Results 191 to 200 of about 614,145 (271)

A Cu‐Based Near‐IR Active MOF with an Ion‐Pair Guest Exhibiting Versatile and Selective Gas‐Solid Reactivity

open access: yesAdvanced Materials, EarlyView.
The new Cu‐containing MOF (Me2NH2)(CuICl2)@[Cu4(INA)4Cl2O]·1.5dmf (3) contains a cation and an anion as guests and shows UV‐near‐mid‐IR absorption and near‐IR emission. MOF 3 shows gas‐solid reactivity in the presence of NH3 and HCOOH to yield two new 3D MOF.
Rajat Saha   +10 more
wiley   +1 more source

Comprehensive Understanding of Accelerated Kinetics Driven by Anion–Diluent Dynamics Enabling Wide Temp Operation in Dual‐Ion Batteries

open access: yesAdvanced Materials, EarlyView.
The transient interactions between TFSI− anions and a diluent within an anion‐dictated electrolyte are revealed, which can reduce interfacial reorganization energy, thereby accelerating ion kinetics and markedly facilitating sustainable anion storage in high‐voltage graphite cathodes for dual‐ion batteries at fast charge and wide temperature range ...
Sungho Kim   +9 more
wiley   +1 more source

Azaporphyrinoid‐Based Photo‐ and Electroactive Architectures for Advanced Functional Materials

open access: yesAdvanced Materials, EarlyView.
A long‐standing collaboration between the Torres and Guldi groups has yielded diverse azaporphyrinoid‐based donor‐acceptor nanohybrids with promising applications in solar energy conversion. This conspectus highlights key molecular platforms and structure‐function relationships that govern light and charge management, supporting the rational design of ...
Jorge Labella   +3 more
wiley   +1 more source

Decoupling Dynamics and Crosslink Stability in Supramolecular Hydrogels Using Associative Exchange

open access: yesAdvanced Materials, EarlyView.
How does reorganization impact the stability of supramolecular hydrogels? In contrast to dissociative crosslink exchange, implementing associative exchange in macroscale DNA hydrogels enables decoupling of reorganization dynamics from thermal and mechanical stability.
Pierre Le Bourdonnec   +4 more
wiley   +1 more source

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