Results 61 to 70 of about 9,583 (259)

Chemical Upcycling of Nitrile Butadiene Rubbers to Polyamines and Polyols by Chemoselective Catalytic Hydrogenation

open access: yesAngewandte Chemie, EarlyView.
We demonstrate here the transformation of NBR (Nitrile butadiene rubber) including post‐consumer waste sourced from nitrile gloves and o‐rings into polyamines and polyols via ruthenium catalyzed hydrogenation. ABSTRACT We report here two new approaches for the chemical recycling/upcycling of nitrile butadiene rubber (NBR) to make either polyamines or ...
Alejandra Sophia Lozano Perez   +7 more
wiley   +2 more sources

Toward Predictive Theory in Single‐Atom Catalysis

open access: yesAdvanced Science, EarlyView.
A lifecycle‐oriented framework reframes modeling in single‐atom catalysis. By combining ensemble‐based descriptions with explicit validation against experimental observables, the approach defines the scope of theory across catalyst synthesis, activity, stability, and safety, clarifying where quantitative insight is possible and where interpretation ...
Andrea Ruiz‐Ferrando   +3 more
wiley   +1 more source

Navigating Nitration Chemistry: A Practical Guide to Reagents, Mechanisms, and Selectivity

open access: yesAngewandte Chemie, EarlyView.
This review highlights key contributions of modern nitration chemistry, emphasizing sustainable mechanistic platforms and comparing the performance of both organic and inorganic reagents across aromatic, ipso‐, olefin, alkyne, and heteroatom nitration. It provides the community with a clearer, unified perspective on current advances and facilitates the
Harry Lecomte   +2 more
wiley   +2 more sources

Fabrication of Composite Cathode for All‐Solid‐State Sodium Batteries

open access: yesAdvanced Energy Materials, EarlyView.
The design of composite cathodes for all‐solid‐state sodium batteries must address three critical challenges—interfacial side reactions, interfacial delamination, and highly tortuous transport pathways. This work outlines structural and interfacial strategies to optimize ion transport and mechanical stability, enabling durable, and high‐performance ...
Gaoming Sun   +6 more
wiley   +1 more source

Structural Insights Into CO2 Transport Pathways in a W‐Formate Dehydrogenase: Structural Basis for CO2 Reduction

open access: yesAngewandte Chemie, EarlyView.
Integrated structural analysis of N. vulgaris formate dehydrogenase AB, an enzyme with applications in climate change mitigation, is reported. The substrate/product diffusion pathways were fully mapped, and a retention site was identified that transiently holds substrates and has a key role in CO2‐reducing activity.
Guilherme Vilela‐Alves   +8 more
wiley   +2 more sources

Elastomer toughened polyimide adhesives [PDF]

open access: yes, 1983
A rubber-toughened addition-type polyimide composition is disclosed which has excellent high temperature bonding characteristics in the fully cured state, and improved peel strength and adhesive fracture resistance physical property characteristics.
St.clair, A. K., St.clair, T. L.
core   +1 more source

Sulfide‐Based Electrolytes for All‐Solid‐State Sodium Batteries

open access: yesAdvanced Energy Materials, EarlyView.
This review covers the structural features and synthesis strategies of sulfide‐based solid electrolytes, as well as critical challenges related to conductivity, interfacial and moisture stability, and scaling‐up for practical application in Sodium‐based All Solid‐State Batteries.
Han Yang   +6 more
wiley   +1 more source

Acceptorless Dehydrogenative Polymerization

open access: yesAngewandte Chemie, EarlyView.
Acceptor‐less dehydrogenative polymerization (ADP) enables the atom‐economic step‐growth synthesis of different type of polymers directly from simple alcohols, releasing H2 as the sole by‐product. This review outlines the mechanistic foundations, catalytic systems, and emerging polymer architectures of ADP, highlighting its potential as a sustainable ...
Xin Liu   +2 more
wiley   +2 more sources

Formation and characterization of inorganic membranes from zeolite-silica microcomposites [PDF]

open access: yes, 1988
Small crystals of zeolites (500-1000 nm) with two- and three-dimensional channel systems (faujasite and ZSM-5 structures) were embedded in amorphous thin films derived from TEOS hydrolyzed in alcoholic solution.
Barrer   +6 more
core   +1 more source

Recent Advances in Nano‐Microstructured Catalysts for Electrochemical Seawater Electrocatalysis

open access: yesAdvanced Energy Materials, EarlyView.
This review highlights advances in nano‐ and microstructured catalysts for electrochemical seawater conversion. It elucidates design principles, mechanistic understanding, and machine‐learning‐assisted discovery, and outlines key challenges and future opportunities toward efficient, selective, and durable seawater electrocatalysis.
Xiaodong Shao   +5 more
wiley   +1 more source

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