the enantioselectivity of Pseudomonas cepacia lipase, inhibition studies were performed with SC- and RC-(RP,SP)-1,2-dialkylcarbamoylglycero-3-O-p-nitrophenyl alkylphosphonates of different alkyl chain lengths. P.
Dijkstra, Bauke W.,   +4 more
core   +2 more sources

quasi-racemic compound

open access: yes, 2014
Citation: 'quasi-racemic compound' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.Q05001 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms.
openaire   +1 more source

5-(2,3-Dichlorophenyl)-3-(4-methoxyphenyl)-1-phenyl-4,5-dihydro-1H-pyrazole

open access: yesIUCrData, 2017
In the racemic title compound, C22H18Cl2N2O, the dihedral angles between the central dihydropyrazole ring (r.m.s. deviation = 0.018 Å) and the pendant methoxyphenyl, phenyl and dichlorophenyl rings are 3.96 (9), 15.90 (9) and 66.65 (9)° respectively ...
D. M. Lokeshwari   +6 more
doaj   +1 more source

Biocatalytic Route to Chiral Precursors of β-Substituted-γ-Amino Acids [PDF]

open access: yes, 2011
In this work, we utilized commercial lipases (from Thermomyces lanuginosa, Rhizopus delemar, and Mucor miehei) as biocatalysts for the efficient synthesis of precursors of β-substituted-γ-amino acids.
Martinez, Carlos A., Mukherjee, Herschel
core   +2 more sources

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