Stabilized Bi(III) Sites Direct *NH2OH Pathway for Efficient Cyclohexanone Oxime Electrosynthesis
Advanced Materials, EarlyView.The electron‐buffering effect stabilizes Bi3+ sites under electroreductive conditions, preserving a favorable interfacial water configuration that sustains the selective *NH2OH pathway and enables efficient cyclohexanone oxime electrosynthesis. ABSTRACT Coupling electrocatalytic nitrite reduction reaction (NO2−RR) with cyclohexanone conversion enables ...
Zichao Xi +8 more
wiley +1 more source
Ligand‐Mediated Shape Engineering of SWIR InAs Colloidal Quantum Dots for Photodetector Applications
Advanced Materials, EarlyView.The table of contents: A robust ligand‐engineering strategy is introduced for SWIR InAs CQDs synthesized from amino‐arsine precursors. Bulky OA ligands induce controlled shape evolution, allowing access to >1700 nm absorption under mild conditions. Halide‐based inkification enables photodetectors with 19.1% EQE at 1300 nm and detectivity exceeding 1010
Taewan Kim +5 more
wiley +1 more source
Advanced Materials, EarlyView.Fully recombinant protein‐based biomaterials execute complex Boolean logic for user‐programmable material degradation and concomitant therapeutic cargo release. Biologics, such as growth factors, can be incorporated within the crosslinkers as “drugamers”, while encapsulated cells can be released according to nested YES/OR/AND‐type logical operations ...
Murial L. Ross +3 more
wiley +1 more source
Advanced Materials, EarlyView.In this research the [4‐(3,6‐dimethyl‐9H‐carbazol‐9‐yl)butyl] phosphonic acid (Me‐4PACz) self‐assembled monolayers (SAMs) to bond with NiOx is first designed to be the organic‐inorganic hybrid hole‐selective layers, which promotes the BiVO4 photoanodes photoelectrochemical water splitting performance with 6.9 mA cm−2 photocurrent at 1.23 VRHE and at ...
Kaige Tian +10 more
wiley +1 more source
Advanced Materials, EarlyView.Selective methane (CH4) photooxidation emerges from architectural decoupling of activation and preservation. Programmable organic semiconductor frameworks spatially organize oxidative flux and intermediate residence, separating reaction zones from product domains to synchronize activation strength with stabilization and establish a selective oxidation ...
Minxian Zhang +5 more
wiley +1 more source
Glucocorticoids induce production of reactive oxygen species/reactive nitrogen species and DNA damage through an iNOS mediated pathway in breast cancer. [PDF]
Breast Cancer Res, 2017 Flaherty RL +8 more
europepmc +1 more source
Hybrid Amyloid–Boron Nitride Aerogels for Lightweight Sound Insulation
Advanced Materials, EarlyView.Amyloid fibrils template the mild formation of boron nitride–rich hybrid aerogels with hierarchical porosity, enhanced BN‐like ordering, and fibril‐reinforced mechanics. These ultralight materials combine thermal stability with strong sound absorption and transmission loss, offering a sustainable bio‐assisted route toward lightweight acoustic shields ...
Mohammad Peydayesh +8 more
wiley +1 more source
Spotlights on immunological effects of reactive nitrogen species: When inflammation says nitric oxide. [PDF]
World J Exp Med, 2015 Predonzani A +3 more
europepmc +1 more source
Solvent‐Guided Chiral Assemblies and Chemical Doping of OEG‐Functionalized Conjugated Polymers
Advanced Materials, EarlyView.Solvent‐dependent aggregation pathways dictate whether conjugated polymers form chiral lyotropic liquid‐crystalline assemblies or achiral packed aggregates. Mapping solvent‐controlled β₁ and β2 states reveals that weaker backbone association favors β₁ aggregates and reorganizable twisted mesophases, whereas stronger backbone association favors β2 ...
Sanghyun Jeon +10 more
wiley +1 more source
Expression of Concern: Activation of the AMP-activated protein kinase by the anti-diabetic drug metformin in vivo: Role of mitochondrial reactive nitrogen species. [PDF]
J Biol Chem, 2019 europepmc +1 more source