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Effect of the Cu2+/1+ Redox Potential of Non-Macrocyclic Cu Complexes on Electrochemical CO2 Reduction [PDF]

open access: yesMolecules, 2023
Cu2+/1+ complexes facilitate the reduction of CO2 to valuable chemicals. The catalytic conversion likely involves the binding of CO2 and/or reduction intermediates to Cu2+/1+, which in turn could be influenced by the electron density on the Cu2+/1+ ion ...
Kyuman Kim   +3 more
doaj   +2 more sources

Leaf Eh and pH: A Novel Indicator of Plant Stress. Spatial, Temporal and Genotypic Variability in Rice (Oryza sativa L.) [PDF]

open access: yesAgronomy, 2018
A wealth of knowledge has been published in the last decade on redox regulations in plants. However, these works remained largely at cellular and organelle levels. Simple indicators of oxidative stress at the plant level are still missing. We developed a
Olivier Husson   +11 more
doaj   +3 more sources

Theoretical Study on Redox Potential Control of Iron-Sulfur Cluster by Hydrogen Bonds: A Possibility of Redox Potential Programming [PDF]

open access: yesMolecules, 2021
The effect of hydrogen bonds around the active site of Anabaena [2Fe-2S] ferredoxin (Fd) on a vertical ionization potential of the reduced state (IP(red)) is examined based on the density functional theory (DFT) calculations.
Iori Era   +8 more
doaj   +2 more sources

Properties of Selenolate-Diselenide Redox Equilibria in View of Their Thiolate-Disulfide Counterparts

open access: yesAntioxidants, 2023
Selenium, the multifaceted redox agent, is characterized in terms of oxidation states, with emphasis on selenol and diselenide in proteinogenic compounds.
Tamás Pálla   +2 more
doaj   +1 more source

Convolutional neural network prediction of molecular properties for aerosol chemistry and health effects

open access: yesNatural Sciences, 2022
Quinones are chemical compounds commonly found in air particulate matter (PM). Their redox activity can generate reactive oxygen species (ROS) and contribute to the oxidative potential (OP) of PM leading to adverse health effects of aerosols.
Matteo Krüger   +7 more
doaj   +1 more source

Connexin hemichannels regulate redox potential via metabolite exchange and protect lens against cellular oxidative damage

open access: yesRedox Biology, 2021
Increased oxidative stress contributes to cataract formation during aging. Anterior epithelial cells are a frontline antioxidant defense system with powerful capacities to maintain redox homeostasis and lens transparency.
Yumeng Quan   +4 more
doaj   +1 more source

Contribution of periphytic biofilm of paddy soils to carbon dioxide fixation and methane emissions

open access: yesThe Innovation, 2022
Rice paddies are major contributors to anthropogenic greenhouse gas emissions via methane (CH4) flux. The accurate quantification of CH4 emissions from rice paddies remains problematic, in part due to uncertainties and omissions in the contribution of ...
Sichu Wang   +7 more
doaj   +1 more source

Redox Potential of Antioxidants in Cancer Progression and Prevention

open access: yesAntioxidants, 2020
The benevolent and detrimental effects of antioxidants are much debated in clinical trials and cancer research. Several antioxidant enzymes and molecules are overexpressed in oxidative stress conditions that can damage cellular proteins, lipids, and DNA.
Sajan George, Heidi Abrahamse
doaj   +1 more source

Substratum Raking Can Restore Interstitial Habitat Quality in Swedish Freshwater Pearl Mussel Streams

open access: yesDiversity, 2023
Functional and oxygenated stream beds provide crucial habitat for multiple endangered stream taxa, including endangered freshwater mussels, fishes, and insect larvae.
Juergen Geist   +3 more
doaj   +1 more source

Iridium: An option for measurement of the redox potential

open access: yesCiencias Marinas, 2003
 Some relevant results are presented of research leading to an alternative redox electrode to platinum. Several different electrodes were subjected to experiments under controlled conditions, mainly in artificial seawater.
LM Rios-Mendoza   +2 more
doaj   +1 more source

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