A DFT investigation of the blue bottle experiment: E∘half-cell analysis of autoxidation catalysed by redox indicators [PDF]
Royal Society Open Science, 2017 The blue bottle experiment is a collective term for autoxidation reactions catalysed by redox indicators. The reactions are characterized by their repeatable cycle of colour changes when shaken/left to stand and intricate chemical pattern formation.
Taweetham Limpanuparb +2 more
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Amplified biochemical oscillations in cellular systems
, 2006 We describe a mechanism for pronounced biochemical oscillations, relevant to microscopic systems, such as the intracellular environment. This mechanism operates for reaction schemes which, when modeled using deterministic rate equations, fail to exhibit ...
A. Goldbeter +30 more
core +1 more source
Latest Developments of the Julia–Kocienski Olefination Reaction: Mechanistic Considerations
MoleculesSince its discovery, the Julia–Kocienski olefination reaction has over past 30 years become one of the key C-C connective methods that is used in late-stage natural product synthesis.
Daniel Chrenko, Jiří Pospíšil
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On a dynamic reaction-diffusion mechanism: The spatial patterning of teeth primordia in the alligator [PDF]
, 1996 It is now well established both theoretically and, more recently, experimentally, that steady-state spatial chemical concentration patterns can be formed by a number of specific reaction–diffusion systems.
Kulesa, P. M., Murray, J. D.
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Current Advances on Structure-Function Relationships of Pyridoxal 5′-Phosphate-Dependent Enzymes
Frontiers in Molecular Biosciences, 2019 Pyridoxal 5′-phosphate (PLP) functions as a coenzyme in many enzymatic processes, including decarboxylation, deamination, transamination, racemization, and others.
Jing Liang +4 more
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Simple one-pot synthesis of thioureas from amine, carbon disulfide and oxidants in water [PDF]
Journal of the Serbian Chemical Society, 2016 The present study reports the new facile methodology for synthesis of symmetrical and asymmetrical thioureas by an one-pot reaction of amine, carbon disulfide and oxidants: hydrogen peroxide, ethylenediamine tetraacetic acid (EDTA)/sodium ...
Milosavljević Milutin M. +6 more
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Molecules, 2023 The involvement of 1,3-dipolar cycloaddition (1,3-DP), double bond migration, metathesis, and nitrile oxide (including in situ-generated nitrile oxide) as dipoles, together with the C=C bond containing dipolarophiles, in the syntheses of 2-isoxazolines ...
Stanisław Krompiec +7 more
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Reaction Mechanism of the Aluminum Nanoparticle: Physicochemical Reaction and Heat/Mass Transfer
, 2020 A lack of clarity in the reaction mechanism of the aluminum nanoparticle (ANP) severely restricts its effective applications.
Qingzhao Chu +5 more
semanticscholar +1 more source
Quantum-Chemical Study of the Benzene Reaction with Fluorine
Atoms, 2023 The reaction of benzene with fluorine atoms may be of interest as a source of phenyl and ipso-fluorocyclohexadienyl radicals or as a method for fluorobenzene gas phase synthesis.
Sergey O. Adamson +6 more
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Poly(ADP-ribosyl)ation by PARP1: reaction mechanism and regulatory proteins
Nucleic Acids Research, 2019 Poly(ADP-ribosyl)ation (PARylation) is posttranslational modification of proteins by linear or branched chains of ADP-ribose units, originating from NAD+. The central enzyme for PAR production in cells and the main target of poly(ADP-ribosyl)ation during
E. E. Alemasova, O. Lavrik
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