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A redox-switchable catalyst with an ‘unplugged’ redox tag

Chemical Communications, 2022
A series of bis-(propyl-imidazoliylidene)-napthalenediimide (NDI) complexes of rhodium and iridium showed effective redox-switching properties, despite the electronic disconnection between the NDI moiety and the metal centres.
Cristian L. Gutiérrez-Peña   +2 more
openaire   +3 more sources

Redox Proteomics

Journal of Proteomics, 2011
We believe that this JoP special issue on Redox Proteomics not only represents one of the numerous attempts to start a network of information among multiplelaboratories working on this delicate topic, but it also promises to start bridging the persisting gaps between the clinical and the academic milieu, hopping that, for the foreseeable future, this ...
Scaloni A, Zolla L
openaire   +5 more sources

The redox switch/redox coupling hypothesis

Neurochemistry International, 2006
We provide an integrative interpretation of neuroglial metabolic coupling including the presence of subcellular compartmentation of pyruvate and monocarboxylate recycling through the plasma membrane of both neurons and glial cells. The subcellular compartmentation of pyruvate allows neurons and astrocytes to select between glucose and lactate as ...
Cerdán, Sebastián   +6 more
openaire   +3 more sources

Redox imbalance

Cell and Tissue Research, 2004
Substantial evidence implies that redox imbalance attributable to an overproduction of reactive oxygen species or reactive nitrogen species that overwhelm the protective defense mechanism of cells contributes to all forms of Parkinson's disease. Factors such as dopamine, neuromelanin, and transition metals may, under certain circumstances, contribute ...
Daniela, Berg   +2 more
openaire   +2 more sources

Redox signaling

Molecular and Cellular Biochemistry, 2002
Reactive oxygen species (ROS) and reactive nitrogen species (RNS) have recently been shown to be involved in a multiplicity of physiological responses through modulation of signaling pathways. Some of the specific signaling components altered by reactive oxygen and nitrogen species (RONS) have begun to be identified.
Henry Jay, Forman   +2 more
openaire   +2 more sources

Redox-capacitor to connect electrochemistry to redox-biology

The Analyst, 2014
It is well-established that redox-reactions are integral to biology for energy harvesting (oxidative phosphorylation), immune defense (oxidative burst) and drug metabolism (phase I reactions), yet there is emerging evidence that redox may play broader roles in biology (e.g., redox signaling).
Eunkyoung, Kim   +5 more
openaire   +2 more sources

Redox clocks: Time to rethink redox interventions

Free Radical Biology and Medicine, 2018
Redox interventions have been controversial in the management of chronic disease. The key reason is believed to be a lack of clarity in our understanding of how endogenous dynamics unfold in biochemical redox mechanisms in live cells. Time-resolved, quantitative research strategies combined with high throughput analysis tools may result in realistic ...
Andras D, Nagy, Akhilesh B, Reddy
openaire   +2 more sources

Redox Control, Redox Signaling, and Redox Homeostasis in Plant Cells

2003
Redox chemistry is a key feature of life. Oxidized substrates are reduced to synthesize functional molecules; reduced substrates are oxidized for energy supply. In addition, cells must fight against uncontrolled oxidation of essential constituents, a process that continuously occurs in an atmosphere of 21% O2. The redox situation is further complicated
openaire   +3 more sources

Redox Control of Apoptosis

Antioxidants & Redox Signaling, 2005
[No abstract available]
openaire   +4 more sources

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