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On reaction rate constants and rate kernels
Chemical Physics Letters, 1978Abstract A simple model for a reversible isomerization reaction A ⇋ B is used to show how rate constants and their time-dependent generalizations can be related to microscopic reactive steps and nonreactive internal dynamics (e.g., vibrational relaxation).
Scott H. Northrup, James T. Hynes
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2023
This chapter considers the properties of rate constants. First, it distinguishes between the rate at which reactants encounter each other from the rate at which they undergo change once they have met. The very important feature of the latter step is the dependence of the relevant rate constant on temperature, which is found in most cases to obey an ...
Peter Atkins +3 more
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This chapter considers the properties of rate constants. First, it distinguishes between the rate at which reactants encounter each other from the rate at which they undergo change once they have met. The very important feature of the latter step is the dependence of the relevant rate constant on temperature, which is found in most cases to obey an ...
Peter Atkins +3 more
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The load dependence of rate constants
The Journal of Chemical Physics, 2008As experimental techniques in biophysics have progressed at the single molecule level, there has been considerable interest in understanding how external mechanical influences (such as load) affect chemical reactions. The majority of biophysical studies investigating load-dependent kinetics use an equation where the rate constant exponentially depends ...
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2018
This chapter assesses the methods used to study the thermodynamics and kinetics of chemical reactions based on quantum chemistry, molecular mechanics and statistical mechanics. Statistical thermodynamics can be used to calculate thermodynamic properties such as relative free energies based on properties of the potential energy surface V(R).
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This chapter assesses the methods used to study the thermodynamics and kinetics of chemical reactions based on quantum chemistry, molecular mechanics and statistical mechanics. Statistical thermodynamics can be used to calculate thermodynamic properties such as relative free energies based on properties of the potential energy surface V(R).
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CODATA recommended values of the fundamental physical constants: 2018
Reviews of Modern Physics, 2021David Newell +2 more
exaly
Calculation of Base Rate Constants from Acid Rate Constants
Journal of the American Chemical Society, 1939Samuel H. Maron, Victor K. La. Mer
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Constant catch or constant harvest rate?
Fisheries Research, 2001Olle Hjerne, Sture Hansson
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CODATA recommended values of the fundamental physical constants: 2014
Reviews of Modern Physics, 2016David Newell +2 more
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