Angewandte Chemie, EarlyView.High‐resolution proton detection is preserved under cryogenic dynamic nuclear polarization (DNP) by combining fast MAS, extensive deuteration and selective methyl protonation. This strategy enables proton‐detected structural studies of biomolecular solids with enhanced sensitivity under DNP conditions.
James Tolchard +16 more
wiley +1 more source
Cross-Sectional Study of Rehabilitation Training Intensity and Physical Restraints in Patients With Cardiovascular Disease and Neurocognitive Disorders in Acute Care Hospitals. [PDF]
CureusIshida Y +10 more
europepmc +1 more source
Angewandte Chemie, EarlyView.Modifying the conformational ensemble of “molten‐globule” protein by the site‐specific incorporation of stereoisomeric 4‐fluoroproline residues modulated its binding affinity and aggregation behavior. 19F NMR spectroscopy enabled the detection of key interactions responsible for structural and dynamic changes. ABSTRACT Recently, the application of deep
Abir Ben Bouzayene +5 more
wiley +1 more source
Beyond the Oxo‐Wall: Synthesis and Reactivity of a Six‐Coordinate Formally CoIV‐Oxo Complex
Angewandte Chemie, EarlyView.We present the first example of a six‐coordinate formally Co(IV)‐oxo complex, [Co(TQA)(O)(OH)]+ (1), which exists as an admixture of CoIV‐oxo and CoIII‐oxyl resonance structures. Complex 1 is capable of performing oxygen atom transfer reactions and abstracting moderately strong hydrogen atoms at rates faster than other characterized CoIV‐oxo compounds.
Jason Shearer +6 more
wiley +1 more source
Pharmacotherapy for pediatric and adolescent agitation in an inpatient behavioral health unit. [PDF]
Ment Health ClinYang M, Rarrick CM, Ross C.
europepmc +1 more source
Angewandte Chemie, EarlyView.An enantioselective photometallobiocatalytic cross‐coupling of pyridotriazoles and secondary alkyltrifluoroborate salts is developed. Cooperative catalysis using eosin B and an engineered protoglobin combines visible‐light‐mediated radical generation with enzymatic metal carbenoid activation, affording valuable N‐heterocyclic products in excellent ...
Huanan Wang +5 more
wiley +1 more source
The impact of structured training on the management of agitated pediatric patients in the emergency department: changes in knowledge and self-efficacy perceptions of physicians. [PDF]
BMC PediatrNalbant T +6 more
europepmc +1 more source
Development and Application of a Unplanned Extubation Assessment and Clinical Decision Support Information System. [PDF]
Risk Manag Healthc PolicyChen H +6 more
europepmc +1 more source
Pre-corticosteroid delusional psychosis and olanzapine-responsive behavioral dyscontrol in autoimmune glial fibrillary acidic protein astrocytopathy: A case report. [PDF]
PCN RepSugisaki T +6 more
europepmc +1 more source